Management of shock loads wastewater produced from water heaters industry

Water heater manufacturing represents one sector of household electrical appliance industry. It includes several batch processes which resulted in a highly polluted wastewater as shock loads. The objective of this study was to manage the shock loads wastewater with a simple and cost-effective approach prior to final discharge into municipality. To achieve this objective, two approaches were studied. The first approach was the chemical treatment of the accumulated shock loads wastewater using alum and an anionic polymer. Although this approach produced a very high-quality effluent, it was economically and technically infeasible. The second approach was a controlled release of the shock loads to the normal daily discharge in a way that guarantees the compliance of the end-off-pipe with the National Regulatory Standards. This solution required establishment of an equalization tank for normal daily flow and a holding tank for controlled release of the shock loads. Mathematical calculations were carried out to determine the most violating parameters in order to calculate the mixing ratio the of shock loads with the normal daily flow. Full engineering design of the proposed solution was carried out. This approach was implemented and proved to be simple, easy to operate, cost-effective and can be replicated in similar batch processing manufacturing plants.     

The Oeschinensee rock avalanche,Bernese Alps,Switzerland: a co-seismic failure 2300 years ago?

Landslide deposits dam Lake Oeschinen (Oeschinensee), located above Kandersteg, Switzerland. However, past confusion differentiating deposits of multiple landslide events has confounded efforts to quantify the volume, age, and failure dynamics of the Oeschinensee rock avalanche. Here we combine field and remote mapping, topographic reconstruction, cosmogenic surface exposure dating, and numerical runout modeling to quantify salient parameters of the event. Differences in boulder lithology and deposit morphology reveal that the landslide body damming Oeschinensee consists of debris from both an older rock avalanche, possibly Kandertal, as well as the Oeschinensee rock avalanche. We distinguish a source volume for the Oeschinensee event of 37 Mm³, resulting in an estimated deposit volume of 46 Mm³, smaller than previous estimates that included portions of the Kandertal mass. Runout modeling revealed peak and average rock avalanche velocities of 65 and 45 m/s, respectively, and support a single-event failure scenario. ³⁶Cl surface exposure dating of deposited boulders indicates a mean age for the rock avalanche of 2.3 ± 0.2 kyr. This age coincides with the timing of a paleo-seismic event identified from lacustrine sediments in Swiss lakes, suggesting an earthquake trigger. Our results help clarify the hazard and geomorphic effects of rare, large rock avalanches in alpine settings.     

Contemporary methods for retrieving the integrated atmospheric water-vapor content and the total cloud liquid-water content

A review of contemporary methods for determining integrated parameters of the water content in the atmosphere―atmospheric water-vapor content and cloud liquid-water content―is presented. Fields of these parameters can only be mapped spatially on the basis of using data of satellite measurements. The least errors of the retrieval of atmospheric water-vapor content and cloud liquid-water content is provided by methods based on using measurements of the satellite-borne scanning multichannel microwave radiometers over the ice-free ocean areas in the absence of precipitation. Most methods for retrieving the atmospheric water-vapor content and cloud liquid-water content from the data of microwave radiometers are based on results of numerical simulation of brightness temperatures of the upwelling microwave radiation of the ocean–atmosphere system. The evolution of satellite-borne microwave radiometers and methods for the retrieval of integrated parameters of water content is presented.     

Estimating areal production of intertidal microphytobenthos based on spatio-temporal community dynamics and laboratory measurements

In situ Microphytobenthic community dynamics were combined with laboratory measurement of predominant species by fluorescence methods to estimate the areal primary production. Field investigation of community dynamics of microphytobenthos (MPB) was conducted from August 2006 to August 2007 in intertidal flats of the Nakdong River estuary, Korea. MPB Biomass varied between 0.47 and 16.58 μg cm^?3 in the surface 1 cm sediment, with two dominant diatom species, Amphora coffeaeformis and Navicula sp., occupying average 77.2 ± 14.9% of total number of MPB cells. The biomass was higher in the slightly muddy sand sites than that in the sand site, and showed different pattern of seasonal variation. The profile of vertical distribution of biomass was an exponential decrease trend with depth in sediments. The biomass proportions in the uppermost 3 mm were 57.6% and 37.8% with and without the presence of biofilm, respectively. The two dominant species were cultured in laboratory, and their photosynthetic parameters, rETR_max (relative maximum electron transport rate), α (light utilization coefficient) and E _k (light saturation parameter) were derived from rETR (relative ETR)-irradiance curves by Imaging- PAM (pulse amplitude modulated) fluorometry. The rETR-irradiance curves showed no significant difference of photosynthetic activities between the two species. The areal potential production ranged from 0.74 to 2.22 g C m^?2 d^?1.     

