Date of minimum of the “protracted” solar cycle 23

We offer an interpretation of the now widely discussed protracted onset of the epoch of solar activity minimum after cycle 23. The interpretation appeals to the Gnevyshev-Ohl rule, but in the context of a new statistical quantity-the product of the cycle amplitude by its duration. Considering this quantity, which has the same physical meaning as that of the integrated characteristic used by Gnevyshev and Ohl, yields a probable estimate for the onset of the minimum of the current cycle in the interval 2009.0–2012.4.     

Polar fossil forests

In the Arctic and Antarctic there are spectacular fossil forests. They are true 'polar forests' because not only are they found as fossils in high latitudes today-they actually grew in the polar regions. They provide important evidence that the climate of the Earth was once much warmer, and that the trees must have been adapted to the strange polar light-regime of winter darkness and continuous summer sunlight.     

Experimental modeling of the interaction of subducted carbonates and sulfur with mantle silicates

Experimental studies in the system Fe,Ni–olivine–carbonate–S (P = 6.3 GPa, T = 1050–1550°C, t = 40–60 h) aimed at modeling of the interaction of subducted carbonates and sulfur with rocks of the silicate mantle and at investigation of the likely mechanism of the formation of mantle sulfides were performed. It is shown that an association of olivine + orthopyroxene + magnesite + pyrite coexisting with a sulfur melt/fluid with dissolved Fe, Ni, and O is formed at T ≤ 1250°C. An association of low-Fe olivine, orthopyroxene, and magnesite and two immiscible melts of the carbonate and S–Fe–Ni–O compositions are formed at T ≥ 1350°C. It is shown that the reduced S-bearing fluids may transform silicates and carbonates, extract metals from the solid-phase matrix, and provide conditions for generation of sulfide melts.     

Inducing mineral precipitation in groundwater by addition of phosphate

Background

Induced precipitation of phosphate minerals to scavenge trace elements from groundwater is a potential remediation approach for contaminated aquifers. The success of engineered precipitation schemes depends on the particular phases generated, their rates of formation, and their long term stability. The purpose of this study was to examine the precipitation of calcium phosphate minerals under conditions representative of a natural groundwater. Because microorganisms are present in groundwater, and because some proposed schemes for phosphate mineral precipitation rely on stimulation of native microbial populations, we also tested the effect of bacterial cells (initial densities of 10⁵ and 10⁷ mL^-1) added to the precipitation medium. In addition, we tested the effect of a trace mixture of propionic, isovaleric, formic and butyric acids (total concentration 0.035 mM).

Results

The general progression of mineral precipitation was similar under all of the study conditions, with initial formation of amorphous calcium phosphate, and transformation to poorly crystalline hydroxylapatite (HAP) within one week. The presence of the bacterial cells appeared to delay precipitation, although by the end of the experiments the overall extent of precipitation was similar for all treatments. The stoichiometry of the final precipitates as well as Rietveld structure refinement using x-ray diffraction data indicated that the presence of organic acids and bacterial cells resulted in an increasing a and decreasing c lattice parameter, with the higher concentration of cells resulting in the greatest distortion. Uptake of Sr into the solids was decreased in the treatments with cells and organic acids, compared to the control.

Conclusions

Our results suggest that the minerals formed initially during an engineered precipitation application for trace element sequestration may not be the ones that control long-term immobilization of the contaminants. In addition, the presence of bacterial cells appears to be associated with delayed HAP precipitation, changes in the lattice parameters, and reduced incorporation of trace elements as compared to cell-free systems. Schemes to remediate groundwater contaminated with trace metals that are based on enhanced phosphate mineral precipitation may need to account for these phenomena, particularly if the remediation approach relies on enhancement of in situ microbial populations.     

Seasonal and spatial variability of particulate matter of a muddy intertidal flood front

The concentration and composition of suspended particulate matter (SPM) were measured weekly for a period of one year in the flood front waters traversing a muddy tidal flat. SPM concentrations were lowest in the winter when portions of the tidal flat were covered with ice, and biological activity was minimal. In contrast, the summer months had the highest SPM concentrations which reflected increased bottom resuspension. The two main sources of SPM were suspended matter carried in from offshore on the flooding tide and resuspended in situ bottom sediments. The offshore source was characterized by low SPM concentrations, coarse textures, and a high content of protein and chlorophyll ‘a’. Samples taken during resuspension events (storms/showers) had high SPM concentrations, finer textures, and were enriched in dead detrital organic material (phaeophytin). At any one time the SPM was primarily an admixture of these two sources. The highest SPM measurements were taken during storm events, with rainfall seeming to play a dominant physical role in aiding resuspension. SPM concentrations, textures, and compositions collected during the storms closely approximated SPM measurements made over newly dug ‘clam flats’.     

Mars: Experimental study of albedo changes caused by dust fallout

An experimental study was undertaken to determine how the spectral and photometric properties of representative Martian areas are affected by fallout of atmospheric dust suspended during dust forms. A laboratory apparatus was used to simulate the uniform fallout and deposition of particles 1 to 5 μm in diameter. Spectral measurements from 0.4- to 1.2-μm wavelengths and photometric measurements at several wavelengths were made for a number of Mars-analog materials before and after deposition of 6 × 10^?5 to 1.5 × 10^?3 g/cm² of simulated fallout. These results indicate that the spectral and photometric properties of Martian regions can be affected significantly even by minute amounts of fallout. For instance, the reflectance at 0.56 μm of an average dark area will increase by 35% after deposition of only 9 × 10^?5 g/cm², and by 70% after deposition of 1.5 × 10^?4 g/cm². Thus the fallout from even one dust storm season (～2 × 10^?3 g/cm²) is sufficient to change significantly the spectral and photometric characteristics of the substrate material, if the fallout were ubiquitous over the surface and if no competing processes of dust removal from surface grains occured.     

On the application of the mode-acceleration method to structural engineering problems

Mode-superposition has been extensively used in computing the dynamic response of complex structures. Two versions of mode-superposition, namely the mode-displacement method and the mode-acceleration method, have been employed. The present paper summarizes the results of a systematic study comparing the accuracy of the mode-displacement and mode-acceleration methods when applied to structures with various levels of damping or various excitation frequencies. The paper also discusses several details concerning the implementation of the mode-acceleration method.     

Lower Eocene carbonate-cemented “chimney” structures (Varna, Bulgaria) — Control of seepage rates on their formation and stable isotopic signature

The genesis of Lower Eocene calcite-cemented columns, “pisoid”-covered structures and horizontal interbeds, clustered in dispersed outcrops in the Pobiti Kamani area (Varna, Bulgaria) is related to fossil processes of hydrocarbon migration. Field observations, petrography and stable isotope geochemistry of the cemented structures and associated early-diagenetic veins, revealed that varying seepage rates of a single, warm hydrocarbon-bearing fluid, probably ascending along active faults, controlled the type of structure formed and its geochemical signature. Slow seepage allowed methane to oxidize within the sediment under ambient seafloor conditions (δ¹⁸O = − 1 ± 0.5‰ V-PDB), explaining columns' depleted δ¹³C ratios of − 43‰. Increasing seepage rates caused methane to emanate into the water column (δ¹³C = − 8‰) and raised precipitation temperatures (δ¹⁸O = − 8‰). Calcite-cemented conduits formed and upward migrating fluids also affected interbed cementation. Even higher-energy fluid flow and temperatures likely controlled the formation of “pisoids”, whereby sediment was whirled up and cemented.