Simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation: conditions for precise shipboard measurements

Appropriate conditions have been achieved for the accurate, rapid, and highly precise shipboard simultaneous determination of dissolved organic carbon and total dissolved nitrogen in seawater by high temperature catalytic oxidation. A nitrogen-specific Antek 705D chemiluminescence detector and a CO₂-specific LiCor Li6252 IRGA have been coupled in-series with a Shimadzu TOC-5000 organic carbon analyser. Precision of both simultaneous measurements is ≤1.5%, i.e. ±1 μmol C l⁻¹ and ±0.3 μmol N l⁻¹, respectively. Quality of analysis is not compromised by vibrations associated with ocean going research vessels.     

A new look at the alkalinity of the Sea of Japan

The most important feature of the distribution of the alkalinity and calcium in the Sea of Japan—the increase in the potential alkalinity with depth under the conditions when the waters are supersaturated in relation to calcium carbonate—is considered. It is demonstrated that this fact cannot be accounted for by the reaction of the formation-dissolution of calcium carbonate. A new concept explaining the alkalinity distribution in the sea is proposed. According to it, the biological pump is the basic process responsible for the alkalinity transport from the euphotic layer into the interior of the sea. Photosynthesis is the driving force for this process. The role of the active element transporting the alkalinity is not calcium carbonate, as has been claimed elsewhere, but extracellular polysaccharides (EPSs) produced by phytoplankton. EPSs bind to calcium and other cations to form transparent exopolymer particles (TEPs). The proposed conception makes it possible to explain the following: (a) the vertical flux of calcium carbonate that is independent of the super-saturation—undersaturation state of the ambient water regarding calcium carbonate; (b) the existence of the calcium carbonate flux regardless of the nature of the plankton skeletons; (c) the nonstoichiometric ratio between the alkalinity and calcium fluxes.     

The relationship between the behavioral activity and the underwater vocalization of the beluga whale (<Emphasis Type="Italic">Delphinapterus leucas</Emphasis>)

The underwater vocalizations of the beluga whale summering in Onega Bay (64°24′N, 35°49′E) were recorded in June–July of 2008. The vocalizations were classified into five major whistle types, four types of pulsed tones, click series, and noise vocalizations. To determine the relationship between the behavioral activity and the underwater vocalizations, a total of fifty-one 2 minute-long samples of the audio records were analyzed in the next six behavioral contexts: directional movements, quiet swimming, resting, social interactions, individual hunting behavior, and the exploration of hydrophones by beluga whales. The overall vocalization rate and the percentage of the main types of signals depend on the behavior of the belugas. We suggest that one of the whistle types (the “stereotype whistle”) is used by belugas for long-distance communications, while other whistle types (with the exception of “squeaks”) and three types of pulsed tones (with the exception of “vowels”) are used for short distance communication. The percentage of “squeaks” and “vowels” was equally high in all the behavioral situations. Thus, we assume that “squeaks” are contact signals. “Vowels” have a specific physical structure and probably play a role in identification signals. A high rate of the click series was observed in the process of social interactions.     

Delivery of chemical elements with atmospheric precipitations to the coastal regions of the Crimea in 2004–2008

We study the space-and-time variations of the delivery of fluxes of 26 elements (Na, K, Rb, Cs, Cu, Ag, Au, Ca, Sr, Ba, Zn, Cd, Hg, Hf, Ta, As, Sb, Cr, Se, Mo, W, Mn, Br, Fe, Co and Ni) with atmospheric precipitations to the sea surface in the regions of Sevastopol and the South Coast of Crimea. It is established A series of general regularities of the delivery of the sum of these elements and their soluble and insoluble forms. We also give the characteristics of their space-time variability.     

Two types of alkaline volcanics in the southwestern Iberian margin: The causes of their diversity

The diverse geodynamic conditions of the parental magma??s melting are responsible for the compositional diversity of the alkaline volcanics near the southwestern margin of Iberia. The petrological-geochemical data show that the volcanics of the Gorringe Bank originated within the continental plate. The parental melilitite melts depleted in silica and anomalously enriched with trace elements could have been generated only in deep settings with a low degree of metasomatically enriched mantle matter melting. The volcanic melilitite-nephelinite-phonolite series is widespread in alkaline provinces of the Eurasian, African, and other continental plates. The Ampere, Josephine, and other seamounts and islands of the region are largely composed of volcanic rocks belonging to the picrobasalt-hawaiite-mugearite association. Their parental magmas were generated within the oceanic plate at shallower depths under a higher degree of moderately enriched oceanic lithospheric mantle melting. Both series of volcanics were formed under the influence of mantle plumes.     

Caspian Sea Level Fluctuations in the Neopleistocene (Was There an Atelian Regression?)

The article deals with deposits exposed in sections along the rivers of the Caspian lowland and on the eastern slope of the Ergenei. The conclusion is made about the lagoonal origin of chocolate clays lying on high-capacity subaerial and alluvial–deltaic deposits. The impact of the Caspian Sea level rise on coastal processes is examined. Taking into account the regularities in the behavior of the coastal zone during sea level rise, subaerial deposits with such thickness in the outcrops could not have been preserved during the early Khvalynian transgression from –100 m. Another curve of Caspian Sea level fluctuations is proposed, where there is no deep Atelian regression between the Khazarian and Khvalynian transgressions. It is concluded that the Khazarian transgression was one of the largest in the history of the Caspian Sea. Its level was slightly less than that of the Khvalynian transgression. The rise of the level of the latter began not from –100 m, but from about 5–15 m; i.e., this transgression was in fact an oscillation of the Caspian Sea against its gradual regression after the Khazarian transgression. Sea level oscillations contributed to the formation of lagoonal-transgressive terraces, in which chocolate clays accumulated.

     

The Ctenophore,Beroe ovata Bruguière, 1789 – the New Invader in the Ecosystem of the Caspian Sea

Oceanology - In November 2020, the invasive ctenophore Beroe ovata Bruguière, 1789 was recorded in samples of gelatinous zooplankton from the northern and central parts of the Caspian Sea. The...     

On Termodynamics of Kolmogorov’s Scaling in Turbulence

Izvestiya, Atmospheric and Oceanic Physics - The model balance equation of turbulence is represented in the form of the first law of thermodynamics. The forms for entropy are derived with an...     

Experience of Studying the Turbulent Structure of the Atmospheric Boundary Layer Using an Unmanned Aerial Vehicle

Izvestiya, Atmospheric and Oceanic Physics - The growing relevance of the use of unmanned aerial vehicles (UAVs) for studying turbulence in the atmospheric boundary layer (ABL) is associated with...     

Comparative Analysis of Arctic Sea Ice Area Derived from Satellite Microwave Radiometry Data (VASIA2 Algorithm) with Ice Charts of the Arctic and Antarctic Research Institute

Izvestiya, Atmospheric and Oceanic Physics - The Arctic Sea ice area, calculated by the VASIA2 algorithm using the SSMIS data during the most intensive melting of the ice cover in 2019, is compared...