Ion Irradiation of Asphaltite: Optical Effects and Implications for Trans-Neptunian Objects and Centaurs

Trans-Neptunian Objects (TNOs) and Centaurs show remarkable colour variationsin the visual and near-infrared spectral regions. Surface alteration processes such asspace weathering (e.g., bombardment with ions) and impact resurfacingmay play an important role in the colour diversity of such bodies. Ion irradiation ofhydrocarbon ices and their mixtures with water ice transforms neutral (grey) surfacecolours of ices to red and further to grey. Along with the ices, TNOs and Centaursprobably contain complex carbonaceous compounds, in particular, complexhydrocarbons. Unlike ices, such refractory organic materials have originally lowvisual albedos and red colours in the visible and near-infrared ranges. Here wepresent the first results of ion irradiation experiments on asphaltite. Asphaltite isa natural complex hydrocarbon material. The reflectance spectra of asphaltite inthe 0.4–0.8 μm range have been recorded before irradiation and after eachirradiation step. We demonstrate that irradiation of this red dark material with30 keV H⁺ and 15 keV N⁺ ions gradually transforms its colour from redto grey as a result of carbonization. A moderate increase in the visual albedo hasbeen observed. These results may imply that the surfaces of primitive red objectsoptically dominated by complex refractory organics may show a similar spaceweathering trend. Our laboratory results were compared with published coloursof TNOs and Centaurs. A broad variety of spectral colours observed for TNOs andCentaurs may be reproduced by various spectra of irradiated organics correspondingto different ion fluences. However, such objects probably also contain ices and silicatecomponents which show different space weathering trends. This fact, together with alack of information about albedos, may explain difficulties to reveal correlations between surface colours within TNO and Centaur populations and their other properties, such as absolute magnitudes and orbital parameters.     

Microtextures and crystal chemistry in P21/c pigeonites

Summary ?A single-crystal X-ray investigation was performed on crystals of P2₁/c natural pigeonite with varying Ca and Fe^* ( = Fe²⁺ + Mn²⁺) contents, in order to verify the effect of microtextural disorder on structure refinements and to constrain the crystal chemistry of pigeonite. Antiphase domains and exsolution lamellae affect differently the refinement results. In a crystal free of exsolution the structure obtained after refinement with all reflections is an average of that of the antiphase domains and of their boundaries, whereas in an exsolved crystal it represents only the structure of the prevailing pigeonite lamellae. The refinement using only h + k odd reflections seems to give the structure of the Ca-free pigeonite characteristic of the antiphase domains rather than that of Ca-rich domain walls. The ratio of the scale factors in refinements with all reflections and with only h + k odd reflections allows the ratios of the exsolved augite and pigeonite phases to be estimated. The crystal chemistry of the investigated samples follows the trends outlined by data on Ca-free and Fe-free synthetic samples. In particular, it is shown that Ca and Fe^* substitution for Mg induce similar changes in the average structure, i.e. both induce an expansion in the M1 polyhedron and decrease the difference between the M2–O3 distances. Received October 18, 2001; revised version accepted February 15, 2002     

Photometric Study of the W Uma-Type Eclipsing Binary System GSC 4832.400

We present a photometric analysis of the eclipsing binary systemGSC4832.400 based on 732 photometric observations obtained on sixteen clear nights during 1999–2000 in the V-Johnson and yb-Strömgren filters. The observed times of the minima yielded a linear ephemeris showing that the system has a constant period of 0.313150 ± 0.000002days. The light curve corresponds to a circular orbit for the system and clearly shows that GSC4832.400 has the defining characteristics of a W UMa-type eclipsing binary. It also shows a small O'Connell effect, which could be due to the presence of a hot spot in the primary star. A preliminary photometric solution based on the assumption of an over contact systemsatis factorily reproduced the observed light curve.     

Size and shape evolution of pores in a viscoplastic matrix under compression

The frequent use of soils and earth materials for hydraulic capping and for geo‐environmental waste containment motivated our interest in detailed modelling of changes in size and shape of macro‐pores to establish links between soil mechanical behaviour and concurrent changes in hydraulic and transport properties. The objective of this study was to use finite element analysis (FEA) to test and extend previous analytical solutions proposed by the authors describing deformation of a single macro‐pore embedded in linear viscoplastic soil material subjected to anisotropic remote stress. The FEA enables to consider more complex pore geometries and provides a detailed picture of matrix yield behaviour to explain shortcomings of approximate analytical solutions. Finite element and analytical calculations agreed very well for linear viscous as well as for viscoplastic materials, only limited for the case of isotropic remote stress due to the simplifications of the analytical model related to patterns and onset of matrix‐yielding behaviour. FEA calculations were compared with experimental data obtained from a compaction experiment in which pore deformation within a uniform modelling clay sample was monitored using CAT scanning. FEA predictions based on independently measured material properties and initial pore geometry provided an excellent match with experimentally determined evolution of pore size and shape hence lending credence to the potential use of FEA for more complex pore geometries and eventually connect macro‐pore deformation with hydraulic properties. Copyright © 2006 John Wiley & Sons, Ltd.     

Resonant and Secular Families of the Kuiper Belt

We review ongoing efforts to identify occupants of mean-motion resonances(MMRs) and collisional families in the Edgeworth–Kuiper belt. Directintegrations of trajectories of Kuiper belt objects (KBOs) reveal the 1:1(Trojan), 5:4, 4:3, 3:2 (Plutino), 5:3, 7:4, 9:5, 2:1 (Twotino), and 5:2 MMRsto be inhabited. Apart from the Trojan, resonant KBOs typically have largeorbital eccentricities and inclinations. The observed pattern of resonanceoccupation is consistent with resonant capture and adiabatic excitation bya migratory Neptune; however, the dynamically cold initial conditions priorto resonance sweeping that are typically assumed by migration simulationsare probably inadequate. Given the dynamically hot residents of the 5:2 MMRand the substantial inclinations observed in all exterior MMRs, a fraction ofthe primordial belt was likely dynamically pre-heated prior to resonancesweeping. A pre-heated population may have arisen as Neptune gravitationallyscattered objects into trans-Neptunian space. The spatial distribution of Twotinosoffers a unique diagnostic of Neptune's migration history. The Neptunian Trojanpopulation may rival the Jovian Trojan population, and the former's existence isargued to rule out violent orbital histories for Neptune. Finally, lowest-order seculartheory is applied to several hundred non-resonant KBOs with well-measured orbitsto update proposals of collisional families. No convincing family is detected.     

Effect of spatial variation characteristics on contouring of design storm depth

The ordinary kriging method, a geostatistical interpolation technique, was applied for developing contour maps of design storm depth in northern Taiwan using intensity–duration–frequency (IDF) data. Results of variogram modelling on design storm depths indicate that the design storms can be categorized into two distinct storm types: (i) storms of short duration and high spatial variation and (ii) storms of long duration and less spatial variation. For storms of the first category, the influence range of rainfall depth decreases when the recurrence interval increases, owing to the increasing degree of their spatial independence. However, for storms of the second category, the influence range of rainfall depth does not change significantly and has an average of approximately 72 km. For very extreme events, such as events of short duration and long recurrence interval, we do not recommend usage of the established design storm contours, because most of the interstation distances exceed the influence ranges. Our study concludes that the influence range of the design storm depth is dependent on the design duration and recurrence interval and is a key factor in developing design storm contours. Copyright © 2003 John Wiley & Sons, Ltd.