Groundwater hydrochemistry and origin in the south-eastern part of Wadi El Natrun,Egypt

The demand for water is rapidly increasing in Egypt, because of high population and agriculture production growth rate, which makes research of water resources necessary. The regional multi-aquifer system of the Miocene–Pleistocene age is discharged in Wadi El Natrun area. Intensive aquifer overexploitation and agricultural development in the area are related to groundwater quality deterioration. Hydrochemical and hydrogeological data was evaluated to determine the groundwater origin and quality in the south-eastern part of wadi, which appears to be more significant for water supply owing to lower groundwater salinity. The dominance of the high mineralised Cl groundwater type was found; however, also less mineralised SO₄ and HCO₃ types were identified there. Based on the ion relations, halite and gypsum dissolution and ion exchange are the most important hydrochemical processes forming the groundwater chemical composition. The Cl dominated groundwater matches the discharge part of the regional hydrogeological system. Contrary, the presence of HCO₃ and SO₄ hydrochemical types corresponds to the infiltration and transferring parts of the hydrogeological system indicating the presence of zones conducting low mineralised groundwater. The discharge area of the over-pumped aquifer in Wadi El-Natrun lies 23 m beneath the sea level with the shoreline being at the distance of 100 km, thus there is a real risk of seawater intrusion. Using the hydrochemical facies evolution diagram, four samples in the centre of the discharge area indicate advanced seawater intrusion. The zones of the highest demand for groundwater quality protection were indicated based on a spatial pattern of hydrogeochemical composition.     

Analysis of contamination hazard of surface water by the methodology of TECHNEAU: a case study from the dam 9 April 1947 in northern Morocco

Preventive protection of surface waters against pollution and the guarantee of the best quality water are the major challenges to provide a sustainable supply of drinking water for the future generations. In this article, we present a hazard mapping application for water contamination of the dam “9 April 1947” located in the northwest of Morocco. This study was motivated by the proliferation of many pollution sources in the study area knowing that the dam feeds the region of Tanger-Asilah that has over 3 million inhabitants. The methodology used was applied for the first time in the city of Freiburg-Ebnet in Germany under the TECHNEAU project funded by the European commission and based on weighting of the different sources of contamination according to three indices: the toxicity index, quantity index, and probability index. The multiplication of the three indices has given us a hazard index named HI varying between 0 and 120 depending on the harmfulness of hazard; the later index has been used to create the final contamination hazard map. The hazard map shows 65% of the watershed area is witnessing a very low danger, 22% of the watershed area is witnessing a low danger, 10% of the watershed area is witnessing a the high danger, and 3% of the watershed area is witnessing a moderate.     

Landslide susceptibility mapping using analytic hierarchy process and information value methods along a highway road section in Constantine,Algeria

This research work deals with the landslide susceptibility assessment using Analytic hierarchy process (AHP) and information value (IV) methods along a highway road section in Constantine region, NE Algeria. The landslide inventory map which has a total of 29 single landslide locations was created based on historical information, aerial photo interpretation, remote sensing images, and extensive field surveys. The different landslide influencing geoenvironmental factors considered for this study are lithology, slope gradient, slope aspect, distance from faults, land use, distance from streams, and geotechnical parameters. A thematic layer map is generated for every geoenvironmental factor using Geographic Information System (GIS); the lithological units and the distance from faults maps were extracted from the geological database of the region. The slope gradient, slope aspect, and distance from streams were calculated from the Digital Elevation Model (DEM). Contemporary land use map was derived from satellite images and field study. Concerning the geotechnical parameters maps, they were determined making use of the geotechnical data from laboratory tests. The analysis of the relationships between the landslide-related factors and the landslide events was then carried out in GIS environment. The AUC plot showed that the susceptibility maps had a success rate of 77 and 66% for IV and AHP models, respectively. For that purpose, the IV model is better in predicting the occurrence of landslides than AHP one. Therefore, the information value method could be used as a landslide susceptibility mapping zonation method along other sections of the A1 highway.     

