Saturation of groundwaters with respect to minerals of the host rocks

Calculations of the saturation of groundwaters with respect to minerals of the rocks hosting these waters indicate that most of the analyzed groundwaters were saturates with respect to calcite, dolomite, and quartz. Brines of chloride-calcic composition were determined to be saturated with respect to calcite, whereas brines of chloride-sodic composition are saturated with respect to dolomite and quartz. The solution was simultaneously saturated with respect to six minerals for the association ankerite-calcite-dolomite-pyrite-quartz-strontianite. An increase in the number of minerals with respect to which solution is saturated is correlated with an increase in the diversity of types of groundwaters and an increase in the runoff rate. The paper proposes possible avenues for searches for relations between hydrogeological and geochemical parameters that make it possible to adapt the thermodynamic models to real geological-hydrogeological conditions. The research was centered on the testing of groundwaters for their saturation with respect to minerals of the rocks hosting these waters. This parameter plays a significant part in forming the geochemical type of natural waters because it reflects the crystallization of a mineral from a solution and, consequently, the removal of an element from the aqueous solution.     

Influence of wind upon water quality in Liverpool Bay

Comprehensive distribution patterns of physical and chemical characteristics have been obtained from a series of cruises in Liverpool Bay. The marked feature of these distributions was their temporal variability, suggesting that the surface residual circulation is also temporally variable. The influence of wind stress upon the circulation pattern and hence water quality of this sea area is illustrated.     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.     

Superposition of gold mineralisation on pre‐existing carbonate alteration: Structural evidence from the Mulgarrie gold deposit,Yilgarn Craton

Carbonate alteration at the Mulgarrie gold mine in the Eastern Goldfields of Western Australia, is represented by porphyroblasts, veins and pervasive, texturally destructive, carbonatisation. Two foliations, S_1M and S_2M, were produced by two separate deformation events at the mine‐scale, D_1M and D_2M. D_1M and D_2M both occurred in response to regional D₂ tectonism. Carbonate alteration was the product of two separate episodes of fluid ingress: the earlier produced magnesite and the latter Fe‐dolomite. Both periods of carbonate alteration occurred pre‐ to early syn‐D_2M, when mafic to ultramafic komatiitic rocks reacted with fluids that moved along regional faults and pre‐date the alteration associated with regional peak metamorphism. Gold at Mulgarrie overprints pre‐ and late syn‐D₂ quartz veins in zones of massive carbonate alteration, suggesting it has a late‐ to post‐D₂ timing. This late timing agrees with the generally accepted syn‐D₃ (and younger) age for gold mineralisation in the Eastern Goldfields. We suggest that carbonate alteration at Mulgarrie is not a product of the hydrothermal event responsible for the gold mineralisation. Rather, the different relative timing of magnesite, Fe‐dolomite and gold indicates there were two carbonate‐producing fluid systems and a fluid transporting the gold overprinted these. Similarly, early carbonate alteration may play a role in localising auriferous vein deposits throughout the Yilgarn and other Archaean cratons.     

Modelling changes in the epidemic range of Southern Pine Beetle using temperature and objective moisture indicators

Summary This report details as statistical model that relates changes in areal coverage of the Southern Pine Beetle (Dendroctonus frontalis Zimm.) to a multivariate combination of temperature and moisture status indices. It is applicable to larger geographic areas than our previous work (Michaels 1984). Performance in a true test (predictive) mode detected the algebraic sign of major coverage changes in a highly significant fashion. The results are purely correlative, rather than causative.This report describes a test-proven tool that can be used by planners to determine whether coverage will change, based upon easily accessed climatic data. An example of its application is provided.

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Zusammenfassung Diese Untersuchung führt ein statistisches Modell aus, welches das flächenmäßige Auftreten vonDendroctonus frontalis Zimm. mit einer Kombination von Temperaturund Feuchteverhältnisindikatoren in Verbindung bringt. Es kann für größere Gebiete verwendet werden als ein früher vorgestelltes (Michaels 1984). Die Anwendung zur Vorhersage zeigte in einem Test gute Übereinstimmung mit der tatsächlich aufgetretenen Richtung der Veränderung in der Verbreitung des Käfers. Die Ergebnisse zeigen Korrelationen, keine Kausalitäten auf.Es wird also ein Werkzeug für den Planer vorgestellt, mit dem die Verbreitungsänderung mit Hilfe leicht zugänglicher klimatologischer Daten bestimmt werden kann. Ein Anwendungsbeispiel wird näher ausgeführt.

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With 5 Figures     

Meteorological excitation of the annual polar motion

Summary. Numerous studies have indicated that the annual term in the polar motion cannot be explained in any detail by meteorological/hydrological excitation and no reasonable alternative excitations have been put forward. Part of the problem has been that the hydrostatic adjustment of the oceans to the atmospheric pressure changes has traditionally been computed using the inverse barometer approach. This approach does not properly model the gravitational interaction between the atmosphere and oceans, and the inverse barometer theory is modified in this paper to account for this properly. The information necessary to compute the ocean tide and polar excitation caused by any change in the atmospheric pressure pattern is presented. The results of the application of this theory to two global atmospheric pressure data sets are examined and compared to results of other workers.
It is concluded that the atmosphere is observed well enough to answer the question of the annual excitation of polar motion and it is argued that the ground water excitation is the component with the largest error and remains the chief obstacle to the successful solution of this problem.     

Meteorological and synoptic aspects of the formation and evolution of the Novorossiysk Bora

The genetic and synoptic classifications of the Novorossiysk Bora are created using the data of daily observations at the Novorossiysk meteorological station and other available synoptic information. Obtained are the quantitative criteria of these classifications, and on this base worked out are the basic scenarios of the generation and evolution of this dangerous phenomenon on the Black Sea coast of Russia. According to the genetic classification, the Bora was divided into four types: frontal, air-mass, monsoon, and gravity. Quantitative criteria worked out for each type can be used for the more accurate forecast of this destructive phenomenon near Novorossiysk. According to the synoptic classification, four classes were distinguished: Azores, North Atlantic, Siberian, and Arctic.