A direct comparison of C and Th ages at Searles Lake, California

Thorium-230 dating on saline of the Lower Salt unit in pluvial Searles Lake, California, shows that this unit was formed between 24,500 and 32,000 years ago. The initial apparent ¹⁴C age of the lake is estimated to be about 900 years. After correcting for nonradiogenic ²³⁰Th and for the initial ¹⁴C age, excellent agreement between ²³⁰Th and ¹⁴C ages is obtained. The reliability of ²³⁰Th dating on salt deposit opens a new way for continuation of absolute chronology below the Lower Salt in Searles Lake.     

Performance assessment of three convective parameterization schemes in WRF for downscaling summer rainfall over South Africa

Austral summer rainfall over the period 1991/1992 to 2010/2011 was dynamically downscaled by the weather research and forecasting (WRF) model at 9 km resolution for South Africa. Lateral boundary conditions for WRF were provided from the European Centre for medium-range weather (ECMWF) reanalysis (ERA) interim data. The model biases for the rainfall were evaluated over the South Africa as a whole and its nine provinces separately by employing three different convective parameterization schemes, namely the (1) Kain–Fritsch (KF), (2) Betts–Miller–Janjic (BMJ) and (3) Grell–Devenyi ensemble (GDE) schemes. All three schemes have generated positive rainfall biases over South Africa, with the KF scheme producing the largest biases and mean absolute errors. Only the BMJ scheme could reproduce the intensity of rainfall anomalies, and also exhibited the highest correlation with observed interannual summer rainfall variability. In the KF scheme, a significantly high amount of moisture was transported from the tropics into South Africa. The vertical thermodynamic profiles show that the KF scheme has caused low level moisture convergence, due to the highly unstable atmosphere, and hence contributed to the widespread positive biases of rainfall. The negative bias in moisture, along with a stable atmosphere and negative biases of vertical velocity simulated by the GDE scheme resulted in negative rainfall biases, especially over the Limpopo Province. In terms of rain rate, the KF scheme generated the lowest number of low rain rates and the maximum number of moderate to high rain rates associated with more convective unstable environment. KF and GDE schemes overestimated the convective rain and underestimated the stratiform rain. However, the simulated convective and stratiform rain with BMJ scheme is in more agreement with the observations. This study also documents the performance of regional model in downscaling the large scale climate mode such as El Niño Southern Oscillation (ENSO) and subtropical dipole modes. The correlations between the simulated area averaged rainfalls over South Africa and Nino3.4 index were ?0.66, ?0.69 and ?0.49 with KF, BMJ and GDE scheme respectively as compared to the observed correlation of ?0.57. The model could reproduce the observed ENSO-South Africa rainfall relationship and could successfully simulate three wet (dry) years that are associated with La Niña (El Niño) and the BMJ scheme is closest to the observed variability. Also, the model showed good skill in simulating the excess rainfall over South Africa that is associated with positive subtropical Indian Ocean Dipole for the DJF season 2005/2006.     

Period–luminosity relations for red supergiant variables – I.The calibration

We present CCD photometry of red supergiant long-period variables (LPVs) in the Per OB1 association, the Large Magellanic Cloud (LMC) and M33. The photometry was obtained in the Kron–Cousins R and I bandpasses and in a narrow bandpass ( λ ₀=8250 Å, FWHM=300 Å) chosen to avoid TiO bands in the spectral energy distribution of the LPVs. Because the strength of the TiO bands varies greatly with temperature, which varies with the phase of an LPV, avoiding TiO reduces the amplitude of the photometric variations seen in LPVs. The result is a lower dispersion and a well defined period–luminosity (PL) relation.
For the LMC sample we find an rms dispersion of 0.27 mag in the narrow-band PL relation and slightly larger dispersions for the LPVs in Per OB1 and M33. This dispersion is comparable to that of the Cepheid PL relation at similar wavelengths. Adopting a distance modulus of 18.5±0.1 mag for the LMC, we obtain distance moduli of 11.68±0.15 mag for Per OB1 and 24.85±0.13 mag for M33. These distances agree well with those based on main sequence fitting for Per OB1 and the Cepheid distance for M33. Since LPVs are ∼ 5 times more common than Cepheids and have a well defined PL relation, LPVs provide a promising method for estimating Galactic and extra galactic distances.     

