Recycling of Organic Matter in the Sediments of Santa Monica Basin,California Borderland

Geochemical and isotopic data for the uppermost 1.2 m of the sediments of the central Santa Monica Basin plain were examined to better understand organic matter deposition and recycling at this site. Isotopic signatures (Δ¹⁴C and δ¹³C) of methane (CH₄) and dissolved inorganic carbon (DIC) indicate the occurrence of anaerobic oxidation of CH₄ that is fueled by CH₄ supplied from a relict reservoir that is decoupled from local organic carbon (C_org) degradation and methanogenesis. This finding was corroborated by a flux budget of pore-water solutes across the basal horizon of the profile. Together these results provide a plausible explanation for the anomalously low ratio between alkalinity production and sulfate consumption reported for these sediments over two decades ago. Shifts in Δ¹⁴C and δ¹³C signatures of C_org have previously been reported across the 20-cm depth horizon for this site and attributed to a transition from oxic to anoxic bottom water that occurred ~350 years BP. However, we show that this horizon also coincides with a boundary between the base of a hemipelagic mud section and the top of a turbidite interval, complicating the interpretation of organic geochemical data across this boundary. Radiocarbon signatures of DIC diffusing upward into surface sediments indicate that remineralization at depth is supported by relatively ¹⁴C-enriched C_org within the sedimentary matrix. While the exact nature of this C_org is unclear, possible sources are hemipelagic mud sections that were buried rapidly under thick turbidites, and ¹⁴C-rich moieties dispersed within C_org-poor turbidite sections.     

A Linear Programming Approach to Determine the Normative Composition of Sedimentary Rocks

The analysis of modal and normative composition of sedimentary rocks is widely used for studying their sources and tectonic settings. The normative calculation of the mineral composition of rocks in this study is formulated as a linear programming problem and is solved by means of the simplex method. This enables both simultaneous and successive subtraction of a set of basic minerals from a rock sample represented by its chemical composition {SiO₂...LOI}. Such an approach provides a more exact calculation of the contribution of basic minerals in the rock. This mathematical approach is used to study two representative sets of sandstones and fine-grained rocks from a Meso- to Neoproterozoic marginal basin of southeastern Siberia (Uchur–Maya region, Yakutia) and a Pennsylvanian-Lower Permian uplifted continental block in Colorado, USA. The calculated normative mineral compositions of the Siberian sandstones are consistent with the observed modal compositions. These sandstones vary from K- Feldspar rich arkoses at the base of the sequence (the Uchur Group, lower Riphean) to quartz arenites or lithic sandstones and wacke in transgressive successions of the middle-upper Riphean. Arkoses and quartz arenites are dominant in Meso- to Neoproterozoic Siberia. These samples represent craton interior uplifted basement and quartzose, recycled orogen provenance of a stable craton in Rodinia. There are higher but consistent discrepancies between the calculated and observed compositions for the Pennsylvanian to Lower-Permian arkoses and quartz arenites (Sangre de Cristo, Belden, and Maroon Formations). The differences between the predicted and observed mineralogy may be due to uncertainties in the modes in the matrix and cement of the sandstones. This normative program should supplement modal calculations and provide better genetic constructions, especially in case of matrix-rich sandstones.     

The Catoca kimberlite pipe, Republic of Angola: A paleovolcanological model

The Catoca kimberlite pipe is among the world’s largest primary diamond deposits. The Catoca volcanic edifice is only slightly eroded. Kimberlitic rocks of various facies compose a crater of about 1 km in diameter and a diatreme. The structure of the pipe and mining conditions of the deposit are complicated by intense intrapipe tectonic processes related to large-amplitude subsidence. Based on geological data, we propose a structural model of the deposit and a paleovolcanological model of the Catoca pipe formed during a full cycle beginning with a stage of active volcanism and completed by stages of gradually waning volcanic activity and sedimentation. It is suggested that the banded tuffisitic kimberlite of the crater zone was deposited at the stage of active volcanic eruption from specific pyroclastic suspension as a low-viscosity mixture of crystals and aqueous sol rich in serpentine.     

Ilmenite composition in the Tellnes Fe–Ti deposit,SW Norway: fractional crystallization,postcumulus evolution and ilmenite–zircon relation

