TitaniQ under pressure: the effect of pressure and temperature on the solubility of Ti in quartz

Quartz and rutile were synthesized from silica-saturated aqueous fluids between 5 and 20 kbar and from 700 to 940°C in a piston-cylinder apparatus to explore the potential pressure effect on Ti solubility in quartz. A systematic decrease in Ti-in-quartz solubility occurs between 5 and 20 kbar. Titanium K-edge X-ray absorption near-edge structure (XANES) measurements demonstrate that Ti⁴⁺ substitutes for Si⁴⁺ on fourfold tetrahedral sites in quartz at all conditions studied. Molecular dynamic simulations support XANES measurements and demonstrate that Ti incorporation onto fourfold sites is favored over interstitial solubility mechanisms. To account for the P–T dependence of Ti-in-quartz solubility, a least-squares method was used to fit Ti concentrations in quartz from all experiments to the simple expression

Variations of Pb in a mine-impacted tropical river,Taxco, Mexico: Use of geochemical,isotopic and statistical tools

The potential environmental threat from Pb in Mexican rivers impacted by historic mining activities was studied using geochemical, isotopic and statistical methods. Lead geochemical fractionation and factor analysis of fractionated and total Pb indicate that anthropogenic sources have contributed significantly to Pb concentrations, while natural sources have contributed only small amounts. The analyses also indicate that two main processes are controlling the total Pb variation throughout the year in both rivers: erosion with discharge processes, and proportional dilution related to differences in grain-size distribution processes. Bio-available Pb in riverbed sediments was greater than 50% in 80% of the sampling stations indicating a high potential environmental risk, according to the risk assessment criteria (RAC). Nevertheless, based on the environmental chemistry of Pb and on multivariate statistical analysis, these criteria did not apply in this particular case. Significant differences (p < 0.05) in total Pb concentrations (from 50 to 5820 mg kg⁻¹) and in the geochemical fractionation were observed as a function of seasonality and location along the river flow path. In the Cacalotenango and Taxco rivers, the highest concentrations of total Pb were found at stations close to tailings during the rainy and post-rainy seasons. The geochemistry of Pb was mainly controlled, during the dry and post-rainy seasons by the organic matter and carbonate content, and in the rainy season by hydrological conditions (e.g., the increase in river flux), hydrological basin erosion, and the suspended solids concentration. Isotopic analyses of the ²¹⁰Pb/²¹⁴Pb ratio showed three processes in the Cacalotenango and Taxco rivers. First, the accumulation of atmospheric excess ²¹⁰Pb, favoured during calmer hydrodynamic conditions in the river basin commonly during dry periods, is recorded by a ²¹⁰Pb/²¹⁴Pb ratio of >1. In the case of the Cacalotenango river, ²¹⁰Pb did show preferential accumulation in sediments. Second, a ²¹⁰Pb/²¹⁴Pb ratio of <1 in some samples might be indicating (a) the presence of eroded material from weathered tailings with similar ²¹⁰Pb depletion (probably by secular disequilibrium caused by weathering or mining processes, which was observed in both rivers), or (b) preferential transport of Pb and sediments during high energy events (e.g., flow increase, as is the case of Taxco river). Third, no significant changes in the ²¹⁰Pb/²¹⁴Pb ratio might be reflecting a situation where mining material is not entering the system, or where hydrodynamic changes throughout the year of equal magnitude allow the system to reach a new equilibrium for the ²¹⁰Pb/²¹⁴Pb ratio. Finally, based on these results it is recommended that inhabitants of the studied area avoid using water from the Cacalotenango river in the rainy and post-rainy seasons, and to take precautions for its use in the dry season, such as allowing suspended material to settle before use, and that they should avoid use of Taxco river water at all times.     

Concurrent Drainage Network Rendering for Automated Pen‐and‐ink Style Landscape Illustration

Pen‐and‐ink style geomorphological illustrations render landscape elements critical to the understanding of surface processes within a viewshed and, at their highest levels of execution, represent works of art, being both practical and beautiful. The execution of a pen‐and‐ink composition, however, requires inordinate amounts of time and skill. This article will introduce an algorithm for rendering creases – linework representing visually significant morphological features – at animation speeds, made possible with recent advances in graphics processing unit (GPU) architectures and rendering APIs. Beginning with a preprocessed high‐resolution drainage network model, creases are rendered from selected stream segments if their weighted criteria (slope, flow accumulation, and surface illumination), attenuated by perspective distance from the viewpoint, exceed a threshold. The algorithm thus provides a methodology for crease representation at continuous levels of detail down to the highest resolution of the preprocessed drainage model over a range of surface orientation and illumination conditions. The article also presents an implementation of the crease algorithm with frame rates exceeding those necessary to support animation, supporting the proposition that parallel processing techniques exposed through modern GPU programming environments provide cartographers with a new and inexpensive toolkit for constructing alternative and attractive real‐time animated landscape visualizations for spatial analysis.     

