Review of the Cambrian volcanic activity in Morocco: geochemical fingerprints and geotectonic implications for the rifting of West Gondwana

International Journal of Earth Sciences - Volcanic activities related to the opening of a Cambrian rift in Morocco were widespread from the Fortunian to the Cambrian Epoch 3. Numerous data are...     

Evaluation of Axial Performance of Hollow Bar Micropiles Constructed with Different Drill Bit to Hollow Bar Diameter Ratio

Geotechnical and Geological Engineering - Hollow bar micropiles (HBMP) have been popular for some time due to their fast installation and efficient load transfer mechanism. In the construction of...     

Inverted Barrovian Metamorphic Zones in the Poly-Deformed Domains of the Western Wadi Allaqi Shear Zone (South Eastern Desert,Egypt): Geochemical and Structural Constraints

Geotectonics - Poly-deformed late-Proterozoic metamorphic domains covering Um Ashira area at the western segment of Wadi Allaqi shear zone, South Eastern Desert of Egypt, show evidences of inverted...     

Sequence stratigraphy and cyclicity in the Middle Eocene of the Fayoum ranges,Western Desert,Egypt: Implications for regional sea level changes

The Middle Eocene deposits in the Fayoum Ranges are composed of complex alternative clastic (claystone and sandstone) and carbonate (limestone and dolostone) facies and dominated carbonate (limestone) facies. Facies are arranged mainly in regression and shallowing upward (emergence) cycles and sequences. Field stratigraphic and microfacies analysis of the study area permits recognition of four major sequences, reflecting 3rd-order cycles. Depositional sequences and cycles are bounded by subaerial erosive surfaces or caliche deposits, ferruginous crust, and by their correlative conformities. Sequence-1 consists of two shallowing-upward cycles (dominate carbonate facies), each of which starts with nummulitic wackestone, capped with nummulitic packstone including Globigerinatheka subconglobata subconglobata biozone. These cycles were deposited under tropical to subtropical conditions as evidenced by the carbonate nature of the rocks and the abundance of nummulites, which need warm conditions for their flourishing. Sequence-2 consists of four emergence cycles based with claystone and capped with wackestone including Morozovella lehneri biozone. The duration (Ma) of sequence-2 (Morozovella lehneri zone) is 3.05 Ma (44.25 Ma for the upper of TA3 3.3 to 41.2 Ma for the lower of TA3 3.5). Sequence-3 includes three rock units (includes Trucorotaloides rohri biozone). The lower unit involves lowstand systems tract, the middle unit contains transgressive systems tract and the upper rock unit includes highstand systems tract. The lowstand systems tract consists of emergence cycles of mixed clastic- carbonate facies, clays at the base and capped with wackestone and packstone facies. The transgressive systems tract consists of dominant carbonate facies, wackestone at the base and capped with packstone facies. Sequence 4 involves transgressive systems tract. The duration of both sequence-3 and sequence 4 has been estimated as 1.8 Ma.     

Predicting river water temperatures using the equilibrium temperature concept with application on Miramichi River catchments (New Brunswick,Canada)

Water temperature influences most of the physical, chemical and biological properties of rivers. It plays an important role in the distribution of fish and the growth rates of many aquatic organisms. Therefore, a better understanding of the thermal regime of rivers is essential for the management of important fisheries resources. This study deals with the modelling of river water temperature using a new and simplified model based on the equilibrium temperature concept. The equilibrium temperature concept is an approach where the net heat flux at the water surface can be expressed by a simple equation with fewer meteorological parameters than required with traditional models. This new water temperature model was applied on two watercourses of different size and thermal characteristics, but within a similar meteorological region, i.e., the Little Southwest Miramichi River and Catamaran Brook (New Brunswick, Canada). A study of the long‐term thermal characteristics of these two rivers revealed that the greatest differences in water temperatures occurred during mid‐summer peak temperatures. Data from 1992 to 1994 were used for the model calibration, while data from 1995 to 1999 were used for the model validation. Results showed a slightly better agreement between observed and predicted water temperatures for Catamaran Brook during the calibration period, with a root‐mean‐square error (RMSE) of 1·10 °C (Nash coefficient, NTD = 0·95) compared to 1·45 °C for the Little Southwest Miramichi River (NTD = 0·94). During the validation period, RMSEs were calculated at 1·31 °C for Catamaran Brook and 1·55 °C for the Little Southwest Miramichi River. Poorer model performances were generally observed early in the season (e.g., spring) for both rivers due to the influence of snowmelt conditions, while late summer to autumn modelling performances showed better results. Copyright © 2005 John Wiley & Sons, Ltd.     