Late Quaternary sea‐level change and evolution of Belfast Lough,Northern Ireland: new offshore evidence and implications for sea‐level reconstruction

The interplay of eustatic and isostatic factors causes complex relative sea‐level (RSL) histories, particularly in paraglacial settings. In this context the past record of RSL is important in understanding ice‐sheet history, earth rheology and resulting glacio‐isostatic adjustment. Field data to develop sea‐level reconstructions are often limited to shallow depths and uncertainty exists as to the veracity of modelled sea‐level curves. We use seismic stratigraphy, 39 vibrocores and 26 radiocarbon dates to investigate the deglacial history of Belfast Lough, Northern Ireland, and reconstruct past RSL. A typical sequence of till, glacimarine and Holocene sediments is preserved. Two sea‐level lowstands (both max. ?40 m) are recorded at c. 13.5 and 11.5k cal a bp . Each is followed by a rapid transgression and subsequent periods of RSL stability. The first transgression coincides temporally with a late stage of Meltwater Pulse 1a and the RSL stability occurred between c. 13.0 and c. 12.2k cal a bp (Younger Dryas). The second still/slowstand occurred between c. 10.3 and c. 11.5k cal a bp . Our data provide constraints on the direction and timing of RSL change during deglaciation. Application of the Depth of Closure concept adds an error term to sea‐level reconstructions based on seismic stratigraphic reconstructions.     

The Development of Laser Ablation ICP-MS and Calibration Strategies: Examples from the Analysis of Trace Elements in Volcanic Glass Shards and Sulfide Minerals

This contribution presents a review of the recent developments in laser ablation inductively coupled plasma-mass spectrometry. We describe the important developments which have occurred in the laser systems used, leading to a spatial resolution of around 20 (im, and give an overview of the major instrument developments which have affected the geological applications of laser ablation ICP-MS. We describe the calibration of laser ablation for the analysis of trace elements in two different matrices: volcanic glass shards and sulfide minerals. We show how single glass shards can be analysed using the National Institute of Standards and Technology (NIST) glass certified reference materials for calibration and demonstrate the effect of using single spot analyses compared to rastering of the calibration sample. We show the importance of inter-shard variation and demonstrate that averaged single shard analyses produce data which compare well with bulk analyses. The calibration of the laser system for sulfide mineral analysis is discussed and two different strategies are proposed, one using spiked pressed powder pellets of sulfides and the other metal reference materials. We present conclusions and recommendations for the calibration of laser ablation ICP-MS instruments.     

Potassium‐argon dates from the Arltunga Nappe complex,northern territory

Twenty‐four mineral separates from the Arunta Complex, four from the metamorphosed Heavitree Quartzite (White Range Quartzite), and one whole rock sample of metamorphosed Bitter Springs Formation, all from the western part of the White Range Nappe of the Arltunga Nappe Complex, and two samples from the autochthonous basement west of the nappe have been dated by the K‐Ar method. The samples from the basement rocks form two groups. Those in the southern or frontal part of the nappe are of Middle Proterozoic (Carpentarian) age (1660–1368 m.y.), determined on hornblende, biotite, and muscovite. In the northern or rear part of the nappe, all but one of the muscovite samples and two biotites are of Middle Silurian to Early Carboniferous age (431–345 m.y.); the remainder of the biotite dates range from 1775 to 548 m.y. (including the two samples from the autochthon), and two hornblendes gave dates of 1639 and 2132 m.y. respectively. All the muscovite samples from the Heavitree Quartzite, and the whole rock sample from the Bitter Springs Formation gave Early to Middle Carboniferous dates (358–322 m.y.). The findings support the identification of the White Range Quartzite as the metamorphosed part of the Heavitree Quartzite, which in turn supports the interpretation of the structure of the area as a large, basement‐cored fold nappe. In addition, they date the time of the Alice Springs Orogeny as pre‐Late Carboniferous, which agrees with fossil evidence from elsewhere in the area. The Alice Springs Orogeny was accompanied by widespread greenschist facies meta‐morphism that progressively metamorphosed the Heavitree Quartzite and Bitter Springs Formation, and retrogressively metamorphosed the Arunta Complex. However, the basement rocks in the southern part of the nappe escaped this metamorphism and retain a Middle Proterozoic age, thus dating the time of the Arunta Orogeny in this region as Carpentarian or older.     

