Protein carbonyls and antioxidant defenses in corkwing wrasse (Symphodus melops) from a heavy metal polluted and a PAH polluted site

The use of fish in environmental monitoring has become increasingly important in recent years as anthropogenic substances, many of which function as prooxidants, are accumulating in aquatic environments. We have measured a battery of antioxidant defenses as a measure of oxidative status, as well as protein carbonylation as a measure of oxidative damage, in corkwing wrasse (Symphodus melops) captured near a disused copper mine, where water and sediment are contaminated with heavy metals, and an aluminum smelter, a site contaminated with PAHs. Results were compared to two different reference sites. Fish at the heavy metal site had lower glucose-6-phosphate dehydrogenase activity and elevated protein carbonyls (1.8 times) compared to fish from the reference site. At the PAH site, EROD was increased 2-fold, while total glutathione and methemoglobin reductase concentration, were decreased. No differences were seen in protein carbonyl levels at the PAH site. Measures of both antioxidant defenses and oxidative damage should be used when assessing effects of xenobiotics on oxidative stress in fish species.     

Size-fractionated uranium isotopes in surface waters in the Jiulong Estuary in China

Surface water was collected from the Jiulong Estuary for determination of activity concentrations of uranium isotopes in different size fractions, namely, greater than 53, 10 -53, 2 - 10, 0.4 -2 μm, 10 000 u -0.4 μm and less than 10 000 u fractions by microfihration and cross-flow uhrafiltration technologies. Results indicated that most of the dissolved uranium （ 〈 0.4 μm） exis- ted in the low molecular mass fraction （ 〈 10 000 u）, and the colloidal uranium-238 （10 000 u -0.4 μm） only contributed less than 1% of the dissolved uranium-238. The fractions of colloidal uranium in the dissolved phases decreased with the increasing sa- linity. A positive linear relationship between uranium-238 activities and salinities was observed for the dissolved, colloidal and low molecular mass fractions, indicating a conservative behavior of uranium in the Jiulong Estuary. In the particulate phases （ 〉 0.4 μm）, the partitioning of uranium isotopes among different size fractions was controlled by the partitioning of particle concentrations. In the regions with salinities below 20, the partitioning of uranium-238 among different size fractions was as follows： 10 - 53 μm 〉 2 - 10 μm 〉 0.4 - 2 μm greater than above 53 μm. However, the order at the offshore station with salinities above 30 changed as follows ： 0.4 - 2 μm 〉 10 - 53 μm 〉 2 - 10 μm greater than above 53 μm. The fraction of the 0.4 - 2 μm particles increased at the offshore station, suggesting the increased contribution of the authigenic uranium. The activity ratio of uranium-234 to uranium-238 in the dissolved phases, including the low molecular mass fraction and the colloidal fraction, was larger than unity, showing the occurrence of excess uranium-234. In contrast, the activity ratio of uranium-234 to uranium-238 in all size fractions of the particulate phase was close to the equilibrium value （1.0）. The observed different values of the activity ratio of uranium-234 to uranium-238 in the dissolved phase and the partic     

芬兰湾中的神秘群岛

看一眼列宁格勒区的地图,不难发现,芬兰湾北部沿岸的海岸线被切割得极深。大量的岛屿、礁石、半岛和海湾形成了芬诺斯坎迪亚典型的断崖地貌景观,后者被认为是芬兰湾北岸自然组合的样本。     

南极Scotia海Dove山脉形成的火山作用及其岩石学、地球化学和构造环境

本研究对来自DOVE盆地（Scotia海南部）中部火山山脊的拖网样品进行了详细的岩石学、地球化学分析,辅以K—Ar年代学分析。研究区水深2000～3000m,地理坐标范围为59°21～23′S和42°27～31′w。本研究的目的在于,通过比较研究区火成岩和形成Scotia、Antartic—Phoenix洋中脊及南设得兰群岛的火山岩之间的地球化学特征和同位素特征,厘定研究区岩浆形成的地球动力学背景以及岩浆作用的绝对年龄。     

