Patterns of Nd and Sr isotopic ratios produced by magmatic and post-magmatic processes in the Shiant Isles Main Sill, Scotland

The Shiant Isles Main Sill of the British Tertiary Igneous Province is a classic example of a differentiated, alkaline basic sill. Four separate intrusions, each emplaced internally in rapid succession, form a 165-m-thick sill hosted by Lower Jurassic sedimentary rocks. Extensive Nd and Sr isotopic studies were conducted on samples from a vertical section through the sill where the relationships of samples to one another are well defined. The results illuminate patterns of modification of isotopic ratios and clarify the petrogenesis (magma sources, crustal contamination), magmatic processes (bulk mixing, interstitial liquid mixing), and post-magmatic alteration (hydrothermal effects on Sr and Nd). Overall, the whole-rock initial ⁸⁷Sr/⁸⁶Sr ratios range from ∼0.7037 to 0.7061 while initial ¹⁴³Nd/¹⁴⁴Nd ratios vary from ∼0.51243 to 0.51286 (ɛ_Nd∼−0.7 to +5.7) – values that contrast markedly with those of the country rock. Acid leaching (HCl) of the whole-rock samples that removes analcime indicates that most of the scatter in the ⁸⁷Sr/⁸⁶Sr is caused by the ubiquitous sub-solidus, aqueous alteration during which more-radiogenic Sr was introduced into the sill, especially along the margins, and also reveals magmatic isotopic ratios. In contrast, Nd was immobile during fluid interaction so that the sill ¹⁴³Nd/¹⁴⁴Nd ratios were not affected, even <1 m from the country-rock contact. Using leached rock values, ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios are inversely correlated from magmatic processes. Magmas with two distinct isotopic compositions were involved: a more primitive one with ¹⁴³Nd/¹⁴⁴Nd ∼0.51285 and ⁸⁷Sr/⁸⁶Sr ∼0.7035 that produced the first two intrusions and a more evolved one (with 0.51252 and 0.7048) that produced the third intrusion. Mixing of the two magmas was very limited, restricted to near contacts between units, and apparently occurred by interstitial melt migration. The more evolved crinanitic magma was probably produced from a batch of the more primitive picritic melt by a small degree of crustal contamination and crystal fractionation during a short crustal residence prior to ascent and emplacement. Received: 20 December 1999 / Accepted: 5 May 2000     

High‐pressure metamorphism in Taiwan: from oceanic subduction to arc‐continent collision?

Abstract The Taiwan orogen has been the focus of a number of models of mountain building processes, but little attention has been paid to high‐pressure (HP) metamorphic rocks that are found as exotic blocks intermingled within the deepest units of the mountain belt. In this study, we re‐appraise from updated petrological and thermodynamic databases the physical conditions of HP metamorphism in Taiwan, and we combine our findings with available geochronological data to estimate the thermal history of these rocks. Our results indicate that peak metamorphic conditions of ～550 °C and 10–12 kbar have been followed by a rapid isothermal decompression, with exhumation possibly as rapid as burial. These units have subsequently been stored at a pressure of ～3 kbar for ～4–5 Myr, before their final exhumation, probably facilitated by the accretion of passive margin sequences during the Late Cenozoic collision. Therefore, HP units in Taiwan maintain a record of processes at depth from the early stages of oceanic subduction to the present arc‐continent collision.     

Reduced-Dimensional Processing for Ground Moving Target Detection in Distributed Space-Based Radar

With multisatellite radar systems, several additional features are achieved: multistatic observation, interferometry, ground moving target indication (GMTI). In this letter, a new reduced-dimensional method based on joint pixels sum-difference (Sigma-Delta) data for clutter rejection and GMTI is proposed. The reduced-dimensional joint pixels Sigma-Delta data are obtained by the orthogonal projection of the joint pixels data of different synthetic aperture radar (SAR) images generated by a multisatellite radar system. In the sense of statistic expectation, the joint pixels Sigma-Delta data contain the common and different information among SAR images. Then, the objective of clutter cancellation and GMTI can be achieved by adaptive processing. Simulation results demonstrate the effectiveness and robustness of the proposed method even with clutter fluctuation and image coregistration errors     

Prediction of Resource Volumes at Untested Locations Using Simple Local Prediction Models

This paper shows how local spatial nonparametric prediction models can be applied to estimate volumes of recoverable gas resources at individual undrilled sites, at multiple sites on a regional scale, and to compute confidence bounds for regional volumes based on the distribution of those estimates. An approach that combines cross-validation, the jackknife, and bootstrap procedures is used to accomplish this task. Simulation experiments show that cross-validation can be applied beneficially to select an appropriate prediction model. The cross-validation procedure worked well for a wide range of different states of nature and levels of information. Jackknife procedures are used to compute individual prediction estimation errors at undrilled locations. The jackknife replicates also are used with a bootstrap resampling procedure to compute confidence bounds for the total volume. The method was applied to data (partitioned into a training set and target set) from the Devonian Antrim Shale continuous-type gas play in the Michigan Basin in Otsego County, Michigan. The analysis showed that the model estimate of total recoverable volumes at prediction sites is within 4 percent of the total observed volume. The model predictions also provide frequency distributions of the cell volumes at the production unit scale. Such distributions are the basis for subsequent economic analyses.

