The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.     

The Hissar–Alay and the Pamirs: Deep-Seated Structure,Geodynamic Model,and Experimental Evidence

The structural and geodynamic features of the Pamirs and the Hissar–Alay have been revealed based on geological and geophysical evidence supplemented by experimental data. It has been shown that both the Pamirs and the Hissar–Alay are geodynamic systems, the formation of which is related to interference of two geodynamic regimes: (i) global orogeny covering extensive territories of Eurasia and determining their similarity and (ii) regional regimes differing for the Pamirs and the Alay, which act independently within Central Asian and Apline–Himalayan mobile belts, respectively. The Pamirs do not act as an indentor during the formation of structure of the Hissar–Alay and areas to the north. It is stated that the Pamir–Alay segment of Asia is a reflection of the geodynamic countermotion setting (3D flow of mountain masses) of several distinct segments of the continental lithosphere, while the Pamirs are an intracontinental subduction domain at the surface, which represents a special tectonic–geodynamic type of structures.     

Composition,Age, and Origin of Cretaceous Granitic Magmatism on the Eastern Chukchi Peninsula

New geochronological and isotopic geochemical data are given, which make it possible to recognize two types of granitic rocks on the eastern Chukchi Peninsula. Early Cretaceous Tkachen and Dolina granitic plutons with zircon ages (U–Pb SIMS) of 119–122 and 131–136 Ma are related to the first type. They cut through Devonian–Lower Carboniferous basement rocks and are overlain by the Aptian–Albian Etelkuyum Formation. Basal units of the latter contain fragments of granitic rocks. Late Cretaceous Provideniya and Rumilet granitic plutons, which contain zircons with ages of 94 and 85 Ma (U–Pb SIMS), respectively, belong to the second type. They cut through volcanic–sedimentary rocks of the Etelkuyum and Leurvaam formations pertaining to the Okhotsk–Chukotka Volcanic Belt. In petrographic and geochemical features, the Early Cretaceous granitic rocks of the Tkachen Pluton are commensurable with I-type granites, while Late Cretaceous granite of the Rumilet Pluton is comparable to A₂-type granite. The Sr–Nd isotopic data provide evidence that from the Early Cretaceous Tkachen and Dolina plutons to the Late Cretaceous Provideniya and Rumilet plutons, the degree of crustal assimilation of suprasubduction mantle-derived melts increases up to partial melting of heterogeneous continental crust enriched in rubidium. An unconformity and various degrees of secondary alteration of volcanic–sedimentary rocks have been established in the Okhotsk–Chukotka Volcanic Belt, and this was apparently caused by transition of the tectonic setting from suprasubduction to a transform margin with local extension.     

Deformations and Manifestations of Degassing in the Sedimentary Cover of the Equatorial Segment of the West Atlantic: Implications for Lithospheric Geodynamics

Manifestations of fluids and deformations in the sedimentary cover, which are both factors of brightening (blanking anomalies) in seismoacoustic records, in the equatorial segment of the Atlantic coincide with the sublatitudinal zones of the activated passive parts of transform faults and with zones of lower gravity anomalies and higher values of remnant magnetization, which form as a result of serpentinization. The cause-and-effect sequence of intraplate phenomena includes: the contrasting geodynamic state → horizontal movements that form macrofractures → water supply to the upper mantle → serpentinization of rocks in the upper mantle → deformations associated with vertical uplift of basement and sedimentary cover blocks, coupled with fluid generation → and fluid accumulation in the sedimentary cover, accompanied by the formation of anomalies in seismoacoustic records. Based on the seismic data, we have identified imbricate-thrust deformations, diapir structures, stamp folds, and positive and negative flower structures, indicating the presence of strike-slip faults in the passive parts of transform faults. The general spatial distribution of deformation structures shows their concentration in cold mantle zones. Correlative comparison of the structural characteristics of deformations shows the direct relationship between the heights of structures and the development of serpentinization processes. As per the age of the basement, deformations range from 27–38 to 43–53 Ma; a quite thick sedimentary cover makes it possible to reveal them based on the characteristic types of seismoacoustic records. The formation of the Antilles arc ca. 10 Ma ago affected the equatorial segment of the Atlantic; it formed kink bands where lithospheric blocks underwent displacements with counterclockwise rotations, deformations related to compression and vertical uplift of crustal fragments, and local extension that favored degassing of endogenous fluids. Sublatitudinally oriented imbricate-thrust deformations with different vergences indicate irregularity and alternating strike-slip directions as blocks between fractures were laterally influenced.     