Computer-composite mapping for geologists

A computer program for overlaying maps has been tested and evaluated as a means for producing geologic derivative maps. Four maps of the Sugar House Quadrangle, Utah, were combined, using the Multi-Scale Data Analysis and Mapping Program, in a single composite map that shows the relative stability of the land surface during earthquakes. Computer-composite mapping can provide geologists with a powerful analytical tool and a flexible graphic display technique. Digitized map units can be shown singly, grouped with different units from the same map, or combined with units from other source maps to produce composite maps. The mapping program permits the user to assign various values to the map units and to specify symbology for the final map. Because of its flexible storage, easy manipulation, and capabilities of graphic output, the composite-mapping technique can readily be applied to mapping projects in sedimentary and crystalline terranes, as well as to maps showing mineral resource potential.     

The Darwin Rise demise: the western Pacific guyot heights trace the trans-Pacific Mendocino fracture zone

The Darwin Rise has been proposed so many times and in so many forms and places that the time has come to make a more comprehensive examination of the region. Lying on the NW Pacific Plate between the Geisha Guyots, the Mid-Pacific Mountains, the equator, and the trenches, the region is roughly bounded by magnetic anomaly M20 (147 Ma). It was subjected to a massive outpouring of lava about 105 to 120 Ma, which created the guyots and seamounts in that region. Guyots are excellent tools for studying events of long ago because they eroded in the same lowstand in the Cretaceous and guyot relief, therefore, is a surrogate for paleo-sealevel. The relief is derived by subtracting the break depth of the summit plateau of a guyot from the regional depth. Guyot relief would necessarily be less in the center than to the periphery if the feature formed on a pre-existing rise, as has been postulated. The existence of a paleo-Darwin Rise would give concentric contours for the region in question. Of the sixty guyots used in this study, thirty-seven of these guyots were surveyed using SASS multibeam in the Marcus-Wake seamount group. Twenty-three guyots were surveyed using random track single-beam sonar surveys. An entirely different scenario is shown. Data revealed a major fracture passing through the area coevally or after the guyots formed. Because the depths to the summit are not the same now, vertical tectonics occurred after subaerial erosion. This means the fracture formed during and after the erosion (roughly 105 Ma) and influenced the normal sequence of events in guyot formation. Depending on how one deciphers trends through the Hess Rise morass, SASS bathymetry shows a continuation of the Surveyor/Mendocino fracture zone swarm inside the M20 region to the NE of these data. The fracture swarm continues to the western Pacific trench system. Based on this information, if the Darwin Rise ever existed, it had to have done so elsewhere.     

Refractory metal nuggets within presolar graphite: First condensates from a circumstellar environment

Transmission electron microscope (TEM) investigations have revealed Os, Ru, Mo‐rich refractory metal nuggets within four different presolar graphites, from both the high‐density (HD) Murchison (MUR) and low‐density (LD) Orgueil (ORG) fractions. Microstructural and chemical data suggest that these are direct condensates from the gas, rather than forming later by exsolution. The presolar refractory metal nugget (pRMN) compositions are variable (e.g., from 8 < Os atom% < 77), but follow the same chemical fractionation trends as isolated refractory metal nuggets (mRMNs) previously found in meteorites (Berg et al. 2009). From these compositions one can infer a temperature of last equilibration with the gas of 1405–1810 K (e.g., Berg et al. 2009 at approximately 100 dyne cm^?2 pressure), which implies that the host graphites form over roughly the same range (in agreement with predictions) and that the pRMNs are chemically isolated from the gas when captured by graphite. Further, the pRMN compositions give evidence that HD graphites form at a higher T than LD ones. Chemical and phase similarities with the isolated mRMNs suggest that the mRMNs also condense directly from a gas, although from the early solar nebula rather than a presolar environment. Although the pRMNs themselves are too small for detection of isotopic anomalies, NanoSIMS isotopic measurements of their host graphites confirm a presolar origin for the assemblages. The two pRMN‐containing LD graphites show evidence of a supernova (SN) origin, whereas the stellar origins of the pRMNs in HD graphite are unclear, because only less‐diagnostic ¹²C enrichments are detectable (as is commonly true for HD graphites).