Alkylation of polycyclic aromatic hydrocarbons in carbonaceous chondrites

Using microprobe laser-desorption, laser-ionization mass spectrometry (μL²MS), we measured the distributions of alkylated and unalkylated polycyclic aromatic hydrocarbons (PAHs) in the free organic material of 20 carbonaceous chondrites. These meteorites represent a variety of meteorite classes and alteration histories, including CI, CK, CM, CO, CR, CV, and Tagish Lake. This work provides information on free organic compounds that is complementary to studies of the structure and composition of meteoritic macromolecular content.For the nine CM2 meteorites analyzed, we observe that higher relative abundances of alkylated PAHs correlate with more intense aqueous activity. We attribute this correlation to the differences in solubility and volatility between unalkylated and alkylated PAHs. Naphthalene and its alkylation series are more susceptible to the effects of aqueous exposure than the less-soluble PAH phenanthrene and its alkylated derivatives. These observations are consistent with the possibility of chromatographic separations on the meteorite parent bodies. We identify six CM2 meteorites with similar PAH distributions that may represent the original, unaltered organic composition of the parent body.Increased metamorphic intensity reduces the abundance of all PAHs. The thermally metamorphosed CK chondrites had no detectable levels of typical meteoritic PAHs. This observation might be explained either by a loss of PAHs caused by volatilization or by a significantly different organic content of the CK parent body.     

Development of large‐scale seismites in Upper Cretaceous fluvial sandstones in a fault‐proximal setting

Large‐scale soft‐sediment deformation structures occur within fluvial sandstone bodies of the Upper Cretaceous Wahweap Formation in the Kaiparowits basin, southern Utah, USA. These structures represent an exceptional example of metre‐scale fault‐proximal, seismogenic load structures in nearly homogenous sandstones. The load structures consist of two types: large‐scale load casts and wedge‐shaped load structures. Large‐scale load casts penetrate up to 4·5 m into the underlying sandstone bed. Wedge‐shaped load structures include metre‐scale, parallel, sub‐vertical features and decimetre‐scale features along the periphery of the large‐scale load casts or other wedge‐shaped load structures. Wedge‐shaped load structures contain well‐developed, medial cataclastic shear deformation bands. All load structures contain pervasive well‐defined millimetre‐thick to centimetre‐thick internal laminae, oriented parallel to the outside form of the load structures and asymptotic to deformation bands. Both types of load structures formed because of an inverted density profile, earthquake‐triggered liquefaction and growth of irregularities (a Rayleigh–Taylor instability) on the sandstone–sandstone erosional contact. The internal laminae and deformation bands formed during deformation and clearly demonstrate polyphase deformation, recording a transition from liquefied to hydroplastic to brittle modes of deformation. Decimetre‐scale wedge‐shaped load structures on the edge of the large‐scale load casts probably formed towards the end of a seismic event after the sediment dewatered and increased the frictional contact of grains enough to impart strength to the sands. Metre‐scale wedge‐shaped load structures were created as the tips of downward foundering sediments were driven into fractures, which widened incrementally with seismic pulsation. With each widening of the fracture, gravity and a suction effect would draw additional sediment into the fracture. Superimposed laminae indicate a secondary syndeformational origin for internal laminae, probably by flow‐generated shearing and vibrofluidization mechanisms. Large‐scale and wedge‐shaped load structures, polyphase deformation and secondary laminae may characterize soft‐sediment deformation in certain fault‐proximal settings.     

岩溶区地表水与地下水资源及环境统一评价的流域边界划分研究

岩溶地区地表水流域与地下水流域边界的分异形式有三类,即：地表分水岭与地下水流域边界在平面分布上基本一致;地表分水岭超出了地下水流域边界;地下水流域边界超出了地表分水岭。岩溶区地表水与地下水耦合流域的顶界为地表水流域的水面及下垫面,底界为浅循环潜水含水层或潜水—承压含水层下伏的隔水层顶面,在大厚度岩溶含水层分布区,可以弱岩溶发育带的顶面作为底界。其中地表水与地下水两个子系统间的次级边界,为地表水流域的下垫面。结合专门调查（勘查）评价和区域调查评价的特性,提出评价单元划分的原则及方法。这有助于在新一轮自然资源调查评价中,以流域为单元系统地开展水资源及环境调查评价,实行地表水和地下水资源及环境的统一管理。     

