Timing and tectonic setting of Grenvillian metamorphism—constraints from a transect along Georgian Bay,Ontario*

Systematic mapping of a transect along the well-exposed shores of Georgian Bay, Ontario, combined with the preliminary results of structural analysis, geochronology and metamorphic petrology, places some constraints on the geological setting of high-grade metamorphism in this part of the Central Gneiss Belt. Correlations within and between map units (gneiss associations) have allowed us to recognize five tectonic units that differ in various aspects of their lithology, metamorphic and plutonic history, and structural style. The lowest unit, which forms the footwall to a regional decollement, locally preserves relic pre-Grenvillian granulite facies assemblages reworked under amphibolite facies conditions during the Grenvillian orogeny. Tectonic units above the decollement apparently lack the early granulite facies metamorphism; out-of-sequence thrusting in the south produced a duplex-like structure. Two distinct stages of Grenvillian metamorphism are apparent. The earlier stage (c. 1160–1120 Ma) produced granulite facies assemblages in the Parry Sound domain and upper amphibolite facies assemblages in the Parry Island thrust sheet. The later stage (c. 1040–1020 Ma) involved widespread, dominantly upper amphibolite facies metamorphism within and beneath the duplex. Deformation and metamorphism recently reported from south and east of the Parry Sound domain at c. 1100–1040 Ma have not yet been documented along the Georgian Bay transect. The data suggest that early convergence was followed by a period of crustal thickening in the orogenic core south-east of the transect area, with further advance to the north-west during and after the waning stages of this deformation.     

The significance of Messinian occurrences of Globorotalia margaritae and Globorotalia puncticulata in Sicily

Globorotalia puncticulata and Globorotalia margaritae are critical species that define internationally recognized planktonic foraminiferal biozones in the Pliocene. These biozones are defined from stratotype sections on Sicily and their fauna are commonly considered to have been introduced to the Mediterranean after an influx of Atlantic water that terminated the late Miocene desiccation of the basin. Herein new discoveries of these species in rocks that predate the late Miocene desiccation are described. These data are supported by magneto- and lithostratigraphy that have been integrated at a single continuous section. Not only do these discoveries question the existing foraminiferal biozone stratigraphy, they also suggest new models for the dispersal of planktonic species. It is proposed that Globorotalia puncticulata and perhaps even Globorotalia margaritae evolved in the Mediterranean during earliest Messinian times (during or before chron C3Bn1n) and dispersed into the Atlantic. This suggests that a marine connection remained between the two sea areas until at least chron C3An.1n. Using the existing geomagnetic polarity time scale, these occurrences are some 2 Myr earlier than previously recorded in the Mediterranean. The distribution of G. margaritae and G. puncticulata in Mediterranean sections is likely to reflect palaeoenvironment or the preservation of deposits rather than the absolute age of the sediments.     

Oil-weathering behavior in Arctic environments

Oil-weathering processes in ice-free subarctic and Arctic waters include spreading, evaporation, dissolution, dispersion of whole-oil droplets into the water column, photochemical oxidation, water-in-oil emulsification, microbial degradation, adsorption onto suspended particulate material, ingestion by organisms, sinking, and sedimentation. While many of these processes also are important factors in ice-covered waters, the various forms of sea ice (depending on the active state of ice growth, extent of coverage and/or decay) impart drastic, if not controlling, changes to the rates and relative importance of different oil-weathering mechanisms. Flow-through seawater wave-tank experiments in a cold room at −35°C and studies in the Chukchi Sea in late winter provide data on oil fate and effects for a variety of potential oil spill scenarios in the Arctic. Time-series chemical weathering data are presented for Prudhoe Bay crude oil released under and encapsulated in growing first-year columnar ice through spring breakup.     

Isobaric cooling and anti-clockwise P–T paths in the Variscan Odenwald Crystalline Complex, Germany

Mineral assemblages in Al₂O₃‐rich, SiO₂‐ and K₂O‐poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid‐German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re‐equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure‐temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low‐P/high‐T conditions and underwent an anti‐clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near‐isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti‐clockwise evolution in a subduction‐related magmatic arc setting. The close spatial association of the low‐P/high‐T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides.     

Rapid vegetation change during the early Holocene in the Faroe Islands detected in terrestrial and aquatic ecosystems

High‐resolution pollen, plant macrofossil and sedimentary analyses from early Holocene lacustrine sediments on the Faroe Islands have detected a significant vegetation perturbation suggesting a rapid change in climate between ca. 10 380 cal. yr BP and the Saksunarvatn ash (10 240±60 cal. yr BP). This episode may be synchronous with the decline in δ¹⁸O values in the Greenland ice‐cores. It also correlates with a short, cold event detected in marine cores from the North Atlantic that has been ascribed to a weakening of thermohaline circulation associated with the sudden drainage of Lake Agassiz into the northwest Atlantic, or, alternatively, a period with distinctly decreased solar forcing. The vegetation sequence begins at ca. 10 500 cal. yr BP with a succession from tundra to shrub‐tundra and increasing lake productivity. Rapid population increases of aquatic plants suggest high summer temperatures between 10 450 and 10 380 cal. yr BP. High pollen percentages, concentrations and influx of Betula, Juniperus and Salix together with macrofossil leaves indicate shrub growth around the site during the initial phases of vegetation colonisation. Unstable conditions followed ca. 10 380 cal. yr BP that changed both the upland vegetation and the aquatic plant communities. A decrease in percentage values of shrub pollen is recorded, with replacement of both aquatics and herbaceous plants by pioneer plant communities. An increase in total pollen accumulation rates not seen in the concentration data suggests increased sediment delivery. The catchment changes are consistent with less seasonal, moister conditions. Subsequent climatic amelioration reinitiated a warmth‐driven succession and catchment stabilisation, but retained high precipitation levels influencing the composition of the post‐event communities. Copyright © 2003 John Wiley & Sons, Ltd.     

SANICLAY: simple anisotropic clay plasticity model

SANICLAY is a new simple anisotropic clay plasticity model that builds on a modification of an earlier model with an associated flow rule, in order to include simulations of softening response under undrained compression following K_o consolidation. Non‐associativity is introduced by adopting a yield surface different than the plastic potential surface. Besides, the isotropic hardening of the yield surface both surfaces evolve according to a combined distortional and rotational hardening rule, simulating the evolving anisotropy. Although built on the general premises of critical state soil mechanics, the model induces a critical state line in the void ratio–mean effective stress space, which is a function of anisotropy. To ease interpretation, the model formulation is presented firstly in the triaxial stress space and subsequently, its multiaxial generalization is developed systematically, in a form appropriate for implementation in numerical codes. The SANICLAY is shown to provide successful simulation of both undrained and drained rate‐independent behaviour of normally consolidated sensitive clays, and to a satisfactory degree of accuracy of overconsolidated clays. The new model requires merely three constants more than those of the modified Cam clay model, all of which are easily calibrated from well‐established laboratory tests following a meticulously presented procedure. Copyright © 2006 John Wiley & Sons, Ltd.