Carbonate equilibria in hydrothermal systems: First ionization of carbonic acid in NaCl media to 300°C

The ionization quotients of aqueous carbon dioxide (carbonic acid) have been precisely determined in NaCl media to 5 m and from 50° to 300°C using potentiometric apparatus previously developed at Oak Ridge National Laboratory. The pressure coefficient was also determined to 250°C in the same media. These results have been combined with selected information in the literature and modeled in two ways to arrive at the best fits and to derive the thermodynamic parameters for the ionization reaction, including the equilibrium constant, activity coefficient quotients, and pressure coefficients. The variation with temperature of the two fundamental quantities $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ and $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ were examined along the saturation vapor pressure curve and at constant density. The results demonstrated again that for reactions with minimal electrostriction changes the magnitudes and variations of $\text{Δ}\text{C}\text{?}{}^{\mathrm{o}}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}{}^{\mathrm{o}}$ with temperature are small and, in addition, $\text{Δ}\text{C}\text{?}{}_{\mathrm{p}}$ and $\text{Δ}\text{V}\text{?}$ are approximately independent of salt concentration.The results have also been applied to an examination of the solubility of calcite as a function of pH (in a given NaCl medium) for the neutral to acidic region both for systems with fixed CO₂ pressure and systems where the calcium ion concentration equals the concentration of carbon. The pH of saturated solutions of calcite with P_CO2 of 12 bars increases from 5.1 to 5.5 between 100° and 300°C.     

Decay of a highly eccentric satellite

The re-entry phase of a highly eccentric satellite is discussed. Numerical simulations allowing the prediction of the exact date of re-entry of a highly eccentric satellite are exposed.It is shown that under very particular circumstances the life of the satellite can be extended by a few days. The number of final revolutions of the rapidly contracting orbit depends critically on the air density between 70 km and 100 km.Re-entry of the European scientific satellite HEOS-1 predicted for 28 October, 1975 is near such a situation.     

Über den Eisengehalt von Alumosilikaten aus Quarzknauern

Zusammenfassung Der Eisengehalt von Andalusiten und Disthenen aus Quarzknauern im Gebiet des Ötztaler—Stubaier Altkristallins wurde regional untersucht. Der Gehalt and Gesamteisen in primären Disthen liegt zwischen 0,17 und 0,22 Gew.% Fe₂O₃, während primäre Andalusite zwischen 0,26 und 1,93 Gew.% Fe₂O₃ schwanken. Dieser Unterschied in den Andalusiten wird auf ein wechselndes Angebot von Fe₂O₃ aus dem Nachbargestein der Knauern zurückgeführt.Ein Zusammenhang zwischen dem Eisengehalt der Andalusite und den verschiedenen Umwandlungsstadien Andalusit—Disthen konnte nicht nachgewiesen werden.

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On the iron content of alumosilicates in quartz nodules

Summary A determination of the regional distribution of the ironcontent of andalusites and kyanites in quartz-segregations of the Oetztal—Stubai crystalline complex gave values of 0.17–0.22% for the total iron in primary kyanite and 0.26–1.93% in andalusite. This difference is probably due to a variation in the Fe₂O₃-content in the country rocks of the quartz veins. No relationship between the iron-content in andalusite and the different stages of transformation from andalusite to kyanite could be established.

     

Ecological-geochemical assessment of the state of the Volga source of water supply to Moscow

Long-term observational data (1992?C2009) on heavy metal (Cu, Zn, Pb, Cr, Ni, V, Mo, Co, Fe, and Mn) content of different links in the Ivankovo Reservoir ecosystem are used to consider the regularities in the distribution and behavior of heavy metals in the system anthropogenic pollution sources-reservoir and its drainage area, thus enabling the assessment of the pollution level of the Volga Source of water supply to Moscow.     

