Al hematites prepared by homogeneous precipitation of oxinates: material characterization and determination of the Morin transition

A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T _M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T _M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases.     

A search for soft X-ray emission from stellar sources

With the soft X-ray detector (0.2–0.284 keV) aboard the Astronomical Netherlands Satellite (ANS) we have searched for X-ray emission from hot star coronae and peculiar stars. On Sirius ( CMa) and Capella ( Aur) X-ray emission has been measured at 6 and 5 level, respectively, above background. In all other cases the search revealed no evidence for soft X-ray emission. Upper limits to the luminosities of about 25 star coronae (main-sequence stars, (sub)giants, and supergiants) and of 4 peculiar stars ( Sco, Lyr, P Cyg, and Car) have been obtained.Paper presented at the COSPAR/IAU Symposium on Fast Transients in X-and Gamma-Rays, held at Varna, Bulgaria, 29–31 May, 1975.     

Towards urbanisation of the non-hydrostatic numerical weather prediction model Lokalmodell (LM)

Numerical weather prediction models are increasingly employed for providing meteorological data for urban air quality applications. Model resolution, physiographic parameters and surface-layer parameterisations need to be adapted to the requirements of the urban boundary layer. The Lokalmodell of the German Weather Service was triple-nested down to a horizontal grid resolution of 1.1 km, urbanised physiographic parameters were implemented, and an additional anthropogenic heat source was introduced. Results of a sensitivity study for a spring dust episode in Helsinki show a clear urbanisation effect of these measures on temperature, humidity and the partitioning of surface fluxes, leading to an increased Bowen ratio and heat storage and an urban heat island effect.     

Cyclic degradation and non-coaxiality of soft clay subjected to pure rotation of principal stress directions

Foundation soils are often under non-proportional cyclic loadings. The deformation behaviour and the mechanism of non-coaxiality under continuous pure principal stress rotation for clays are not clearly investigated up to now. In order to study the effect of pure principal stress rotation, a series of cyclic undrained tests on Shanghai soft clay subjected to cyclic rotation of principal stress directions keeping the deviatoric stress constant under the pure rotation condition were conducted using hollow cylinder apparatus. Based on this, the evolutions of excess pore pressure and strains during cyclic loading were investigated, together with the effects of the intermediate principal stress parameter and the deviatoric stress level on stress–strain stiffness and non-coaxiality. The result can provide an experimental basis for constitutive modelling of clays describing the behaviour under non-proportional loadings.     

Dating of Quaternary Sediments from Western Borneo, Using Optically Stimulated Luminescence

Optically Stimulated Luminescence (OSL) dates from five sites in western Kalimantan are compared with ¹⁴C and thermo-luminescence dates from other sediments in the region. There is now strong evidence that the Old Alluvium of Peninsular Malaysia is of late Pleistocene age and that it can be correlated with the White Sand Complexes of western Borneo. This contrasts with the late Pliocene to mid Pleistocene ages for Old Alluvium, based primarily on stratigraphic deductions, put forward by geoscientists examining the regional tin deposits. This study shows that the upper parts, at least, of the western Borneo White Sand Complexes were deposited mid-way through the last glaciation (76 ka), with extensive terminal Pleistocene re-deposition (11.2-9.8 ka) and at least two gully erosion events during the Holocene (5.8-3.8 ka and 0.48 ka).     

Eruption episodes and magma recharge events in andesitic systems: Mt Taranaki,New Zealand

Eruption episodes, where a series of eruption events are generically related, can include the eruption of a wide spectrum of volcanic activity over decadal periods. This paper concentrates on the opening phases of an eruption episode which occurred approximately 1800 yrs BP from Mt Taranaki, New Zealand. These events spanned the eruption of differing bulk compositions and styles from two distinct vent locations; an andesitic sub-plinian eruption from the summit vent and a scoria cone-building eruption of basaltic magma from a satellite vent. Compositional profiles and zoning textures of plagioclase, amphibole and clinopyroxene phenocrysts from the opening andesitic event show evidence of magma mixing and subsequent crystallisation just prior to the initiation of the eruption episode. Titanomagnetite grain morphology and Ti variation suggest that the magma mixing event occurred within a few days to weeks before the eruption acting as a trigger for it. We present a magmatic model which is constrained by the petrological observations and eruptions of the episode. In this model magma differentiation at depth causes its rise and recharging of a mid-crustal magma storage area at 5–7 km. Although the recharging magma differed slightly in oxygen fugacity and temperature, it was compositionally and physically similar enough to the residing andesitic magma to allow efficient mixing. The petrological characteristics described here can be readily observed and enable identification of mixing events in other recent eruption episodes.     