不同平均时间对LOPEX10资料涡动相关湍流通量计算结果影响的探讨

通过处理涡动相关系统观测的近地层湍流脉动量可以获取地—气间感热和潜热通量,然而选择不同平均时间对通量计算的结果有较大影响。采用黄土高原陆面过程野外观测试验(LOPEX10)期间获得的涡动相关系统观测资料,分析了不同平均时间对湍流通量计算的影响,并采用雷诺平均和分解方法推导了平均时间引起的通量差值的数学表达式(Flux Compensation,FC)。结果表明:(1)FC公式可以说明采用不同平均时间数据之间的关系,也可以直接计算低频涡旋对湍流通量的贡献。FC公式计算的结果与直接计算的不同平均时间通量计算之差的相关系数在0.95以上,并可以确定计算湍流通量的最佳平均时间。(2)通过采用Ogive函数确定了计算LOPEX10期间通量的最佳平均时间长度为30min,印证了利用雷诺平均和分解方法计算湍流通量补偿的准确性。(3)通过进一步的数学变换,证明了平均时间对湍流通量计算的影响直接与湍流低频变化相关,FC公式可以用来确定涡动相关观测数据的最佳平均时间,并且在获得较高时间分辨率的湍流通量数据的同时,补偿因平均时间过短而遗漏的低频信息。     

Application of sugar foam to red soils in a semiarid Mediterranean environment

The study described here involved evaluating the effects that the application of one by-product (sugar foam waste) has upon red soils in the region of La Mancha (Central Spain). In view of the fact that this is a location where this type of soil abounds, this technique has been a common practice for many years. The principal goal was to investigate the impact of this approach on some of the soil properties and, secondly, on its level of fertility. As a result, this represents an investigation into the effects that this type of waste has on some soil quality parameters. The results showed that, after the addition of by-products over 25 years, sugar foam waste is of agricultural interest mainly due to the increase in organic matter concentration (about 2%) and, to a lesser extent, by increases in calcium carbonate (more than 30%) and P (four times more). The soil pH was also found to increase slightly (1.4), while the electrical conductivity almost did not change. The properties associated with these pedological qualities therefore had a positive effect by improving nutrient availability. As a result, foams arising from sugar industries have a positive effect on soil quality and the application of such foams to soils is beneficial since the need to dispose this residue is also removed.     

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Application of kriging with external drift to estimate hydraulic conductivity from electrical-resistivity data in unconsolidated deposits near Montalto Uffugo, Italy

In the framework of various studies to characterize the aquifer at the groundwater experimental field near Montalto Uffugo, Italy, the present work estimates the spatial distribution of hydraulic conductivity of the unconsolidated deposits that underlie the area, by applying the geostatistical technique of kriging with external drift to electrical-resistivity and hydraulic-conductivity data. The reliability of the estimation method was tested by implementing a model, based on the method of cells, that simulates groundwater flow, with the estimated values of hydraulic conductivity. The results obtained indicate that the estimation method used has an acceptable degree of reliability.     

Calculating the two-dimensional magnetotelluric Jacobian in finite elements using reciprocity

To speed up the calculation of the field Jacobian for 2-D magnetoteliuric inversion using finite elements, the principle of electromagnetic reciprocity is applied. The governing relationship for the Jacobian of the field along strike is obtained by differentiating the Helmholtz equation with respect to the resistivity of each region in the finite-element mesh. The result is a similar Helmholtz equation for the Jacobian, with new sources distributed over all nodes within the parameter medium. However, according to the principle of electromagnetic reciprocity, the roles of sources and receivers are interchangeable. Utilizing reciprocity, the field values obtained from the original forward problem and for new unit sources imposed at the receivers are then utilized in the calculation of the Jacobian by simple multiplication and summation with finite-element terms at each rectangle in the mesh. For the auxiliary (across-strike) fields, the Jacobian terms are obtained by solving source vectors loaded with parabola coefficients used in the approximation to Maxwell's equations. Jacobian terms for the apparent resistivity ( p _a), the impedance phase (φ) and the vertical magnetic field ( K _zy) are then calculated utilizing the parallel- and auxiliary-field Jacobians. Comparison of Jacobian values obtained from reciprocity calculations and by differencing two forward solutions show that the reciprocity method is accurate and can be used to decrease the number of calculations required to obtain sensitivities by one to two orders of magnitude.