C18 Sep-Pak Extractable Dissolved Organic Copper Related to Hydrochemistry in the North-west Mediterranean

Extractable organic copper using C18 Sep-Pak cartridges was investigated in seawater after laboratory experiment showed that the (C18 Sep-Pak) cartridges were reliable, in open and coastal waters with normal levels of dissolved organic carbon, for the separation of a specific fraction of organo-copper complexes.Given that the Sep-Pak cartridges retain the hydrophobic fraction of the dissolved organic matter, this extraction technique was applied for studying the characteristics of this particular hydrophobic dissolved organic copper fraction (hDOCu) in the north-western Mediterranean waters. Surface distribution of hDOC is influenced by organic matter input from the river Rhone and its estuary as well as the physical processes affecting the primary productivity such as coastal upwelling. By correlating hDOCu concentrations with total dissolved copper and other hydrochemical data such as salinity and dissolved organic carbon, it was possible to examine the behaviour of hDOCu in the water masses of different sources and ages.Marine organic matter has been shown to have high complexing capacity. Productive superficial and intermediate waters as well as deep waters showed relatively high and comparable complexing capacity indicating that old organic matter may have strong complexing sites.     

An investigation into the Winkler modeling of the cyclic response of rigid footings

The response of shallow foundations under lateral cyclic loading is generally nonlinear and involves rocking, sliding, settlement, and may also involve foundation uplift and soil yielding. Unlike pile foundations, the nonlinear Winkler model is not widely used for modeling cyclic soil–footing–structure interaction (SFSI) problems. Nonetheless, it has some important features that make it more attractive than conventional finite element approaches, and is a recommended approach in the FEMA 356 design guideline. This paper explores the strengths and limitations of the FEMA 356 nonlinear Winkler modeling approach, when used in predicting the cyclic response of various recent SFSI experiments. The results of the study show that the model is capable of satisfactorily predicting all the different cyclic response quantities apart from permanent horizontal displacements. This should therefore be noted when using the approach in design.     

Geoelectrical exploration for groundwater in Al Maha Forest,Ain Jouhra,Morocco

An area of about 30 km² located in Ain Jouhra, south of Rabat, Morocco, was the subject of a geoelectric resistivity investigation. The main goal of the investigation was the assessment of the groundwater potential of the uppermost aquifer. The aquifer conditions such as depth, thickness and boundaries were also investigated. The obtained apparent resistivity curves were first analysed qualitatively and classified using simple curve shapes. Thereafter, the data were converted to resistivity and thickness pairs semi‐quantitatively by means of master curves and then quantitatively by computer modelling using ATO and Winsev software (Zohdy, 1989; Zohdy and Bisdrof, 1989). Lithological control from the available single well with a stratigraphic log aided in the correlation of the resistivity values to different rock units. Three different AB‐spacing iso‐resistivity maps, an isopach map of the main groundwater‐bearing horizon, the depth to the aquifer substratum map and five geoelectric cross‐sections were constructed. The interpretation of these soundings indicates the presence of an unconfined to semi‐confined sandy aquifer with relatively important extent and varying thickness. The maximal thickness of the aquifer is recorded in the central part of the investigated area and is thinning southwards to pinch out farther to the south. Geophysical as well as field data indicate a hydraulic connection between the upper and deeper aquifers. Indeed, the two aquifers are separated from each other by a marly substratum that is indicated throughout the area by the lowest values of the interpreted true resistivity. The value of this resistivity varies laterally, most likely due to the lateral variation in the shale‐to‐sand ratio. The altitude of the substratum decreases towards the north, and increases southwards. Regarding the availability of the groundwater in the study area, zones with high potential are theoretically expected to occur in the central part where the transversal resistance is greatest. However, sufficient water supply and high flow rates from wells intended to produce restrictively from the most upper aquifer are not likely to exist. This conclusion, which seems to be very pessimistic, is evidenced from two real field and experimental observations. The first is the rapid fall of the level of Gharnoug lake, despite the ongoing feeding by three wells. Hence, the amount of water level drop cannot be accounted for by the evaporation alone. That means that the deeper aquifer is continuously draining the upper aquifer at a high flow rate. Very low rates are recorded in all the wells that penetrated only the upper aquifer, the exception being the well that reached deeper into the lower aquifer. The flow rate in this lower aquifer measured 18 litre s^?1. Copyright © 2007 John Wiley & Sons, Ltd.     

Centrifuge modelling of normal fault–foundation interaction

Earthquake fault ruptures may emerge at the ground surface causing large differential movements. When fault ruptures emerge at or adjacent to the position of existing foundations, significant damage can be caused. However, the study of recent faulting events revealed that in some circumstances the fault-rupture emergence is deflected by the presence of buildings leaving the buildings intact. A centrifuge modelling study has been conducted to investigate how normal faults interact with strip foundations which run parallel to the strike direction. The study confirms that fault rupture may be deviated by the presence of the foundation so that the foundation is protected from the most serious differential movements. However, whilst the fault propagates to the soil surface the foundation has to withstand initial movements before the final fault rupture emergence mechanism is activated. The centrifuge results suggest that it is the bearing pressure of the foundation which causes the deviation of the fault rather than the kinematic restraint of the foundation. The interaction between the earthquake fault and the shallow foundation depends on the foundation bearing pressure, foundation width, soil depth and position of the fault relative to the foundation and these aspects should be considered in design. Results from the tests are used to validate a series of finite element analyses as reported in an accompanying paper.     

