Palynofacies and sea-level changes in the Upper Cretaceous of the Vocontian Basin, southeast France

Upper Cretaceous platform carbonates of the Vocontian Basin (southeastern France) have been investigated in a cross-section from the proximal deposits exposed in the lower Rhône Valley to the distal part of the basin in the Southern Subalpine Ranges north of Nice. The stratigraphic interval studied in detail spans the uppermost Turonian and Coniacian.Palynofacies patterns were used to detect eustatic signals at a third-order scale and are the tool for correlation of proximal and distal platform deposits. The organic constituents observed in the studied samples have been grouped into a continental fraction, including higher plant debris (phytoclasts) and sporomorphs, and a marine fraction with dinoflagellate cysts, acritarchs, prasinophytes, and foraminiferal test linings. The main factors influencing the stratigraphic and spatial distribution of land-derived, allochthonous, and marine, relatively autochthonous, organic particles are the proximity of land, the organic productivity, the degree of biodegradation and the hydrodynamic conditions of the depositional system. Palynofacies parameters used for the sequence stratigraphic interpretation are: (1) the ratio of continental to marine constituents (CONT/MAR ratio); (2) the ratio of opaque to translucent phytoclasts (OP/TR ratio); (3) the phytoclast particle size and shape; and (4) the relative proportion and species diversity of marine plankton. Ternary diagrams illustrating significant proximality changes were used to decipher transgressive-regressive trends within the succession.High amounts of translucent phytoclasts and decreasing values of the CONT/MAR ratio occur during the phase of relative sea-level rise in the upper Turonian. The stratigraphic interval of maximum flooding around the Turonian/Coniacian boundary is marked by the highest abundance and species diversity of dinoflagellate cysts, and by high percentages of opaque, equidimensional particles within the phytoclast group. The OP/TR ratio is still high within the lower Coniacian representing the early highstand deposits, whereas the relative abundance of marine constituents is again decreasing. Sedimentary organic matter of the upper Coniacian is dominated by large, blade-shaped, mainly opaque phytoclasts, which are a characteristic palynofacies signature of late highstand deposits.The present study demonstrates the high potential of palynofacies analysis in high-resolution stratigraphy and correlation of sedimentary series of shallow epeiric seas.     

Organic carbon deposition and phosphorus accumulation during Oceanic Anoxic Event 2 in Tarfaya, Morocco

With a multi-proxy approach, an attempt was made to constrain productivity and bottom-water redox conditions and their effects on the phosphorus accumulation rate at the Mohammed Plage section on the Tarfaya coast, Morocco, during the Cenomanian-Turonian Anoxic Event (OAE 2). A distinct δ¹³C_org isotope excursion of +2.5‰ occurs close to the top of the section. The unusually abrupt shift of the isotope excursion and disappearance of several planktonic foraminiferal species (e.g. Rotalipora cushmani and Rotalipora greenhornensis) in this level suggests a hiatus of between 40–60 kyrs at the excursion onset. Nevertheless, it was possible to determine both the long-term environmental history as well as the processes that took place immediately prior to and during OAE 2. TOC% values increase gradually from the base of the section to the top (from 2.5% to 10%). This is interpreted as the consequence of a long-term eustatic sea-level rise and subsidence causing the encroachment of less oxic waters into the Tarfaya Basin. Similarly a reduction in the mineralogically constructed ‘detrital index’ can be explained by the decrease in the continental flux of terrigenous material due to a relative sea-level rise. A speciation of phosphorus in the upper part of the section, which spans the start and mid-stages of OAE 2, shows overall higher abundances of P_reactive mass accumulation rates before the isotope excursion onset and lower values during the plateau. Due to the probable short hiatus, the onset of the decrease in phosphorus content relative to the isotope excursion is uncertain, although the excursion plateau already contains lower concentrations. The C_org/P_total and V/Al ratios suggest that this reduction was mostly likely caused by a decrease in the available bottom oxygen content (probably as a result of higher productivity) and a corresponding fall in the phosphorus retention ability of the sediment. Productivity appears to have remained high during the isotope plateau possibly due to a combination of ocean-surface fertilisation via increased aridity (increased K/Al and Ti/Al ratios) and/or higher dissolved inorganic phosphorus content in the water column as a result of the decrease in sediment P retention. The evidence for decreased P-burial has been observed in many other palaeoenvironments during OAE 2. Tarfaya's unique upwelling paleosituation provides strong evidence that the nutrient recycling was a global phenomenon and therefore a critical factor in starting and sustaining OAE 2.     

Preliminary results for a semi-automated quantification of site effects using geomorphometry and ASTER satellite data for Mozambique,Pakistan and Turkey

Estimation of the degree of local seismic wave amplification (site effects) requires precise information about the local site conditions. In many regions of the world, local geologic information is either sparse or is not readily available. Because of this, seismic hazard maps for countries such as Mozambique, Pakistan and Turkey are developed without consideration of site factors and, therefore, do not provide a complete assessment of future hazards. Where local geologic information is available, details on the traditional maps often lack the precision (better than 1:10,000 scale) or the level of information required for modern seismic microzonation requirements. We use high-resolution (1:50,000) satellite imagery and newly developed image analysis methods to begin addressing this problem. Our imagery, consisting of optical data and digital elevation models (DEMs), is recorded from the ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) sensor system. We apply a semi-automated, object-oriented, multi-resolution feature segmentation method to identify and extract local terrain features. Then we classify the terrain types into mountain, piedmont and basin units using geomorphometry (topographic slope) as our parameter. Next, on the basis of the site classification schemes from the Wills and Silva (1998) study and the Wills et al (2000) and Wills and Clahan (2006) maps of California, we assign the local terrain units with V _s 30 (the average seismic shear-wave velocity through the upper 30m of the subsurface) ranges for selected regions in Mozambique, Pakistan and Turkey. We find that the applicability of our site class assignments in each region is a good first-approximation for quantifying local site conditions and that additional work, such as the verification of the terrain’s compositional rigidity, is needed.     