On the instability of weakly radially anisotropic star clusters

We discuss contradictions existing in the literature in the problem on the stability of collisionless spherical stellar systems, which are the simplest anisotropic generalization of the well-known polytropic models. On the one hand, calculations of the growth rates within the framework of a linear stability theory and N-body simulations suggest that these systems should become stable when the parameter s characterizing the degree of anisotropy of the stellar velocity distribution becomes lower than some critical value s _crit > 0. On the other hand, according to Palmer and Papaloizou, the growth rate should be nonzero up to the isotropic limit s = 0. Using our method of determining the eigenmodes of stellar systems, we show that even though the mode growth rates in weakly radially anisotropic systems of this type are nonzero, they are exponentially small, i.e., decrease as γ ∝ exp(−a/s) when s → 0. For slightly radially anisotropic systems with a finite lifetime, this actually implies stability.     

PEDOGENESIS IN LATE PREHISTORIC INDIAN MOUNDS,UPPER MISSISSIPPI VALLEY

Inceptisols are developed on silt loam, loam, and sandy loam Indian mounds at the Keller Mound Group and Bluff Top Mound in northeastern Iowa. The mounds date to the Allamakee Phase of the Late Woodland Period (ca. 1650–1250 B.P.) and are built with fill obtained from the A, E, and upper B horizons of pre-existing soils (Alfisols). Differences in the morphologic and chemical characteristics of soils on different mounds are attributed to textural differences of the mounds' fill. Coarse-textured mound fill is pedogenically altered at a faster rate than fine-textured fill, but total carbon percentage of the A horizon attains a steady state faster in fine-textured mound fill. Total phosphorus content is used to determine from which horizons of pre-existing soils the specific layers of mound fill originated. Rates and pathways of pedogenesis in mound fill may not provide good analogues for the early stages of soil development in materials that have not undergone previous weathering and subsequent modification by humans. Nevertheless, mound soils are useful benchmarks for some pedologic studies since they provide time lines for evaluating minimum rates for development of argillic and albic horizons, as well as attainment of the Alfisol order.     

Principles of tabling

The mechanism of concentration on the shaking table is discussed and a fresh attempt is made to obtain the theoretical model describing the velocity of a fluid in depth and time when in contact with a symmetrically reciprocating surface.The significance of the many design and operational variables and their interrelationships are examined. The various areas where the shaking table plays its role are then considered.The relevant features of micropanner, superpanner and the subsequent macropanner and pulsepanner are also treated since they all, like the shaking table, have the differential motion in common.     

Influence of wind upon water quality in Liverpool Bay

Comprehensive distribution patterns of physical and chemical characteristics have been obtained from a series of cruises in Liverpool Bay. The marked feature of these distributions was their temporal variability, suggesting that the surface residual circulation is also temporally variable. The influence of wind stress upon the circulation pattern and hence water quality of this sea area is illustrated.     

The role of prior model calibration on predictions with ensemble Kalman filter

This paper, based on a real world case study (Limmat aquifer, Switzerland), compares inverse groundwater flow models calibrated with specified numbers of monitoring head locations. These models are updated in real time with the ensemble Kalman filter (EnKF) and the prediction improvement is assessed in relation to the amount of monitoring locations used for calibration and updating. The prediction errors of the models calibrated in transient state are smaller if the amount of monitoring locations used for the calibration is larger. For highly dynamic groundwater flow systems a transient calibration is recommended as a model calibrated in steady state can lead to worse results than a noncalibrated model with a well-chosen uniform conductivity. The model predictions can be improved further with the assimilation of new measurement data from on-line sensors with the EnKF. Within all the studied models the reduction of 1-day hydraulic head prediction error (in terms of mean absolute error [MAE]) with EnKF lies between 31% (assimilation of head data from 5 locations) and 72% (assimilation of head data from 85 locations). The largest prediction improvements are expected for models that were calibrated with only a limited amount of historical information. It is worthwhile to update the model even with few monitoring locations as it seems that the error reduction with EnKF decreases exponentially with the amount of monitoring locations used. These results prove the feasibility of data assimilation with EnKF also for a real world case and show that improved predictions of groundwater levels can be obtained.