The Pongola structure of southeastern Africa: The world's oldest preserved rift?

Rocks of the Pongola Supergroup form an elongate belt in the Archean Kaapvaal Craton of southern Africa. Because these rocks exhibit many features that are characteristic of rocks deposited in continental rifts, including rapid lateral variations in thickness and character of sediments, volcanic rocks that are bimodal in silica content, coarse, basement derived conglomerates and thick sequences of shallow water sedimentary facies associations, we suggest that the Pongola Supergroup was deposited in such a rift. The age of these rocks (approximately 3.0 Ga) makes the Pongola structure the world's oldest well-preserved rift so far recognized, and comparison of the Pongola Rift with other rifts formed more recently in earth history reveals striking similarities, suggesting that the processes that formed this rift were not significantly different from those that form continental rifts today.     

Starspot modelling of the RS CVn binary HK lacertae

Investigating more than 270 nightly mean magnitudes of the long-period RS CVn binary HK Lac, we can draw some conclusions about the nature of its complicated light variations. The mean brightness, the apparent photometric period, and the shape of the light curve all show strong variations. Analysis with a starspot model, assuming two large spots and a general uniform spottedness, indicates two comparably large spots which appear to have maintained their separate identities for the last 15 yr and drifted in longitude separation from each other smoothly by only about 45°. The phase of the two spots indicates both are rotating very nearly synchronously with the orbital motion, one slightly (0.025%) faster and the other slightly (0.080%) slower. the latitudes of the two spots, one farther above the equator and one closer to the equator, are consistent with solar-type differential rotation and yield an estimate of 25±12° for the co-rotating latitude. A correlation between mean spot latitude and instantaneous photometric period yields another estimate of 31±2°, in agreement with the first.     

An assessment of biases associated with caging,tethering, and trawl sampling of summer flounder (<Emphasis Type="Italic">Paralichthys dentatus</Emphasis>)

We provide an example of the type of bias assessment that should, but often is not, used in ecological studies using techniques such as caging, tethering, and trawl sampling. Growth rates of summer flounder (Paralichthys dentatus) from cage enclosures were compared to those from mark-recapture trials, and prey types (identified through stomach content analysis) compared between caged fish and wild fish collected from nursery sites over a 2-yr period. Site-specific growth rates estimated from the caging method were similar (± 15%) to those estimated from the mark-recapture trials. Prey types were nearly identical between caged and wild fish, although selectivity may have varied quantitatively. Caging summer flounder will generally be an appropriate tool with which to measure growth rates in the wild, but comparisons with an independent measurement method are necessary for validation. In tethering trials, predation was significantly greater on tethered than on untethered fish, indicating that tethering is not an appropriate tool with which to measure absolute rates of predation on juvenile summer flounder. The lack of effects of substrate (sand versus mud) and fish origin (hatchery-reared versus wild) on predation of tethered versus untethered fish indicates that tethering trials will not indicate treatment-specific differences when none exist. Tethering may be an acceptable method for comparing relative rates of predation on different substrates and between hatchery-reared and wild juvenile summer flounder in the field, although true differences in treatment levels could be masked by tethering. Beam trawl efficiency estimates for juvenile summer flounder were similar between beach and marsh habitats, but differed significantly between marsh sites, indicating that site-specific trawl efficiency estimates may be critical to accurately assess juvenile flounder the appropriateness of comparisons of size-frequency information between the sites and habitats used in this study. Caging, tethering, and beam trawl sampling are appropriate tools for measuring ecological parameters of juvenile summer flounder, but only if possible biases of each method are identified and compensated for when interpreting data collected using these methods.     

The chad basin: An active intra-continental basin

Well over one hundred separate graben formed in association with ocean opening can be recognized around the shores of the Atlantic Ocean. The graben are linked forming an elaborate network of triple-rift systems. Some rifts developed to form ocean but many failed. The stratigraphie and structural history of these rift structures is varied and helps to illuminate the processes that operate at continental rupture. Rifting has been commonly accompanied by basaltic vulcanism and rapid accumulation of several kilometers of sediment. Horsts within the graben strongly influence early sediment distribution. Generally, rift faulting ceases about the time of onset of normal marine sedimentation but there are a few exceptions and some graben formed at ocean opening have influenced sediment distribution more than 100 m.y. later. Although tensional structures predominate strike-slip and compressional structures have developed locally in the graben. The rivers bringing the largest amounts of sediment into the Atlantic during the last 150 m.y. have prograded along failed rift arms formed at continental rupture. In some cases their deltas have come to lie on oceanic crust.     