The Tendencies of the Development of the Mineral-Resources Sector at the Turn of the Century

Important tendencies in development of the world mineral-resources sector at the beginning of the 21st century were an increase in production and consumption of mineral materials differentiated by types of metals and nonmetallic mineral raw materials, by countries and regions, as well as the concentration of the production of mineral raw materials in a small number of countries, and a reduction in industrial reserves of minerals in the world economy, even at the current stage of their extraction. These tendencies should be taken into account in working out a strategy for development of the Russian mineral raw-material base.     

The Correlation of the Upper Cretaceous Zonal Schemes of the Eastern European Platform Based on Foraminifera,Radiolaria, and Nannoplankton

This article proposes a biostratigraphic scheme for the Upper Cretaceous of the East European Platform on the basis of the distribution in the sections of three groups of microfossils: foraminifera (both planktonic and benthic), radiolarians, and nannoplankton. Most of the stage and substage boundaries are confirmed by macropaleontological data. The most divided units are those distinguished based on benthic foraminifers and nannoplankton. The diversity of these microfossils and their constant presence allowed us to identify zones and subzones, while it is possible to subdivide only the beds by planktonic foraminifers and radiolarians. The most favorable stages in the development of plankton biota can be considered the Turonian–Coniacian interval when the basins of the East European Platform experienced an intensive influence from warm waters of the Tethys Ocean. The global Campanian cooling is clearly recorded, which affected the taxonomic diversity of all microfossil groups.     

The Effect of Aggregation of Impurity Nitrogen on Diamond X-Ray Luminescence

Two samplings of 65 diamond crystals divided by the intensity of a slow X-ray luminescence component are studied from the Arkhangel’skaya and Karpinskogo-1 pipes. IR and EPR spectroscopies revealed a relationship between the nitrogen A and P2 centers of the diamonds and the presence of a slow X-ray luminescence component. Its absence in most diamonds with high content of P1 (C) centers is explained by the low number of A and P2 centers.     

Biosorption of Rare-Earth Elements and Yttrium by Heterotrophic Bacteria in an Aqueous Environment

This paper reports the results of the experimental determination of the coefficient of sorption of rare-earth elements and yttrium (REY) under conditions of acidic pH using several strains of heterotrophic bacteria (Microbacterium sp., Curtobacterium sp., Bacillus subtilis, Pseudomonas putida, and Bacillus pumilis) that are widespread in natural and technogenic waters of the Far East (Russia). Insignificant fractionation between heavy and light rare-earth elements, negative cerium and dysprosium anomalies, and a positive europium anomaly were revealed. The selectivity of REY biosorption by gram-positive and gram-negative bacteria, as well as inertia of the biosorption process under more acidic conditions of the medium, were shown.     

Integrated Geophysical Works on the Kozlovka Anomaly (Kaluga Region)

This work presents integrated geophysical studies that were carried out to identify the nature of the intense magnetic anomaly detected by the results of land surveying on the right bank of the Slushka River in the territory of the Yukhnovskii district of Kaluga Region. The comprehensive interpretation of the geophysical data and the laboratory measurements of the core made it possible to determine the nature and parameters of the anomaly-forming object that is located in the upper part of the section; it consists of loams that contain such magnetic minerals as greigite, pyrrhotite, and magnetite.     

The Structure and Formation Conditions of the Bedenekir Formation Deposits (Thithonian Stage) of Mountainous Crimea

The composition and origin of the Bedenekir Formation deposits of Mountainous Crimea are detailed on the basis of our work results and analysis of both published and unpublished data.