Geomechanical modelling to assess fault integrity at the CO2CRC Otway Project,Australia

This paper presents the first published 3D geomechanical modelling study of the CO2CRC Otway Project, located in the state of Victoria, Australia. The results of this work contribute to one of the main objectives of the CO2CRC, which is to demonstrate the feasibility of CO₂ storage in a depleted gas reservoir. With this aim in mind, a one-way coupled flow and geomechanics model is presented, with the capability of predicting changes to the in situ stress field caused by changes in reservoir pressure owing to CO₂ production and injection. A parametric study investigating the pore pressures required to reactivate key, reservoir-bounding faults has been conducted, and the results from the numerical simulation and analytical analysis are compared. The numerical simulation indicates that the critical pore fluid pressure to cause fault reactivation is 1.15 times the original pressure as opposed to 1.5 times for the comparable analytical model. Possible reasons for the differences between the numerical and analytical models can be ascribed to the higher degree of complexity incorporated in the numerical model. Heterogeneity in terms of lateral variations of hydrological and mechanical parameters, effect of topography, presence of faults and interaction between cells are considered to be the main sources for the different estimation of critical pore pressure. The numerical model, which incorporates this greater complexity, is able then to better describe the state of stress that acts in the subsurface compared with a simple 1D analytical model. Moreover, the reactivation pressures depend mainly on the state of stress described; therefore we suggest that numerical models be performed when possible.     

Refractory metal nuggets within presolar graphite: First condensates from a circumstellar environment

Transmission electron microscope (TEM) investigations have revealed Os, Ru, Mo‐rich refractory metal nuggets within four different presolar graphites, from both the high‐density (HD) Murchison (MUR) and low‐density (LD) Orgueil (ORG) fractions. Microstructural and chemical data suggest that these are direct condensates from the gas, rather than forming later by exsolution. The presolar refractory metal nugget (pRMN) compositions are variable (e.g., from 8 < Os atom% < 77), but follow the same chemical fractionation trends as isolated refractory metal nuggets (mRMNs) previously found in meteorites (Berg et al. 2009). From these compositions one can infer a temperature of last equilibration with the gas of 1405–1810 K (e.g., Berg et al. 2009 at approximately 100 dyne cm^?2 pressure), which implies that the host graphites form over roughly the same range (in agreement with predictions) and that the pRMNs are chemically isolated from the gas when captured by graphite. Further, the pRMN compositions give evidence that HD graphites form at a higher T than LD ones. Chemical and phase similarities with the isolated mRMNs suggest that the mRMNs also condense directly from a gas, although from the early solar nebula rather than a presolar environment. Although the pRMNs themselves are too small for detection of isotopic anomalies, NanoSIMS isotopic measurements of their host graphites confirm a presolar origin for the assemblages. The two pRMN‐containing LD graphites show evidence of a supernova (SN) origin, whereas the stellar origins of the pRMNs in HD graphite are unclear, because only less‐diagnostic ¹²C enrichments are detectable (as is commonly true for HD graphites).     

Lithospheric thickness beneath the southern Kenya Rift: implications from basalt geochemistry

