Size scales over which ordinary chondrites and their parent asteroids are homogeneous in oxidation state and oxygen-isotopic composition

Literature data demonstrate that on a global, asteroid-wide scale (plausibly on the order of 100 km), ordinary chondrites (OC) have heterogeneous oxidation states and O-isotopic compositions (represented, respectively, by the mean olivine Fa and bulk Δ¹⁷O compositions of equilibrated samples). Samples analyzed here include: (a) two H5 chondrite Antarctic finds (ALHA79046 and TIL 82415) that have the same cosmic-ray exposure age (7.6 Ma) and were probably within ∼1 km of each other when they were excavated from the H-chondrite parent body, (b) different individual stones from the Holbrook L/LL6 fall that were probably within ∼1 m of each other when their parent meteoroid penetrated the Earth’s atmosphere, and (c) drill cores from a large slab of the Estacado H6 find located within a few tens of centimeters of each other. Our results indicate that OC are heterogeneous in their bulk oxidation state and O-isotopic composition on 100-km-size scales, but homogeneous on meter-, decimeter- and centimeter-size scales. (On kilometer size scales, oxidation state is heterogeneous, but O isotopes appear to be homogeneous.) The asteroid-wide heterogeneity in oxidation state and O-isotopic composition was inherited from the solar nebula. The homogeneity on small size scales was probably caused in part by fluid-assisted metamorphism and mainly by impact-gardening processes (which are most effective at mixing target materials on scales of ?1 m).     

Investigation of Failure Mechanisms and Migration of Organic Chemicals at Wilsonville, Illinois

Ground water contamination was discovered in 1981 in a monitoring well at the Earthline disposal facility near Wilsonville, Illinois. Organic chemicals had migrated at a rate 100 to 1000 times greater than predicted when the site received its permit to operate in 1978. Postulated failure mechanisms included migration through previously unmapped permeable zones, subsidence of an underground mine, organic-chemical and clay-mineral interactions, acid-mine drainage and clay interactions, trench-cover settlement, and erosion.
In this investigation, the Illinois State Geological Survey found the primary reason for the rapid migration: the presence of previously undetermined fractures and joints in glacial till. The inaccurate predictions of hydraulic conductivity were based on laboratory-determined values that did not adequately measure the effects of fractures and joints on the transit time calculations. Field-measured hydraulic conductivity values were generally 10 to 1000 times greater than their laboratory-measured counterparts, thus largely accounting for the discrepancy between predicted and actual migration rates in the transit time calculations. The problem was compounded, however, by the burial of liquid wastes and by trench covers that allowed excess surface runoff to enter the trenches. Organic-chemical and clay-mineral interactions may also have exacerbated the problem in areas where liquid organic wastes were buried.     

On the existence of lateral relative motions on Mars

A preliminary study of photomosaic maps of Mars suggests that large lateral relative motions of a relatively thick lithosphere may have occurred. Transform faults (at two different stages of their evolution) are described, together with a possible triple junction. Diffuse diverging plate boundaries can be found, whereas converging ones remain a problem.     

Effects of alteration on element distributions in archean tholeiites from the Barberton greenstone belt,South Africa

Major and trace element and modal analyses are presented for unaltered, epidotized, and carbonated tholeiite flows from the Barberton greenstone belt. Au, As, Sb, Sr, Fe⁺³, Ca, Br, Ga, and U are enriched and H₂O, Na, Mg, Fe⁺², K, Rb, Ba, Si, Ti, P, Ni, Cs, Zn, Nb, Cu, Zr, and Co are depleted during epidotization. CO₂, H₂O, Fe⁺², Ti, Zn, Y, Nb, Ga, Ta, and light REE are enriched and Na, Sr, Cr, Ba, Fe⁺³, Ca, Cs, Sb, Au, Mn, and U are depleted during carbonization-chloritization. The elements least affected by epidotization are Hf, Ta, Sc, Cr, Th, and REE; those least affected by carbonization-chloritization are Hf, Ni, Co, Zr, Th, and heavy REE. Both alteration processes can significantly change major element concentrations (and ratios) and hence caution should be used in distinguishing tholeiites from komatiites based on major elements alone. The amount of variation of many of the least mobile trace elements in the altered flows is approximately the same as allowed by magma model calculations. Hence, up to about 10% carbonization and 60% epidotization of tholeiite do not appreciably affect the interpretation of trace-element models for magma generation.     