Vertical distribution of dissolved organic carbon (DOC) in the Western Mediterranean Sea in relation to the hydrological characteristics

Vertical profiles of dissolved organic carbon (DOC) from eight hydrological stations in the Tyrrhenian Sea, Sardinia Channel and Algerian Sea, are reported. DOC exhibits concentrations ranging from 58 to 88 μM in surface water, 43–57 μM in the intermediate layer and 49–63 μM in deep waters. The assessment of the hydrological characteristics allows different water masses in the study area to be identified; moreover, different hydrological processes are observed in the Tyrrhenian and Algerian basins. DOC exhibits different values in the different water masses. The lowest DOC concentrations (43–46 μM) were found in the Tyrrhenian Levantine Intermediate Water (LIW). Correlations between DOC and apparent oxygen utilization (AOU), investigated within each water mass, exhibit different behaviors in the intermediate and deep waters, suggesting the occurrence of different processes of oxygen consumption in the different water masses.     

Dynamic response of the leg of a tension leg platform subjected to an axial, suddenly applied load at one end

This paper deals with the solution of the problem of the dynamic response of the leg of a tension leg platform subjected to an axial, suddenly applied load at one end, considering a highly simplified model but taking into account several complicating factors. The problem is solved by means of a non-harmonic Fourier expansion in terms of eigenfunctions obtained from a non-regular Sturm-Liouville system.     

A reanalysis of the relationship between strong westerlies and precipitation in the Great Plains and Midwest regions of North America

A conceptual model relating expanded or strengthened mid-latitude summer westerlies with summer precipitation patterns has been used to explain past drought events in the Great Plains and Midwest of North America, including drought between 1200 and 1400 AD. However, this relationship was originally described using 20 years of instrumental data from the mid 20{th} century, and has not been verified with modern datasets. We reinvestigated the relationship between July westerlies and precipitation in the United States using instrumental records of the last 55 years. We also investigated whether changes in summer zonal flow patterns associated with precipitation anomalies represent a shift in the latitude of peak westerly winds or an increase in wind speed, or a combination of both.Finally, we briefly compare the pattern of precipitation anomalies to paleoclimatic records of drought between 1200 and 1400 AD. Results confirm that strong westerlies are associated with a band of decreased precipitation extending from the northern Rockies into the Midwest. Changes in summer westerlies associated with these patterns are characterized by a strengthening of mean westerly winds, with only a slight southward shift of peak winds over the Atlantic. Changes in the strength of the westerlies over both the Pacific and Atlantic appear to be important to precipitation deficits in the Midwest. Proxy-climate records from 1200 to 1400 AD indicate widespread drought in the Great Plains and Midwest, consistent with the hypothesis of stronger westerlies at this time. However, drought conditions also extended to other regions of North America, indicating a more detailed understanding of the potential causes and synoptic climatology is needed.     

Petrography, chemistry and origin of early diagenetic concretions in the Lower Carboniferous of the Isle of Man

Three silicified limestone horizons of D1 age from the Visean of the Isle of Man contain calcitic concretions with peripheral silica crusts, occasionally surrounded by a further calcitic layer. Components of the original sediment include carbonate skeletons, carbonaceous grains, sponge spicules and muscovite. Diagenetic products include calcite, dolomite, pyrite, sphalerite, clays, feldspar and quartz. The concretions are composed of neomorphic calcite. The time of recrystallization and the identity of the neomorphic precurosor are both unknown. Displacive, fibrous calcite is chemically similar to neomorphic calcite and both are of early diagenetic age. Granular and rhombic ferroan calcites are of late diagenetic age and were precipitated from pore-waters with Sr/Ca, Mg/Ca and Fe/Ca ratios unlike those of seawater. The difference between early silicification which produced silica crusts and later diffuse silicification of the host sediment is related to a change in sediment transmissivity between the two silicification periods. A four-fold scheme of concretionary growth is proposed. The supply of silica is from sponge spicules and that of carbonate from seawater via porewater. The distribution of organic matter, either as sporadic large carcasses or as small carcasses concentrated in particular horizons, is believed to be vital for carbonate precipitation and controls the distribution of concretions. Awareness of the multiplicity of diagenetic changes is essential in interpretation of early porewater systems and in the origin of products which are often metastable and destined to subsequent changes. No single model is an explanation for all types of concretionary growth.