Using GC-MS/Combustion/IRMS to determine the C/C ratios of individual hydrocarbons produced from the combustion of biomass materials--application to biomass burning

Simultaneous mass spectral detection and stable carbon isotope analysis was performed on individual indigenous n-alkanes isolated from single C₄ and C³ plant species and on a series of aliphatic and polycyclic aromatic hydrocarbons (PAH) produced from the combustion of these same biomass materials. The analysis technique used a combined gas chromatograph-mass spectrometer/combustion/isotope ratio mass spectrometer (GC-MS/C/IRMS). Precision (2σ) for replicate measurements of individual compounds in standard solutions using this novel configuration ranged between 0.2 and 0.5‰ for n-alkanes and 0.3 and 0.8‰ for PAH. Accuracy of the n-alkane measurements ranged between 0.1 and 0.4‰ and that of the PAH measurements ranged between 0.2 and 0.9‰. Replicate GC-MS/C/IRMS measurements on the combustion-derived n-alkene/alkane pairs were performed to within a precision of between 0.1 and 1.1‰ and the precision for the combustion PAH was similar to the standard PAH solution. No notable isotopic effects were observed when altering the temperature of the combustion process from 900 to 700°C, or as a result of the individual n-alkenes/alkanes partitioning between the gaseous and condensate fractions. Combustion-derived n-alkenes/alkanes ranged from C₁₁ to C₃₁, and the C₄-derived n-alkenes/alkanes were approx. 8‰ more enriched in ¹³C than the C₃-derived compounds. Both the C₄ and C₃-derived n-alkenes/alkanes (C₂₀-C₃₀) were isotopically similar to the indigenous n-alkanes and were 2-3‰ more depleted in ¹³C than the lower mol. wt (C₁₁₁₁-C₁₉) n-alkenes/alkanes, suggesting an independent origin for the lower mol. wt compounds. Combustion-generated C₄ and C₃-derived 2-, 3-, and 4-ring PAH were also isotopically distinct (Δδ = 10‰). Unlike the n-alkenes/alkanes, no compound-to-compound variations were observed between the low and high mol. wt PAH. This study demonstrates that the isotopic composition of original plant biomass material is mainly preserved in the aliphatic hydrocarbons and PAH generated by its combustion. Consequently, analyses of these compounds in sediments impacted by fire occurrences may provide useful information about paleo-fire activity that may help elucidate the impact biomass burning may have had and could have on climate-biosphere interactions.     

Effective collision strengths for forbidden transitions in e-N and e-o scattering

Cross sections for forbidden transitions between all terms of the ground state configurations in electron scattering by atomic nitrogen and atomic oxygen are calculated using the R-matrix method. These cross sections are used to obtain effective collision strengths which are found to differ substantially from previous calculations at electron temperatures of interest in the physics of the upper atomsphere of the earth.     

Exploring controls of the early and stepped deglaciation on the western margin of the British Irish Ice Sheet

New optically stimulated luminescence dating and Bayesian models integrating all legacy and BRITICE-CHRONO geochronology facilitated exploration of the controls on the deglaciation of two former sectors of the British–Irish Ice Sheet, the Donegal Bay (DBIS) and Malin Sea ice-streams (MSIS). Shelf-edge glaciation occurred ~27 ka, before the global Last Glacial Maximum, and shelf-wide retreat began 26–26.5 ka at a rate of ~18.7–20.7 m a^–1. MSIS grounding zone wedges and DBIS recessional moraines show episodic retreat punctuated by prolonged still-stands. By ~23–22 ka the outer shelf (~25 000 km²) was free of grounded ice. After this time, MSIS retreat was faster (~20 m a^–1 vs. ~2–6 m a^–1 of DBIS). Separation of Irish and Scottish ice sources occurred ~20–19.5 ka, leaving an autonomous Donegal ice dome. Inner Malin shelf deglaciation followed the submarine troughs reaching the Hebridean coast ~19 ka. DBIS retreat formed the extensive complex of moraines in outer Donegal Bay at 20.5–19 ka. DBIS retreated on land by ~17–16 ka. Isolated ice caps in Scotland and Ireland persisted until ~14.5 ka. Early retreat of this marine-terminating margin is best explained by local ice loading increasing water depths and promoting calving ice losses rather than by changes in global temperatures. Topographical controls governed the differences between the ice-stream retreat from mid-shelf to the coast.     