Results of the solar constant experiment onboard Spacelab 1

A cavity type absolute radiometer was flown on Spacelab 1 in December 1983. We obtain a value of the solar constant of 1361.5 W m^–2 with an estimated accuracy of ±2.3 W m^–2 or 0.17%. When comparing this with other recent determinations, we find discrepancies which we consider indicative of metrological problems in present day absolute radiometry.     

PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia)

The results of the first study of the PGE distribution in deformed lherzolites of the Udachnaya kimberlite pipe (Yakutia) are presented here. The complex character of evolution of the PGE composition in the Deformed lherzolites is assumed to be the result of silicate metasomatism. At the first stage, growth in the amount of clinopyroxene and garnet in the rock is accompanied by a decrease in the concentration of the compatible PGE (Os, Ir). During the final stage, the rock is enriched with incompatible PGE (Pt, Pd) and Re possible due to precipitation of submicron-sized particles of sulfides in the interstitial space of these mantle rocks.     

Field-Scale Evaluation of Bioaugmentation Dosage for Treating Chlorinated Ethenes

A field demonstration was performed to evaluate the impacts of bioaugmentation dosage for treatment of chlorinated ethenes in a sandy-to-silty shallow aquifer. Specifically, bioaugmentation using a commercially available Dehalococcoides (DHC)-containing culture was performed in three separate groundwater recirculation loops, with one loop bioaugmented with 3.9 × 10¹¹ DHC, the second loop bioaugmented with 3.9 × 10¹² DHC, and the third loop bioaugmented with 3.9 × 10¹³ DHC. Groundwater monitoring was performed to evaluate DHC growth and migration, dechlorination rates, and aquifer geochemistry. The loop inoculated with 3.9 × 10¹² DHC showed slower dechlorination rates and DHC migration/growth compared with the other loops. This relatively poor performance was attributed to low pH conditions. Results for the loops inoculated with 3.9 × 10¹¹ and 3.9 × 10¹³ DHC showed similar timeframes for dechlorination, as evaluated at a monitoring well approximately 10 feet downgradient of the DHC injection well. Application of a recently developed one-dimensional bioaugmentation fate and transport screening model provided a reasonable prediction of the data in these two loops. Overall, these results suggest that increasing bioaugmentation dosage does not necessarily result in decreased dechlorination timeframes in the field. The ability to predict results suggests that modeling potentially can serve as an effective tool for determining bioaugmentation dosage and predicting overall remedial timeframes.     

Surface water–groundwater interaction and chemistry in a mineral-armored hydrothermal outflow channel, Yellowstone National Park, USA

Small quantities of groundwater interact with hydrothermal surface water to drive in-stream geochemical processes in a silica-armored hot-spring outflow channel in Yellowstone National Park, USA. The objective of this study was to characterize the hydrology and geochemistry of this unique system in order to (1) learn more about the Yellowstone Plateau’s subsurface water mixing between meteoric and hydrothermal waters and (2) learn more about the chemical and physical processes that lead to accumulation of streambed cements, i.e., streambed armor. A combination of hydrological, geochemical, mineralogical, microscopic, and petrographic techniques were used to identify groundwater and surface-water exchange. Interaction could be identified in winter because of differences in surface water and groundwater composition but interaction at other times of the year cannot be ruled out. Dissolved constituents originating from groundwater (e.g., Fe(II) and Mg) were traced downstream until oxidation and/or subsequent precipitation with silica removed them, particularly where high affinity substrates like cyanobacterial surfaces were present. Because the stream lies in a relatively flat drainage basin and is fed mainly by a seasonally relatively stable hot spring, this system allowed study of the chemical processes along a stream without the obscuring effects of sedimentation.     

Where Are the Women? Accounting for Discrepancies in Female Doctorates in U.S. Geography

Although there have been noticeable improvements in recent years, geography continues to be a predominantly male discipline. The percentage of women receiving PhDs in geography has tracked lower than the U.S. average of female PhDs. Previous studies of women's contribution to geography have focused on personal accounts or on the study of some of the most prominent practitioners, with a few studies using basic data on PhDs awarded and Association of American Geographers membership to determine trends. This article provides a comprehensive overview of doctoral degrees in geography by gender, over time, and across all universities in the United States by examining an alternative database, that of doctoral dissertations. The analysis yields three separate types of results. First, historical and contemporary variations among U.S. universities are examined. Second, data indicate that male and female doctoral students differ in the sex of their advisor. Third, a simple regression model explains some of the discrepancies in the proportion of female doctoral students by department. In sum, this article provides a comprehensive empirical study of the factors that might contribute to the continued disparities in female doctoral students in geography.