Geochemical data are reported for samples from the flanks and floor of the southern Kenya Rift Valley in the Lake Magadi area, and from two central volcanoes located within the rift valley. Rift lavas include samples of Singaraini and Ol Tepesi basalts on the eastern flank, Kirikiti basalts from the western flank, and plateau trachytes from the rift valley floor. Central volcano samples are from Ol Esayeiti and Lenderut located on the eastern flank. The rift basalts are mildly ne-normative, moderately evolved (Mg#=0.39-0.62) alkali basalts and show an overall range in differentiation. Incompatible trace element abundances are moderately elevated (Nb=17-51; Zr=93-274; La=17-55 ppm) and show strongly coherent variations and constant inter-element ratios (e.g. Zr/Nb=4.2-5.5; Nb/Ta=17.5ǂ.4; (La/Sm)_n=7.3ǃ.1); isotope ratios are restricted in range (⁸⁷Sr/⁸⁶Sr=0.70393-0.70436; ¹⁴³Nd/¹⁴⁴Nd=0.51272-0.51280; ²⁰⁶Pb/²⁰⁴Pb=19.87-19.92; ²⁰⁷Pb/²⁰⁴Pb=15.68-15.70; ²⁰⁸Pb/²⁰⁴Pb=39.56-39.71). Central volcano lavas are more alkaline in character and include basanite (Ol Esayeiti; Mg# >60) and hawaiite to benmoreite (Lenderut; Mg#=0.48-0.38). Incompatible element ratio are similar to those of the rift basalts, although the chondrite normalised REE patterns are steeper (La/Sm)_n=17.4ǃ.2). ⁸⁷Sr/⁸⁶Sr (0.70358, 0.70391), ¹⁴³Nd/¹⁴⁴Nd (0.51280, 0.51267), ²⁰⁶Pb/²⁰⁴Pb (19.96,20.17), ²⁰⁷Pb/²⁰⁴Pb (15.66,15.76) and ²⁰⁸Pb/²⁰⁴Pb (39.80,40.00) ratios of Ol Esayeiti basanites are similar to the rift basalts, whereas the Lenderut lavas have unusually low¹⁴³Nd/¹⁴⁴Nd (0.512388-0.512453) ratios for their ⁸⁷Sr/⁸⁶Sr (0.70370-0.70481) ratios, and distinctly less radiogenic and variable Pb isotope compositions (²⁰⁶Pb/²⁰⁴Pb=17.93-19.01; ²⁰⁷Pb/²⁰⁴Pb=15.43-15.58; ²⁰⁸Pb/²⁰⁴Pb=37.91-39.14). An integrated model is developed in which the geochemical signature of the lavas is attributed to variable degrees of melting to depths within the garnet stability field, and in the presence of residual amphibole. The stability fields of these phases in P-T space indicates that the lavas must have formed within the sub-continental lithosphere rather than within the underlying ambient asthenosphere or a rising mantle plume. The subcontinental lithospheric mantle must therefore extend to a depth of at least 75 km beneath the Lake Magadi area, which contrasts with recent gravity models for the area, which infer that lithospheric mantle is absent beneath this section of the southern Kenya Rift.     

The Darwin Rise demise: the western Pacific guyot heights trace the trans-Pacific Mendocino fracture zone

The Darwin Rise has been proposed so many times and in so many forms and places that the time has come to make a more comprehensive examination of the region. Lying on the NW Pacific Plate between the Geisha Guyots, the Mid-Pacific Mountains, the equator, and the trenches, the region is roughly bounded by magnetic anomaly M20 (147 Ma). It was subjected to a massive outpouring of lava about 105 to 120 Ma, which created the guyots and seamounts in that region. Guyots are excellent tools for studying events of long ago because they eroded in the same lowstand in the Cretaceous and guyot relief, therefore, is a surrogate for paleo-sealevel. The relief is derived by subtracting the break depth of the summit plateau of a guyot from the regional depth. Guyot relief would necessarily be less in the center than to the periphery if the feature formed on a pre-existing rise, as has been postulated. The existence of a paleo-Darwin Rise would give concentric contours for the region in question. Of the sixty guyots used in this study, thirty-seven of these guyots were surveyed using SASS multibeam in the Marcus-Wake seamount group. Twenty-three guyots were surveyed using random track single-beam sonar surveys. An entirely different scenario is shown. Data revealed a major fracture passing through the area coevally or after the guyots formed. Because the depths to the summit are not the same now, vertical tectonics occurred after subaerial erosion. This means the fracture formed during and after the erosion (roughly 105 Ma) and influenced the normal sequence of events in guyot formation. Depending on how one deciphers trends through the Hess Rise morass, SASS bathymetry shows a continuation of the Surveyor/Mendocino fracture zone swarm inside the M20 region to the NE of these data. The fracture swarm continues to the western Pacific trench system. Based on this information, if the Darwin Rise ever existed, it had to have done so elsewhere.     