Pattern,style and timing of British–Irish Ice Sheet retreat: Shetland and northern North Sea sector

The offshore sector around Shetland remains one of the least well-studied parts of the former British–Irish Ice Sheet with several long-standing scientific issues unresolved. These key issues include (i) the dominance of a locally sourced ‘Shetland ice cap’ vs an invasive Fennoscandian Ice Sheet; (ii) the flow configuration and style of glaciation at the Last Glacial Maximum (i.e. terrestrial vs marine glaciation); (iii) the nature of confluence between the British–Irish and Fennoscandian Ice Sheets; (iv) the cause, style and rate of ice sheet separation; and (v) the wider implications of ice sheet uncoupling on the tempo of subsequent deglaciation. As part of the Britice-Chrono project, we present new geological (seabed cores), geomorphological, marine geophysical and geochronological data from the northernmost sector of the last British–Irish Ice Sheet (north of 59.5°N) to address these questions. The study area covers ca. 95 000 km², an area approximately the size of Ireland, and includes the islands of Shetland and the surrounding continental shelf, some of the continental slope, and the western margin of the Norwegian Channel. We collect and analyse data from onshore in Shetland and along key transects offshore, to establish the most coherent picture, so far, of former ice-sheet deglaciation in this important sector. Alongside new seabed mapping and Quaternary sediment analysis, we use a multi-proxy suite of new isotopic age assessments, including 32 cosmogenic-nuclide exposure ages from glacially transported boulders and 35 radiocarbon dates from deglacial marine sediments, to develop a synoptic sector-wide reconstruction combining strong onshore and offshore geological evidence with Bayesian chronosequence modelling. The results show widespread and significant spatial fluctuations in size, shape and flow configuration of an ice sheet/ice cap centred on, or to the east of, the Orkney–Shetland Platform, between ~30 and ~15 ka BP. At its maximum extent ca. 26–25 ka BP , this ice sheet was coalescent with the Fennoscandian Ice Sheet to the east. Between ~25 and 23 ka BP the ice sheet in this sector underwent a significant size reduction from ca. 85 000 to <50 000 km², accompanied by several ice-margin oscillations. Soon after, connection was lost with the Fennoscandian Ice Sheet and a marine corridor opened to the east of Shetland. This triggered initial (and unstable) re-growth of a glaciologically independent Shetland Ice Cap ca. 21–20 ka BP with a strong east–west asymmetry with respect to topography. Ice mass growth was followed by rapid collapse, from an area of ca. 45 000 km² to ca. 15 000 km² between 19 and 18 ka BP , stabilizing at ca. 2000 km² by ~17 ka BP. Final deglaciation of Shetland occurred ca. 17–15 ka BP , and may have involved one or more subsidiary ice centres on now-submerged parts of the continental shelf. We suggest that the unusually dynamic behaviour of the northernmost sector of the British–Irish Ice Sheet between 21 and 18 ka BP – characterized by numerous extensive ice sheet/ice mass readvances, rapid loss and flow redistributions – was driven by significant changes in ice mass geometry, ice divide location and calving flux as the glaciologically independent ice cap adjusted to new boundary conditions. We propose that this dynamism was forced to a large degree by internal (glaciological) factors specific to the strongly marine-influenced Shetland Ice Cap.     

Mapped Predictions of Manganese and Arsenic in an Alluvial Aquifer Using Boosted Regression Trees

Manganese (Mn) concentrations and the probability of arsenic (As) exceeding the drinking-water standard of 10 μg/L were predicted in the Mississippi River Valley alluvial aquifer (MRVA) using boosted regression trees (BRT). BRT, a type of ensemble-tree machine-learning model, were created using predictor variables that affect Mn and As distribution in groundwater. These variables included iron (Fe) concentrations and specific conductance predicted from previously developed BRT models, groundwater flux and age estimates from MODFLOW, and hydrologic characteristics. The models also included results from the first airborne geophysical survey conducted in the United States to target an entire aquifer system. Predictions of high Mn and As occurred where Fe was high. Predicted high Mn concentrations were correlated with fraction of young groundwater (less than 65 years) computed from MODFLOW results. High probabilities of As exceedance were predicted where groundwater was relatively old and airborne electromagnetic resistivity was high, typically proximal to streams. Two-variable partial-dependence plots and sensitivity analysis were used to provide insight into the factors controlling Mn and As distribution in groundwater. The maps of predicted Mn concentrations and As exceedance probabilities can be used to identify areas where these constituents may be high, and that could be targeted for further study. This paper shows that incorporation of a selected set of process-informed data, such as MODFLOW results and airborne geophysics, into a machine-learning model improves model interpretability. Incorporation of process-rich information into machine-learning models will likely be useful for addressing a wide range of problems of interest to groundwater hydrologists.