Modeling of environmental influence in structural health assessment for reinforced concrete buildings

One branch of structural health monitoring (SHM) utilizes dynamic response measurements to assess the structural integrity of civil infrastructures. In particular,modal frequency is a widely adopted indicator for structural damage since its square is proportional to structural stiffness. However,it has been demonstrated in various SHM projects that this indicator is substantially affected by fluctuating environmental conditions. In order to provide reliable and consistent information on the health status of the monitored structures,it is necessary to develop a method to filter this interference. This study attempts to model and quantify the environmental influence on the modal frequencies of reinforced concrete buildings. Daily structural response measurements of a twenty-two story reinforced concrete building were collected and analyzed over a one-year period. The Bayesian spectral density approach was utilized to identify the modal frequencies of this building and it was clearly seen that the temperature and humidity fluctuation induced notable variations. A mathematical model was developed to quantify the environmental effects and model complexity was taken into consideration. Based on a Timoshenko beam model,the full model class was constructed and other reduced-order model class candidates were obtained. Then,the Bayesian modal class selection approach was employed to select the one with the most suitable complexity. The proposed model successfully characterizes the environmental influence on the modal frequencies. Furthermore,the estimated uncertainty of the model parameters allows for assessment of the reliability of the prediction. This study not only improves the understanding about the monitored structure,but also establishes a systematic approach for reliable health assessment of reinforced concrete buildings.     

Size scales over which ordinary chondrites and their parent asteroids are homogeneous in oxidation state and oxygen-isotopic composition

Literature data demonstrate that on a global, asteroid-wide scale (plausibly on the order of 100 km), ordinary chondrites (OC) have heterogeneous oxidation states and O-isotopic compositions (represented, respectively, by the mean olivine Fa and bulk Δ¹⁷O compositions of equilibrated samples). Samples analyzed here include: (a) two H5 chondrite Antarctic finds (ALHA79046 and TIL 82415) that have the same cosmic-ray exposure age (7.6 Ma) and were probably within ∼1 km of each other when they were excavated from the H-chondrite parent body, (b) different individual stones from the Holbrook L/LL6 fall that were probably within ∼1 m of each other when their parent meteoroid penetrated the Earth’s atmosphere, and (c) drill cores from a large slab of the Estacado H6 find located within a few tens of centimeters of each other. Our results indicate that OC are heterogeneous in their bulk oxidation state and O-isotopic composition on 100-km-size scales, but homogeneous on meter-, decimeter- and centimeter-size scales. (On kilometer size scales, oxidation state is heterogeneous, but O isotopes appear to be homogeneous.) The asteroid-wide heterogeneity in oxidation state and O-isotopic composition was inherited from the solar nebula. The homogeneity on small size scales was probably caused in part by fluid-assisted metamorphism and mainly by impact-gardening processes (which are most effective at mixing target materials on scales of ?1 m).     

Uranium (U) concentration and its genetic significance in the phosphorites of the Paleoproterozoic Bijawar Group of the Lalitpur district,Uttar Pradesh,India

The paper presents the uranium (U) concentration and distribution pattern in the Paleoproterozoic phosphorites of Lalitpur district of Uttar Pradesh. The study of thin sections, SEM and XRD reveal that apatite is the essential phosphate mineral while quartz and feldspars are the dominant gangue in the phosphorites of the investigated area. The collophane is observed to be mostly oolitic in form and microspherulitic in texture. The major element geochemistry indicated that the phosphorite samples are rich in P₂O₅, CaO, SiO₂ and Fe₂O₃ whereas depletion of MgO, MnO, K₂O and Al₂O₃ was observed. The CaO/P₂O₅ ratio ranges from 1.13 to 1.46 which is slightly lower than that of cations and anions substituted francolite (1.621) and close to that of carbonate-fluorapatite (1.318). The trace element geochemistry indicates that the phosphorites of Lalitpur have the significant range of U concentration (1.67 to 129.67 μg/g) which is more than that of Th (0.69 to 0.09 μg/g) among the analysed trace elements in the phosphorite samples of the area. The positive correlation of U with P₂O₅, CaO and U/P₂O₅ indicates a close association of U with phosphate minerals like collophane (apatite), whereas negative correlation of U with SiO₂ and Fe₂O₃ may be due to mutual replacement. The antipathetic relationship of U with Ni may be an indication of high oxidizing conditions, whereas sympathetic relationship of U with K₂O points towards higher alkaline conditions of the basin of deposition during phosphatization. The variable concentration of U and its relationship with significant major and trace elements in most of the phosphorite samples lead one to believe that the deposition of these phosphorites might have taken place in highly alkaline medium during fairly oxidizing to weakly reducing environmental conditions of geosynclinal basin.