Spectral characteristics of natural and artificial seismic events in the Lop Nor test site, China

Seismic discriminants based on the spectral seismogram and spectral magnitude techniques have been tested to discriminate between three events; a nuclear explosion which took place in Lop Nor, China with m _b 6.1 and two earthquakes from the closest area with m _b 5.5 and 5.3, respectively. The spectral seismogram of the three events shows that the frequency content of the nuclear explosion differs from that of the earthquakes where the P wave is richier in high frequency content in the nuclear explosion than the corresponding earthquakes. It is also observed that the energy decays more rapidly for the nuclear explosion than for the earthquakes. Furthermore, the spectral magnitudes reveal significant differences in the spectra between the nuclear explosion and the two earthquakes. The observed differences appear to be quite enough to provide a reliable discriminant. The estimated stress drop from the magnitude spectra indicates a higher stress drop of the nuclear explosion relative to the earthquakes of the same tectonic region.     

Evaluation of phosphorus bioavailability in El Mex Bay and Lake Mariut sediments

Phosphorus (P) fractions and their bioavailability in the sediments from El Mex Bay and Lake Mariut in Egypt were investigated using different chemical extraction methods. Sodium bicarbonate (NaHCO3) extractable P (Olsen-P) was the largest fraction (14.42%), followed by algal available P (AAP) (3.56%), water soluble P (WSP) (0.79%), and readily desorbable P (RDP) (0.06%) for El Mex Bay. While AAP con-tributed 9.94% to total P in sediments from Lake Mariut, Olsen-P 8.53%, WSP 4.11%, and RDP 0.92%. Summation of the bioavailable P fractions didn't exceed the sediment quality guidelines, and, therefore, P doesn't represent a danger to marine organisms. Correlation coefficients showed that no apparent relations between total P (TP) and iron (Fe), aluminum (Al), and calcium (Ca) in the sediments. Fur-thermore, Fe:P ratio was less than 15 indicting that there was not enough Fe in surface sediments to bind to P at most of the sampling sites. The positive correlation between TP and organic matter (OM) for Lake Mariut and El Mex Bay sediments indicated that the organic matter content of the sediment was a useful predictor of the total phosphorus content. Data from this study constitute a baseline of phosphorus bioavailability in sediments from El Mex Bay and Lake Mariut and could be used as a reference for future studies on the changes of bioavailable and residual phosphorus fractions over time.     

Look-ahead vertical seismic profiling inversion approach for density and compressional wave velocity in Bayesian framework

To reduce drilling uncertainties, zero-offset vertical seismic profiles can be inverted to quantify acoustic properties ahead of the bit. In this work, we propose an approach to invert vertical seismic profile corridor stacks in Bayesian framework for look-ahead prediction. The implemented approach helps to successfully predict density and compressional wave velocity using prior knowledge from drilled interval. Hence, this information can be used to monitor reservoir depth as well as quantifying high-pressure zones, which enables taking the correct decision during drilling. The inversion algorithm uses Gauss–Newton as an optimization tool, which requires the calculation of the sensitivity matrix of trace samples with respect to model parameters. Gauss–Newton has quadratic rate of convergence, which can speed up the inversion process. Moreover, geo-statistical analysis has been used to efficiently utilize prior information supplied to the inversion process. The algorithm has been tested on synthetic and field cases. For the field case, a zero-offset vertical seismic profile data taken from an offshore well were used as input to the inversion algorithm. Well logs acquired after drilling the prediction section was used to validate the inversion results. The results from the synthetic case applications were encouraging to accurately predict compressional wave velocity and density from just a constant prior model. The field case application shows the strength of our proposed approach in inverting vertical seismic profile data to obtain density and compressional wave velocity ahead of a bit with reasonable accuracy. Unlike the commonly used vertical seismic profile inversion approach for acoustic impedance using simple error to represent the prior covariance matrix, this work shows the importance of inverting for both density and compressional wave velocity using geo-statistical knowledge of density and compressional wave velocity from the drilled section to quantify the prior covariance matrix required during Bayesian inversion.