全球石油资源估计及对21世纪石油产量的预测

将地球沉积盖层作为统一的系统,对全球常规可采石油资源进行概率估计,并对21世纪末之前的全球石油产量进行预测。结果表明全球石油产量最有可能在2020—2030年间达到高峰,每年42～47亿吨。届时主要的产区将在波斯湾、西西伯利亚和东西伯利亚,上游部门的注意力将转向北极陆架。至少到2040年前,年产量将维持在42—45亿吨水平。     

土壤剖面的磁学特征及其对交通污染的指示意义——以北京首都机场高速公路为例

对北京首都机场高速公路旁采集的土壤柱状T01剖面的磁学参数和金属元素分析,探讨了研究区内现代交通导致的土壤磁学性质的变化及其对环境污染的响应.结果表明,磁参数(χ,ARM和SIRM)与重金属含量呈同步垂向变化趋势.来源于交通运输排放的污染物是土壤剖面上部(0～8 cm)磁性和金属含量增强的主要原因,8cm以下,土壤基本未受到污染,磁性矿物和重金属含量较低,磁性颗粒变化稳定,基本代表了该地区土壤的自然背景.尽管土壤岩石磁学分析表明剖面上下部受污染和未受污染样品的磁载体均是粒度较粗的多畴磁铁矿,但是结合磁参数比值曲线,说明底部样品的磁颗粒的粒度较顶部偏细.磁性矿物的含量变化没有影响磁颗粒的粒度特征.指标聚类等相关分析表明,土壤磁参数(χ,ARM和SIRM)与重金属元素(Pb,Zn和Cu)含量显著相关;结合模糊聚类分析,磁参数可用于追踪、识别交通污染物质在土壤剖面中的富集、迁移状态,揭示不同深度土壤的污染程度.     

天然水中矿物溶解度的预测——25℃时高离子强度的Na-K-Mg-Ca-H-Cl-SO_4-OH-HCO_3-CO_3-H_2O体系

Harvie和Weare(1980)的矿物溶解度模型,被扩展到25℃时高浓度的8组份体系Na-K-Mg-Ca-H-Cl-SO_4-OH-HCO_3-CO_3-CO_2-H_2O。该模型就其水电解质溶液的热力学而言,是以Pitzer(1973)及其同事们的半经验公式为基础的。利用大量的适用于大多数亚体系的有效的等压、电动势及溶解度资料,把模型参数化。模型的推测能力,已通过体系中比参数化所用资料更为复杂的实验资料进行对比而证实。本文讨论了水电解质溶液的化学模型的基本特点和pH与溶液平衡特性之间的关系。     

蒸汽驱油强化采油过程的遥测

为了构造蒸汽驱油范围内重油砂的层析图像,需要得到井间地震速度及高频电磁(EM)衰减数据,用了初至地震波来构造两井间的一块10m宽、8m高的垂直平面的彩色层析图像，用两个高频（17及15MHz)EM透射层析构造了20m宽、8m高平面，速度层析图明显地指示了一面岩层、其上、下都有油砂，EM层析图则指示了一更复杂的有页岩夹层的油砂地质，最深的EM层析图显示出了活动蒸汽区的上部，并指出了页岩层下蒸汽运移的通道，这些结果显示了井间整个平面的详细结论，并提供了一更好的方法，来理解蒸汽驱油环境的原地重油回采工艺。     

环太平洋带构造地层地体

引言近年来,北美克迪勒拉是通过分离的构造地层地体增生而形成的这一认识已经得到可资利用的新的地质、地球物理和古生物资料的支持(Jones等,1981;Jonts等,1983;Coney等,1980;Davis等,1978;Balke等,1983)。同样的增生过程似乎也影响了环太平洋边缘的大部分地区。为了探讨这一假说,我们已经编制了初步的环太平洋地体图。本文的目的是回顾Coney等(1980)和Jones等(1983)所提出的地体分析