Distribution and Enrichment of Heavy Metals in Recent Sediments of Safaga Bay,Egypt

The present study was undertaken for assessing the level of heavy metals such as iron, manganese, zinc, copper, nickel, cadmium, lead, and cobalt in recent sediment samples of Safaga Bay, Egypt. Concentration of heavy metals in sediments shows significant variability and ranges from 863.37 to 1144.93 ppm for Fe, 64.29–586.8 ppm for Mn, 2.7–12.68 ppm for Zn, 3.01–7.2 ppm for Pb, 1.53–3.29 ppm for Ni, 0.55–1.57 ppm for Co, 0.16–1.37 ppm for Cu, and 0.22–0.4 ppm for Cd.

Sediment pollution assessments were carried out using an enrichment factor and geoaccumulation index. The calculation of enrichment factor showed that Cd is enriched by 4.1 due to phosphate sources in Safaga Bay. The Geoaccumulation index results revealed that there are positive and negative correlations between Fe, Zn, Mn, Pb, Ni, Cu, Co, and Cd indicating that these metals have complicated geochemical behaviors.     

Evaluation of uncertainties in the CRCM-simulated North American climate

This work is a first step in the analysis of uncertainty sources in the RCM-simulated climate over North America. Three main sets of sensitivity studies were carried out: the first estimates the magnitude of internal variability, which is needed to evaluate the significance of changes in the simulated climate induced by any model modification. The second is devoted to the role of CRCM configuration as a source of uncertainty, in particular the sensitivity to nesting technique, domain size, and driving reanalysis. The third study aims to assess the relative importance of the previously estimated sensitivities by performing two additional sensitivity experiments: one, in which the reanalysis driving data is replaced by data generated by the second generation Coupled Global Climate Model (CGCM2), and another, in which a different CRCM version is used. Results show that the internal variability, triggered by differences in initial conditions, is much smaller than the sensitivity to any other source. Results also show that levels of uncertainty originating from liberty of choices in the definition of configuration parameters are comparable among themselves and are smaller than those due to the choice of CGCM or CRCM version used. These results suggest that uncertainty originated by the CRCM configuration latitude (freedom of choice among domain sizes, nesting techniques and reanalysis dataset), although important, does not seem to be a major obstacle to climate downscaling. Finally, with the aim of evaluating the combined effect of the different uncertainties, the ensemble spread is estimated for a subset of the analysed simulations. Results show that downscaled surface temperature is in general more uncertain in the northern regions, while precipitation is more uncertain in the central and eastern US.     

Experimental superheating of water and aqueous solutions

The metastable superheated solutions are liquids in transitory thermodynamic equilibrium inside the stability domain of their vapor (whatever the temperature is). Some natural contexts should allow the superheating of natural aqueous solutions, like the soil capillarity (low T superheating), certain continental and submarine geysers (high T superheating), or even the water state in very arid environments like the Mars subsurface (low T) or the deep crustal rocks (high T). The present paper reports experimental measurements on the superheating range of aqueous solutions contained in quartz as fluid inclusions (Synthetic Fluid Inclusion Technique, SFIT) and brought to superheating state by isochoric cooling. About 40 samples were synthetized at 0.75 GPa and 530-700 °C with internally-heated autoclaves. Nine hundred and sixty-seven inclusions were studied by micro-thermometry, including measuring the temperatures of homogenization (Th: L + V → L) and vapor bubbles nucleation (Tn: L → L + V). The Th-Tn difference corresponds to the intensity of superheating that the trapped liquid can undergo and can be translated into liquid pressure (existing just before nucleation occurs at Tn) by an equation of state. Pure water (840-935 kg m⁻³), dilute NaOH solutions (0.1 and 0.5 mol kg⁻¹), NaCl, CaCl₂ and CsCl solutions (1 and 5 mol kg⁻¹) demonstrated a surprising ability to undergo tensile stress. The highest tension ever recorded to the best of our knowledge (−146 MPa, 100 °C) is attained in a 5 m CaCl₂ inclusion trapped in quartz matrix, while CsCl solutions qualitatively show still better superheating efficiency. These observations are discussed with regards to the quality of the inner surface of inclusion surfaces (high P-T synthesis conditions) and to the intrinsic cohesion of liquids (thermodynamic and kinetic spinodal). This study demonstrates that natural solutions can reach high levels of superheating, that are accompanied by strong changes of their physico-chemical properties.