Arsenic anomalies in shallow Venetian Plain (Northeast Italy) groundwater

A pilot area within the Venetian Plain was selected to assess the arsenic (As) contamination of groundwater. The area represents a typical residential, industrial and agricultural organization representative of most western countries, and is also devoid of lithologies with high or anomalous As content. Hydrogeological and chemical data have been collected, the latter spatialized by a geostatistical approach. The unconfined aquifer reservoir varies from a predominantly gravel composition in the north to a sandy and silt–clay composition further south, including peat layers. The hydrochemical features of the waters are rather homogeneous, featuring low mineral content and a Ca-bicarbonate signature. In contrast, the redox state is highly variable; oxidizing conditions are predominant in the northern and coarse parts of the aquifer, whereas reducing potentials prevail in the southern and silt–clay parts. Several well waters contain arsenic in excess of drinkable limits (=10 ppb), and most of these wells are located in the southern area. A large portion of the studied area has a high probability of containing non-potable water (up to 150 ppb As). Remarkably, As “hot spots” (As > 300 ppb, up to 431 ppb) were identified at the transition from gravel to silt–clay sediments. No industrial or agricultural source of As has been found.     

Laboratory study of deep-water breaking waves

In an attempt to elucidate the mechanics of deep-water wave breaking, a variety of breaking waves, including spilling and plunging waves, of different length scales and geometries was studied. The waves were generated through wave-wave interactions using wave packets with constant-steepness components, constant-amplitude components, and also components following the Pierson-Moskowitz distribution. Wave steepening prior to breaking were found to cause an increase in the high frequency spectral slope of the wave spectrum. The slopes were correlated to the type of breaking and the intensity of the breaking. The energy loss through breaking varied with the spectral characteristics of the wave packet. On the other hand, it was also noted that, irrespective of the wave packet, the losses were from the higher frequency end of the first harmonics.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

The solubility of quartz in aqueous sodium chloride solution at 350°C and 180 to 500 bars

The solubility of quartz in 2, 3, and 4 molal NaCl was measured at 350°C and pressures ranging from 180 to 500 bars. The molal solubility in each of the salt solutions is greater than that in pure water throughout the measured pressure range, with the ratio of solubility in NaCl solution to solubility in pure water decreasing as pressure is increased. The measured solubilities are significantly higher than solubilities calculated using a simple model in which the water activity in NaCl solutions decreases either in proportion to decreasing vapor pressure of the solution as salinity is increased or in proportion to decreasing mole fraction of water in the solvent.     

Guided wave propagation in laterally varying media - II. Lg-waves in north-western Europe

Summary. Lg -wave observations at NORSAR from a sequence of explosions straddling the Central Graben in the North Sea, show that the phase is almost extinguished by passing through this structure. For models of the graben structure, based on seismic refraction experiments, with crustal thinning beneath a zone of thickened sediments, numerical modelling of Lg propagation shows very poor transmission. The inclusion of attenuation simulating the effects of scattering from faults and other complex structures further diminishes the transmittivity. The theoretical effect of a crustal pinch is to redistribute S energy over a wide range of groups velocities, a pattern that fits well with the observations.
Three components recordings at NORSAR of explosive charges fired in water covering a wide range of azimuths, show significant transverse components to the seismograms. The transverse energy builds up with travel time and for Lg is of the same order as the vertical component. These results are consistent with the theoretical prediction of progressive net transfer of energy from Rayleigh to Love modes as the wavetrain propagates through a three-dimensionally heterogeneous medium.     

VELOCITY DISPERSION OF SEISMIC WAVES*

In well velocity surveys made to calibrate Sonic (CV) Logs the calibration survey uses frequencies around 50 Hz whereas the Sonic Logging tool uses frequencies around 20 kHz. There thus exists the possibility of making a direct measure of velocity dispersion. In any one survey the disturbing factors, both instrumental and operational, will often mask any dispersive effect that might exist. Consequently this paper reports on a statistical analysis of the velocity differences resulting from calibration surveys and Sonic logs. Only Borehole Compensated Sonic Logs were used. Four areas were investigated: the North Sea, Abu Dhabi, Libya and Alaska. After rejecting logs and calibration records which were obviously in error there remained 424000 feet (about 130 km) of usable log distributed throughout 66 wells. The four areas were analysed separately and in no case was the estimated dispersion significantly different from zero. However, the mean values did correlate with lithology from (? 0.17 ± 0.18)% for the essentially carbonate section in Abu Dhabi to (+ 0.45 ± 0.25)% for the sand-shale section in Alaska, a positive sign meaning that the higher frequencies travelled faster. Except for Alaska the calibration surveys were made with a wall-clamp geophone, and for these areas amplitude measurements were made. After suitable corrections estimates of the absorption parameter Q were obtained. These varied from 20 to 200 with mean values of 63 for Libya, 70 for Abu Dhabi and 88 for the North Sea (excluding the Tertiary). If, as is usually assumed, the absorption mechanism is linear and is described by a Q which is independent of frequency, then these values would necessarily imply dispersion of several percent. As instanced above no such dispersion was observed. It is possible that the expected dispersion was compensated for by invasion of the mud filtrate into the borehole walls, but it is more likely that the absorption mechanism was substantially non-linear.     

Sources of dissolved REE in mountainous streams draining granitic rocks, Sierras Pampeanas (Córdoba, Argentina)

Stream waters draining granitic terrains from the highest part (850 to 2200 m a.s.l.) of Sierras Pampeanas (Córdoba, Argentina, ∼32°S, ∼65°W) were sampled in order to define sources and distribution of dissolved rare earth elements (REE), and to describe the geochemical processes that govern their mobility. The contribution of the regional granite to the dissolved REE pool in stream water is limited due to the physical conditions predominating in the area (i.e., steep slopes and semiarid climate). Therefore, precipitation is considered a seasonally significant source controlling REE concentration in stream water. Dissolved REE concentrations are inversely correlated with monthly precipitation and rainfall frequency. During the rainy season (i.e., the austral summer) REE concentrations in stream water are lower than during the dry season (i.e., austral winter). Such low concentrations reflect the balance between the REE input from precipitation and their removal by adsorption. In contrast, during the dry season, the longer residence time of water within fractures and colluvium determines an increased REE concentration in the base flow. Lower pH values also contribute to raise REE concentration through desorption from mineral surfaces.