Potassium diffusion in melilite: Experimental studies and constraints on the thermal history and size of planetesimals hosting CAIs

Abstract— Among the calcium‐aluminum‐rich inclusions (CAIs), excess ⁴¹K (⁴¹K*), which was produced by the decay of the short‐lived radionuclide ⁴¹Ca (t_1/2 = 0.1 Myr), has so far been detected in fassaite and in two grains of melilites. These observations could be used to provide important constraints on the thermal history and size of the planetesimals into which the CAIs were incorporated, provided the diffusion kinetic properties of K in these minerals are known. Thus, we have experimentally determined K diffusion kinetics in the melilite end‐members, åkermanite and gehlenite, as a function of temperature (900–1200 °C) and crystallographic orientation at 1 bar pressure. The closure temperature of K diffusion in melilite, T_c(K:mel), for the observed grain size of melilite in the CAIs and cooling rate of 10–100 °C/Myr, as calculated from our diffusion data, is much higher than that of Mg in anorthite. The latter was calculated from the available Mg diffusion data in anorthite. Assuming that the planetesimals were heated by the decay of ²⁶Al and ⁶⁰Fe, we have calculated the size of a planetesimal as a function of the accretion time t_f such that the peak temperature at a specified radial distance r_c equals T_c(K:mel). The ratio (r_c/R)³ defines the planetesimal volume fraction within which ⁴¹K* in melilite grains would be at least partly disturbed, if these were randomly distributed within a planetesimal. A similar calculation was also carried out to define R versus t_f relation such that ²⁶Mg* was lost from ?50% of randomly distributed anorthite grains, as seems to be suggested by the observational data. These calculations suggest that ?60% of melilite grains should retain ⁴¹K* if ?50% of anorthite grains had retained ²⁶Mg*. Assuming that t_f was not smaller than the time of chondrule formation, our calculations yield minimum planetesimal radius of ?20–30 km, depending on the choice of planetesimal surface temperature and initial abundance of the heat producing isotope ⁶⁰Fe.     

Uneven Distribution of Pseudotormentus De Wever et Caridroit (Radiolaria, Protozoa): Provincialism of a Permian Planktonic Microorganism

The Permian planktonic distribution is not well known, in contrast to other fossil distributions of nekton and benthos. Radiolaria are representative microfossils of plankton in the Permian palaeocean. This study compares both correlated radiolarian occurrences (Pseudotormentus De Wever et Caridroit and Quadriremis Nazarov et Ormiston) in literature data from the Pacific Rim and quantitative data from the Liuhuang and Gujingling sections in South China. Pseudotormentus distributions are concentrated in the Panthalassa, whereas Quadriremis occurrences are distributed over both the Panthalassa and the Palaeotethys. The uneven distribution of Pseudotormentus seems to have been controlled by a difference in the oceanic basins, indicating the presence of faunal differences in Permian planktonic microorganisms between the Panthalassa and the Palaeotethys. In other words, this study infers the provincialism of Permian planktonic microorganisms. The uneven distribution is explainable by a hypothesis that Pseudotormentus was strongly affected by a Panthalassan equatorial current.     

Effects of tides and weather on sedimentation of iron‐oxyhydroxides in a shallow‐marine hydrothermal environment at Nagahama Bay,Satsuma Iwo‐Jima Island,Kagoshima, southwest Japan

Nagahama Bay of Satsuma Iwo‐Jima Island, southwest Japan, is an excellent place for studying sedimentation of iron‐oxyhydroxides by shallow‐marine low‐temperature hydrothermal activity. Its fishing port has a narrow entrance that limits exchange of seawater between the bay and open ocean, allowing the accumulation of fine‐grained precipitates of iron‐bearing materials (Fe‐oxyhydroxides) on the seafloor. The fishing port is usually filled with orange‐ to brown‐colored Fe‐rich water, and deposits >1.5 m thick Fe‐rich sediments. To elucidate the movement and depositional processes of the Fe‐rich precipitates in the bay, we conducted continuous profiling of turbidity throughout the tidal cycle and monitoring of surface water. The results showed that clear seawater entered the bay during the rising tide, and turbid colored water flowed into the ocean during the ebb tide. Neap tide was found to be an optimal condition for sedimentation of Fe‐oxyhydroxides due to weak tidal currents. Storms and heavy rains were also found to have influenced precipitation of Fe‐oxyhydroxides. Storm waves disturbed the bottom sediments, resulting in increased turbidity and rapid re‐deposition of Fe‐oxyhydroxides with an upward‐fining sequence. Heavy rain carried Fe‐oxyhydroxides originally accumulated in nearby beach sands to the bay. Our findings provide information on optimal conditions for the accumulation of Fe‐rich sediments in shallow‐marine hydrothermal settings.     

Thermal metamorphic history of a Ca,Al‐rich inclusion constrained by high spatial resolution Mg isotopic measurements with NanoSIMS 50L

Abstract– Mg isotope data were collected by NanoSIMS with high‐precision and high‐spatial resolution from a coarse‐grained type B Ca‐, Al‐rich inclusion (CAI), EK1‐6‐3, in the Allende CV3 chondrite to evaluate the time scale of parent body thermal metamorphism. The CAI melilite and fassaite contain excesses of ²⁶Mg (²⁶Mg*) from the in‐situ decay of ²⁶Al; the inferred initial ratio, (²⁶Al/²⁷Al)₀ = (5.8 ± 2.4) × 10^?5, is consistent with many previously reported coarse‐grained CAIs from CV chondrites (e.g., MacPherson et al. 1995 ). However, the anorthite has heterogeneous (²⁶Al/²⁷Al)₀, ranging from 1.8 × 10^?5 to 3.3 × 10^?6. The ²⁶Al‐²⁶Mg systematics within the anorthite is consistent with thermal diffusion of Mg isotopes during metamorphism. We also show that the heterogeneous distribution of ²⁶Mg* in anorthite could have resulted from thermal diffusion of ²⁶Mg* over a 0.6–0.8 Ma time span. Mg diffusion thus may be responsible for the (²⁶Al/²⁷Al)₀ heterogeneity within anorthite in CAIs.     

冻结作用下黏土中水、盐迁移试验研究

为了探究冻结作用下黏土中水盐迁移特性,采用室内单向冻结试验装置,基于TDR技术对添加不同溶质（NaCl）浓度的土样进行了土中温度、含水率及电导率（EC）的同时连续测量。结果表明：溶质的添加引起土中孔隙水冰点下降,造成土中成冰量减少,从而导致含溶质土样的冻结深度大于不含溶质土样;在封闭系统中随着溶质浓度的增大,土中水分迁移量和溶质迁移率均有增大趋势,距离冻结锋面越远,水分、溶质迁移量就越少;冻结锋面附近液态水凝结成冰,引起冻结锋面附近溶质浓度变化剧烈,溶质浓度急剧增大。