Using spatial statistics to identify the uranium hotspot in groundwater in the mid-eastern Gangetic plain,India

The occurrence of uranium in groundwater is of particular interest due to its toxicological and radiological properties. It has been considered as a relevant contaminant for drinking water even at a low concentration. Uranium is a ubiquitously occurring radionuclide in the environment. Four hundred and fifty-six (456) groundwater samples from different locations of five districts of South Bihar (SB) were collected and concentrations of uranium (U) were analyzed using a light-emitting diode (LED) fluorimetric technique. Uranium concentrations in groundwater samples varied from 0.1 µg l^?1 to 238.2 µg l^?1 with an average value of 12.3 µg l^?1 in five districts of Bihar in the mid-eastern Gangetic plain. This study used hot spot spatial statistics to identify the distribution of elevated uranium concentration in groundwater. The hypothesis whether spatial distribution of high value and low value of U is more likely spatially clustered due to random process near a uranium hotspot in groundwater was tested based on z score and Getis-Ord Gi* statistics. The method implemented in this study, can be utilized in the field of risk assessment and decision making to locate potential areas of contamination.     

Klimatologische Untersuchung über die geographische Verteilung der Globalstrahlung und der diffusen Himmelsstrahlung

Zusammenfassung Die vorliegende strahlungsklimatologische Studie verfolgt den Zweck, ausschließlich auf Grund von Meßergebnissen anhand ausgewählter Beispiele gegensätzlicher Großaumklimate zunächst die typischen Eigenschaften des Jahresganges der Globalstrahlung (T) und der diffusen Himmelsstrahlung (D) zu untersuchen. In Ergänzung hierzu werden häufigkeitsstatistische Betrachtungen über die Eigenheiten im Verhalten dieser Strahlungselemente im Bereich verschieden beschaffener geographischer Räume angestellt. Dabei zeigt sich, daß neben dem jahreszeitlichen Ablauf auch die Häufigkeitsverteilungen vonT undD sich zur Klimatypisierung heranziehen lassen. Ein besonderes Interesse beansprucht der jahreszeitliche Verlauf des VerhältnissesD/T in den Hauptklimazonen der Erde. Ferner wird die Breitenabhängigkeit der Globalstrahlung (T), der diffusen Himmelsstrahlung (D) und des VerhältnissesD/T behandelt. Hinsichtlich der Höhenabhängigkeit ergibt sich auf Grund des Verhaltens vonT undD für die gemäßigten Breiten eine Abnahme des QuotientenD/T. Den Abschluß bilden strahlungsklimatologische Überlegungen zur Frage der Abhängigkeit des VerhältnissesD/T von der Sonnenscheindauer im Bereich charakteristischer Klimazonen der Erde.

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Summary The present study of radiation climatology, exclusively basing on results of measurements, presents selected examples of contrary large-scale climatic conditions and examines the typical features of the annual variation of global radiation (T) and diffuse sky radiation (D). Supplementary considerations on frequency statistics refer to the peculiarities in the behaviour of these two radiation elements in different geographical areas. It results that beside the seasonal variation frequency distributions ofT andD can be used for a characterization of radiation climates. The seasonal variation of the characteristic ratioD/T in the main climatic zones of the earth is of particular interest. Furthermore, the latitudinal dependency of global radiation (T), diffuse sky radiation (D) and of the ratioD/T is discussed. As to the dependence on altitude the ratioD/T shows a decrease in temperate latitudes on account of the behaviour ofD andT. Finally climatological reflections on the dependence of the ratioD/T on the duration of sunshine in characteristic climatic regions of the earth are discussed.

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Résumé La présente étude de la climatologie du rayonnement a pour but de déterminer les propriétés typiques de l'évolution annuelle du rayonnement global (T) et du rayonnement diffus du ciel (D) et cela exclusivement sur la base de mesures faites et d'exemples choisis parmi des climats très différenciés. En complément, on prend en considération des statistiques de la fréquence des particularités de ces deux éléments à l'intérieur d'aires géographiques de climats divers. On en déduit que, à côté de l'évolution annuelle, la répartition des fréquences deT et deD permettent d'établir le type du climat. L'évolution saisonnière du rapportD/T est tout spécialement intéressant dans les principales zones climatiques de la terre. On considère ensuite la dépendance du rayonnement global (T), du rayonnement diffus du ciel (D) et du rapportD/T de la latitude du lieu. Dans les zones tempérées, le quotientD/T diminue avec l'altitude. L'auteur termine par des réflexions concernant la climatologie du rayonnement en relation avec la dépendance du rapportD/T de la durée d'insolation dans des zones climatiques caractéristiques de notre planète.

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