Paleomagnetism and Detrital Zircon Geochronology of the Upper Vindhyan Sequence, Son Valley and Rajasthan, India: A ca. 1000 Ma Closure age for the Purana Basins?

The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including ⁸⁷Sr/⁸⁶Sr and δ ¹³C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α₉₅ = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α₉₅ = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period.     

Late Quaternary Bison diminution on the Great Plains of North America: evaluating the role of human hunting versus climate change

Body size changes of Bison and mortality age structure data document the effects of climate-driven environmental change and human hunting pressure on large mammals in North America. Morphometric and mortality data are drawn from 58 archaeological and 9 paleontological localities dating between 37,000 and 250 calBP. Proxy information on body size is based on measurements recorded on 901 adult calcanei (os calcis) and 1026 humeri. In addition, published mortality profiles from 24 archaeological faunal assemblages spanning the last 14,000 years were used to approximate the age structure of bison populations. These results suggest that dramatic diminution in bison body size occurred in several short bursts, rather than a continuous gradual decline. These periods of rapid size reduction correlate with times of ecological reorganization, when aridity-driven changes in grasslands decreased forage quality and availability. Mortality age data indicate that the decrease in body size occurred in a context where there was no evidence for a progressively severe juvenile bias in bison populations. Overall, it appears that the changes in body size were a reaction to environmental conditions rather than the result of human predation pressure.     

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.     

Soil contamination from urban and industrial activity: example of the mining district of Linares (southern Spain)

The Linares region (southern Spain) has been subjected to two important sources of pollution: the intensive mining works and the urban-industrial activity. To obtain a geochemical characterisation of the soil, 31 trace elements were analysed and 669 soil samples were collected. By means of clustering analysis, we identified groups of elements and grid squares in which relations could be established concerning soil lithology, urban and industrial activities and the degree of pollution impact; in addition, we were able to characterise the geochemical background of the study area. The multivariate study led us to identify four factors. Particularly important was factor 2, which represented the elements associated with mineral paragenesis (Cu, Pb, As, Co, Mn, Zn, Sn, Ba). This factor also contains elements related with an urban-industrial activity, such as Pb, Cu, Zn, As and Ba. Furthermore, we identified factor 4, associating Ni, V and Cr, and which is related to the use of fuels.     

Determining effective wellbore permeability from a field pressure test: a numerical analysis of detection limits

We propose a simple pressure test that can be used in the field to determine the effective permeability of existing wellbores. Such tests are motivated by the need to understand and quantify leakage risks associated with geological storage of CO₂ in mature sedimentary basins. If CO₂ is injected into a deep geological formation, and the resulting CO₂ plume encounters a wellbore, leakage may occur through various pathways in the “disturbed zone” surrounding the well casing. The effective permeability of this composite zone, on the outside of the well casing, is an important parameter for models of leakage. However, the data that exist on this key parameter do not exist in the open literature, and therefore specific field tests need to be done in order to reduce the uncertainty inherent in the leakage estimates. The test designed and analyzed herein is designed to measure effective wellbore permeability within a low-permeability caprock, bounded above and below by permeable reservoirs, by pressurizing the reservoir below and measuring the response in the reservoir above. Alternatively, a modified test can be performed within the caprock without directly contacting the reservoirs above and below. We use numerical simulation to relate pressure response to effective well permeability and then evaluate the range of detection of the effective permeability based on instrument measurement error and limits on fracture pressure. These results can guide field experiments associated with site characterization and leakage analysis.     

Space–time distribution of ancient and active alluvial karst subsidence: examples from the central Ebro Basin,Spain

Space and time variations of alluvial karst subsidence in the central Ebro Basin are analysed in trenches (paleodolines), aerial photographs (historical dolines) and field surveys (present-day active dolines). The measured subsidence rates, as well as a comparison between densities of paleodolines computed in randomly selected scan-lines and density of active dolines computed in maps, suggest that present-day subsidence in favourable areas is more intense than that of Pleistocene times. According to diachronic maps drawn from (a) different aerial photographs taken after 1946 and (b) field surveys on deformations in urbanized areas, subsidence behaved as a nearly steady process while the whole area was used for agriculture. In contrast, rapid changes (through periods of several tens of years) have occurred in urbanized areas, in which dolines expand their boundaries through small marginal collapses, shifting sharply their sinking centres to neighbouring sites. These rapid changes do not have an equivalent in observed paleodolines.     

Environmental risk evaluation of the use of mine spoils and treated sewage sludge in the ecological restoration of limestone quarries

The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality, came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications. Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium, phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values obtained were very elevated.