Monitoring Large-Scale Tests for Nuclear Waste Disposal

Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment) involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data during long transient periods characterised by very large variations of suction within the bentonite.     

Experimental investigation of the effects of temperature and ionic strength on Mo isotope fractionation during adsorption to manganese oxides

The Mo stable isotope system is being applied to study changes in ocean redox. Such applications implicitly assume that Mo isotope fractionation in aqueous systems is relatively insensitive to frequently changing environmental variables such as temperature (T) and ionic strength (I). A major driver of fractionation is the adsorption of Mo to Mn oxyhydroxide surfaces [Barling J. and Anbar A. D. (2004) Molybdenum isotope fractionation during adsorption by manganese oxides. Earth Planet. Sci. Lett.217(3-4), 315-329]. Here, we report the results of experiments that determine the extent to which Mo isotope fractionation during adsorption of Mo to the Mn oxyhydroxide mineral birnessite is sensitive to T and I. The results are compared to new predictions from quantum chemical computations. We measured fractionation from 1 to 50 °C at I = 0.1 m and found that Δ^97/95Mo_{dissolved-adsorbed} varies from 1.9‰ to 1.6‰ over this temperature range. Experiments were also performed at 25 °C in synthetic seawater (I = 0.7); fractionation at this condition was the same within analytical error as in low ionic strength experiments. These findings confirm that the Mo isotope fractionation during adsorption to Mn oxyhydroxides is relatively insensitive to variations and T and I over environmentally relevant ranges. To relate these findings to potential mechanisms of Mo isotope fractionation, we also report results for density functional theory computations of the fractionation between and various possible structures of molybdic acid as a function of temperature. Because no plausible species fractionates from with a magnitude matching the experiments, we are left with three possibilities to explain the fractionation: (1) solvation effects on the vibrational frequencies of aqueous species considered thus far are significant, such that our calculations in vacuo yield inaccurate fractionations; (2) a trace aqueous species not yet considered fractionates from and then adsorbs to birnessite; or (3) a surface complex not present in solution forms on birnessite in which Mo is not tetrahedrally coordinated. Our findings help validate assumptions underlying paleoceanographic applications of the Mo isotope system and also lead us closer to understanding the mechanism of isotope fractionation during adsorption of Mo to Mn oxyhydroxides.     

Elemental Concentrations in Japanese Silicate Rock Standards JA-1, JR-1 and JB-2

Data on three Japanese geochemical reference samples (JR-1, JA-1, and JB-2) are presented. Ten major and thirty-five trace element concentrations were determined using x-ray fluorescence, instrumental thermal neutron activation, thermal neutron capture prompt gamma-ray spectrometry, delayed neutron assay, automated thermal neutron activation analysis, inductively coupled plasma emission, atomic absorption, and ion selective electrode. Good agreement between the various methods and with recent literature values were obtained using error weighted mean concentrations for the samples.     

Chemical denudation rates in Kärkevagge, Swedish Lapland

This study examines the spatial and temporal variability of chemical denudation rates in Kärkevagge, northern Sweden. The chemical flux rates within the valley are strongly influenced by the local geology. Chemical denudation rates determined for the study period are more than double those previously reported in the literature for this valley. Rates of greater than 46t km⁻² a⁻¹ were measured at the valley mouth over the course of the melt season. This difference is likely due to differences in measurement technique compared to that used by past researchers. This rate is also much higher than for other arctic and alpine watersheds. Chemical denudation in Kärkevagge is comparable to larger temperate rivers. The rapid chemical denudation in Kärkevagge is likely due to sulfide weathering creating acid solutions.     

HH 111 STIS Observations and their Analysis using Analytical and Numerical Models

The internal structure of stellar jets arising from young stellar objects is characterized by a series of `knots' or condensations which have highly supersonic proper motions. These structures, we believe, are the result of a variable ejection from the source, which leads to the formation of internal working surfaces or small bowshock within the jet beam. In this paper we present a long-slit spectrum of Herbig-Haro object HH 111 obtained with STIS and an interpretation of this observation in terms of an ejection velocity variability model.     

Propagation and absorption of electron-cyclotron maser radiation during solar flares

The electron-cyclotron maser is believed to be the source of microwave spike bursts often observed during solar and stellar flares. Partial absorption of this radiation as it propagates through the corona can produce plasma heating and soft X-ray emission over an extended region. In this paper, the propagation and absorption of the maser radiation during solar flares are examined through linear theory and electro-magnetic particle simulations. It is shown using linear theory that strong absorption of the radiation should occur as it propagates towards the second harmonic layer where the magnetic field is half as strong as in the emission region. Only radiation propagating nearly parallel to the magnetic field in a low-temperature plasma may be able to escape under certain, limited conditions. Finite temperature effects can cause radiation propagating nearly perpendicular to the magnetic field to refract, causing enhanced absorption. Particle simulations are then used to evaluate the nonlinear response of the plasma as the maser radiation propagates through the absorption layer. It is shown that some of the maser radiation is able to escape through a process of absorption below the second harmonic of the local gyrofrequency and re-emission above it. The fraction able to escape is much higher than that predicted by linear theory, although the amount of escaping energy is only a small fraction of the incident energy. The bulk of incident energy goes into the perpendicular heating of the ambient electrons, with the rate of energy absorption showing no signs of leveling off during the simulations. This indicates that the absorption layer does not become optically thin after continuous heating by the maser radiation. A few electrons are accelerated to several tens of keVs as a result of the heating.     

Comparative tolerance of two estuarine annelids to fluoranthene under normoxic and moderately hypoxic conditions

The tolerance of the oligochaete Monopylephorus rubroniveus and the polychaete Streblospio benedicti to sediment-associated fluoranthene was characterized under normoxic (>80% dissolved oxygen saturation) and moderately hypoxic ( approximately 50% dissolved oxygen saturation) conditions. Under both conditions, M. rubroniveus was highly tolerant of fluoranthene. Streblospio benedicti was considerably less tolerant of fluoranthene compared with M. rubroniveus. In addition, S. benedicti was less tolerant to fluoranthene under moderately hypoxic conditions, although no differences in sensitivity between the two oxygen conditions were observed based upon median lethal tissue residues. Bioaccumulation factors were higher for S. benedicti exposed to moderate hypoxia, suggesting that behavioral adaptations to compensate for the lower dissolved oxygen increased its bioaccumulation of fluoranthene. The results of the present laboratory study demonstrate that (1). changes in annelid tolerance to fluoranthene under varying oxygen conditions is a species-dependent phenomenon and (2). the differential tolerance of these two annelids to these combined stressors is consistent with their relative abundances in the field.