Major and trace element XRF and in situ LA-ICP-MS analyses of ilmenite in the Tellnes ilmenite deposit, Rogaland Anorthosite Province, SW Norway, constrains a two stage fractional crystallization model of a ferrodioritic Fe-Ti-P rich melt. Stage 1 is characterized by ilmenite-plagioclase cumulates, partly stored in the lower part of the ore body (Lower Central Zone, LCZ), and stage 2 by ilmenite-plagioclase-orthopyroxene-olivine cumulates (Upper Central Zone, UCZ). The concentration of V and Cr in ilmenite, corrected for the trapped liquid effect, (1) defines the cotectic proportion of ilmenite to be 17.5 wt% during stage 1, and (2) implies an increase of D _V^Ilm during stage 2, most likely related to a shift in fO₂. The proportion of 17.5 wt% is lower than the modal proportion of ilmenite (ca. 50 wt%) in the ore body, implying accumulation of ilmenite and flotation of plagioclase. The fraction of residual liquid left after crystallization of Tellnes cumulates is estimated at 0.6 and the flotation of plagioclase at 26 wt% of the initial melt mass. The increasing content of intercumulus magnetite with stratigraphic height, from 0 to ca. 3 wt%, results from differentiation of the trapped liquid towards magnetite saturation. The MgO content of ilmenite (1.4–4.4 wt%) is much lower than the expected cumulus composition. It shows extensive postcumulus re-equilibration with trapped liquid and ferromagnesian silicates, correlated with distance to the host anorthosite. The Zr content of ilmenite, provided by in situ analyses, is low (<114 ppm) and uncorrelated with stratigraphy or Cr content. The data demonstrate that zircon coronas observed around ilmenite formed by subsolidus exsolution of ZrO₂ from ilmenite. The U-Pb zircon age of 920 ± 3 Ma probably records this exsolution process. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.     

Microcomputer aided lineament analysis of Son-Mahanadi Valley coal basins,Central India from Landsat data

In the overall tectonic set up of various coal basins of the Peninsular India, the Son-Mahanadi Valley coal basins of Central India have a unique disposition. The coal measures sediments of Peninsular India are developed along well defined E-W and NW-SE trending linear narrow belts. The Son-Mahanadi Valley basins represent the tract where NW-SE trending Mahanadi Valley basins seemingly merge with the major east-west trending Damodar-Koel-Son-Satpura alignment. Landsat data of Son-Mahanadi Valley basins in the four spectral bands (0.5 to 1.1 Micrometers) were used to pick up the lineaments which are possibly of geologic origin. Detailed analysis of lineaments were carried out with the help of three softwares. Diglin (to produce rose diagram) and PLLIN (to plot digitized lineaments to produce a map on any scale) by a Hewlett Packard 45 series microcomputer equipped with graphics screen, plotter, digitiser and floppy disc unit. Detailed analysis revealed a pronounced direction roughly, N 70°E which is present in the northern half of the area while N 40°W direction is present alongwith N 70°E in the southern half. These trends correspond to the NW-SE trending Mahanadi Valley and to the E-W trending Damodar-Son Satpura belt. The above clearly brings out the striking parallelism between the lineament trends in the basement and the overlying coal bearing Gondwana Sediments. This parallelism is suggestive of a genetic relationship between the two.     

Restrain of a seismically isolated bridge by external stoppers

The current design of seismically isolated bridges usually combines the use of bearings and stoppers, as a second line of defence. The stoppers allow the development of the in-service movements of the bridge deck, without transmitting significant loads to the piers and their foundations, while during earthquake they transmit the entire seismic action. Despite the fact that stoppers, which restrain the transverse seismic movements of the deck, are used frequently in seismically isolated bridges, the use of longitudinal stoppers is relatively rare, mainly due to the large in-service constraint movements of bridges. The present paper proposes a new type of external longitudinal stoppers, which are installed in stiff sub-structures-boundaries, aiming at limiting the bridge seismic movements. The parametric investigation, which was conducted in order to identify the seismic efficiency of the external stoppers, showed that the interaction of the bridge with the stiff boundaries can lead to significant reductions in the seismic movements of the bridge. Serviceability is appropriately arranged in the paper by expansion joints and approach slabs.     

Electromagnetic inertio-gravity waves in the Earth's ionosphere

Propagation of electromagnetic inertio-gravity (IG) waves in the partially ionized ionospheric E- and F-layers is considered in the shallow water approximation. Accounting of the field-aligned current is the main novelty of the investigation. Existence of two new eigen-frequencies for fast and slow electromagnetic waves is revealed in the ionospheric E-layer. It is shown that in F-layer slowly damping new type of inertial-fast magnetosonic waves can propagate. Slowly damping low-frequency oscillations connected with the field-aligned conductivity are found. Broad spectrum of oscillations is investigated.     

A contribution to the theory of the equatorial noise generation in the Earth’s magnetosphere

This work is devoted to the study of the generation of the equatorial noise—electromagnetic emission below the LHR frequency observed near the equatorial plane of the magnetosphere at distances of ~4R_E. According to accepted views, the generation of the equatorial noise is related to the instability of ring current protons. In this work, a logarithmic distribution of energetic protons over the magnetic moment with an empty loss cone is proposed, and arguments for the formation of such a distribution are presented. The main result of the work is the calculation and analysis of the instability growth rate of waves forming the equatorial noise. The growth rate obtained in this work significantly differs from that encountered in the literature.