Large-scale dune erosion tests to study the influence of wave periods

Large-scale physical model tests were performed to quantify the effects of the wave period on dune erosion. Attention was focussed on 2D cross-shore effects in a situation with sandy dunes and extreme water levels and wave conditions. Besides profile measurements, detailed measurements in time and space of water pressure, flow velocities and sediment concentrations were performed in the near near-shore area. It was concluded that a longer wave period leads to a larger dune erosion volume and to a larger landward retreat of the dune face. Tests with double-peaked wave spectra showed that the influence of the spectral shape on dune erosion was best represented by the T_m − 1,0 spectral mean wave period, better than the peak wave period, T_p. The effect of the wave period on dune erosion was implemented in a dune erosion prediction method that estimates erosion volumes during normative storm conditions for the Dutch coast. More details of the measurements and additional analyses of physical processes are described in an accompanying paper by Van Thiel de Vries et al. [Van Thiel de Vries, J.S.M., van Gent, M.R.A., Reniers, A.J.H.M. and Walstra, D.J.R., submitted for publication. Analysis of dune erosion processes in large scale flume experiments, In this volume of Coastal Engineering.].     

A One-dimensional Ensemble Forecast and Assimilation System for Fog Prediction

A probabilistic fog forecast system was designed based on two high resolution numerical 1-D models called COBEL and PAFOG. The 1-D models are coupled to several 3-D numerical weather prediction models and thus are able to consider the effects of advection. To deal with the large uncertainty inherent to fog forecasts, a whole ensemble of 1-D runs is computed using the two different numerical models and a set of different initial conditions in combination with distinct boundary conditions. Initial conditions are obtained from variational data assimilation, which optimally combines observations with a first guess taken from operational 3-D models. The design of the ensemble scheme computes members that should fairly well represent the uncertainty of the current meteorological regime. Verification for an entire fog season reveals the importance of advection in complex terrain. The skill of 1-D fog forecasts is significantly improved if advection is considered. Thus the probabilistic forecast system has the potential to support the forecaster and therefore to provide more accurate fog forecasts.     

MANAGEMENT AND SUBSURFACE EFFECTS ON RUNOFF AND SEDIMENT YIELD FROM SMALL WATERSHEDS

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Structure and Stability of Ionization Fronts

The study of the dynamics of ionization fronts has moved far since Franz Kahn helped define the field in the 1950s. Nevertheless, the stability of the fronts and the nature of elephant trunks and bright rims in HII regions remain contentious issues. This revised version was published online in July 2006 with corrections to the Cover Date.     

Heterogeneous characteristics of streambed saturated hydraulic conductivity of the Touchet River,south eastern Washington,USA

Traditionally a streambed is treated as a layer of uniform thickness and low saturated hydraulic conductivity (K) in surface‐ and ground‐water studies. Recent findings have shown a high level of spatial heterogeneity within a streambed and such heterogeneity directly affects surface‐ and ground‐water exchange and can have ecological implications for biogeochemical transformations, nutrient cycling, organic matter decomposition, and reproduction of gravel spawning fish. In this study a detailed field investigation of K was conducted in two selected sites in Touchet River, a typical salmon spawning stream in arid south eastern Washington, USA. In‐stream slug tests were conducted to determine K following the Bouwer and Rice method. For the upper and lower sites, each 50 m long and 9 m wide and roughly 20 m apart, a sampling grid of 5 m longitudinally and 3 m transversely was used. The slug tests were performed for each horizontal coordinate at 0·3–0·45, 0·6–0·75, 0·9–1·05 and 1·2–1·35 m depth intervals unless a shallower impenetrable obstruction was encountered. Additionally, water levels were measured to obtain vertical hydraulic gradient (VHG) between each two adjacent depth intervals. Results indicated that K ranged over three orders of magnitude at both the upper and lower sites and differed between the two sites. At the upper site, K did not differ significantly among different depth intervals based on nonparametric statistical tests for mean, median, and empirical cumulative distribution, but the spatial pattern of K varied among different depth intervals. At the lower site, K for the 0·3–0·45 m depth interval differed statistically from those at other depth intervals, and no similar spatial pattern was found among different depth intervals. Zones of upward and downward water flow based on VHG also varied among different depth intervals, reflecting the complexities of the water flow regime. Detailed characterization of the streambed as attempted in this study should be helpful in providing information on spatial variations of streambed hydraulic properties as well as surface‐ and ground‐water interaction. Copyright © 2009 John Wiley & Sons, Ltd.