Evaluation of sampling devices for the determination of polycyclic aromatic hydrocarbons in surface microlayer coastal waters

The sea surface microlayer (SML) may play an important role on the transport and fate of persistent organic pollutants in the marine environment. In order to evaluate the appropriateness of a number of sampling devices for the analysis of 14 parent polycyclic aromatic hydrocarbons (3-5 aromatic rings), marine SML waters were sampled using a glass plate, a rotating drum/roller, a metal screen and a surface slick sampler. The underlying waters were also sampled for the determination of the corresponding enrichment factors (EF = [C](microlayer)/[C](underlying water)). The EFs were phase dependent, ranging from 1 to 3 for the dissolved phase and between 4 and 7 for the particulate phase. In order to better assess the performance of the different sampling methods, in terms of phase partitioning, the truly dissolved and colloidal phases were also estimated. Generally, no significant differences were found for the enrichment factors provided by the different methods, due to the observed large variability in concentrations that can be attributed to small-scale coastal processes. However, the metal screen is recommended as the most efficient sampling method for the study of PAHs taking into account the amount of water collected versus time.     

阿留申岛弧的非火山颤动

在阿留申岛弧观测到了一些非火山颤动。在数座火山上的大跨区的地震台网也监测到颤动状的事件,因此不可能与任何一座火山体有关。虽然目前还不能给这些颤动定位,但我们根据多个台网的反射时差和振幅给出了大概的位置。多数非火山颤动是在所推断的太平洋消减板块闭锁区或从蠕动到闭锁转换区记录到的。有一次非火山颤动事件是在拉特群岛和安德烈亚诺夫群岛附近地区地震活动和火山活动增强时期记录到的。类似的同步增加以往在阿留申群岛记录到过,并被假设是由慢滑动事件引起的大范围应力变化造成的。2008年7月12日奥克莫克火山喷发约1小时后在科罗文和大锡特金地震台网记录到显著的非火山颤动。非火山颤动并不是分散地出现在整个阿留申岛弧,而似乎是集中在几个地区。用2500km的消减带,我们有机会检查这些地区并将其与不产生非火山颤动地区加以比较,以便确定产生该颤动的作用因素。     

电子显微镜的摄影测量校准方法

由于多次的电子——光学投影，在电子显微镜中构成了影像。如果在投影时能保持正象立体条件的话，那么从几何观点将用投影方法获得电子——显微镜影像。     

An inverse procedure to estimate transmissivity from heads and SP signals

Experimental hydraulic heads and electrical (self-potential) signals associated with a pumping test were used in an inverse model to estimate the transmissivity distribution of a real aquifer. Several works reported in the literature show that there is a relatively good linear relationship between the hydraulic heads in the aquifer and electrical signals measured at the ground surface. In this experimental test field, first, the current coupling coefficient was determined by the best fit between experimental and modeled self-potential signals at the end of the pumping phase. Soon afterward, with the hydraulic heads obtained from the self-potential signals, the transmissivity distribution of the aquifer was conditioned by means an inverse model based on the successive linear estimator (SLE). To further substantiate the estimated T field from the SLE analysis, we analyzed the drawdown rate, the derivative of the drawdown with respect to the ln(t), because the drawdown rate is highly sensitive to the variability in the transmissivity field. In our opinion, these results show that self-potential signals allow the monitoring of subsurface flow in the course of pumping experiments, and that electrical potentials serve as a good complement to piezometric observations to condition and characterize the transmissivity distribution of an aquifer.     

地下水中氡底数和异常浓度的形成及其普查的意义

含氢地下水,即氢浓度增高的水(超过36爱曼),系矿水的一种,它可用于矿泉医疗。假如对地下水中氢的底数浓度和异常浓度的形成条件有正确的概念,那么这种水也能作为寻找放射性矿床的普查标志。促成地下水氢的富集的基本因素之一是被地下水冲洗的岩石中镭的绝对含量。但是,目前对岩石中放射性元素分布规律的知识尚很有限。尼柯诺夫认为,近十年来总趋势是:过去采用过的岩石中放射性元素含量值是下降,而且接近岩浆岩和沉积岩的平均值。从尼柯諾夫文章中借用的、并经维诺格拉多夫的资料加以补充的表l     

六价铀的比色测定

本文提出了一种新的极灵敏的试剂用于六价铀的比色测定。这个试剂的名称是1-苯-3-甲基-4-(3-羧基-4-羟基苯-偶氮)-吡-唑-5-酮。     

震后快速钻探:历史、现状与未来

大地震发生后立即在断层带上进行钻探可以帮助我们获取更多的地震信息,尤其是可获得决定断层动态破裂的摩擦水平和强度,观测断层的愈合过程及可能触发余震的应力变化,并可获取控制破裂过程的重要的物理和化学属性。在2008年11月由国际大陆科学钻探项目（ICDP）和南加州地震中心（SCEC）联合在日本东京举办的为期3天的“震后快速钻探：历史、现状与未来”研讨会上,     

Paleozoic Accretion-Collision Events and Kinematics of Ductile Deformation in the Eastern Part of the Southern-Central Tianshan Belt, China

The Tianshan range could have been built by both late Early Paleozoic accretion and Late Paleozoic collision events. The late Early Paleozoic Aqqikkudug-Weiya suture is marked by Ordovician ophiolitic melange and a Silurian flysch sequence, high-pressure metamorphic relics, and mylonitized rocks. The Central Tianshan belt could principally be an Ordovician volcanic arc; whereas the South Tianshan belt, a back-arc basin. Macro- and microstructures, along with unconformities, provide some kinematic and chronological constraints on 2-phase ductile deformation. The earlier ductile deformation occurring at ca. 400 Ma was marked by north-verging ductile shearing, yielding granulite-bearing ophiolitic melange blocks and garnet-pyroxene-facies ductile deformation, and the later deformation, a dextral strike-slip tectonic process, occurred during the Late Carboniferous-Early Permian. Early Carboniferous molasses were deposited unconformably on pre-Carboniferous metamorphic and ductilely sheared rocks, implying t     

柴北缘鱼卡地区中侏罗统石门沟组含煤层段沉积有机相分析

柴达木盆地北缘鱼卡地区中侏罗统石门沟组含煤段中发育有油页岩、煤、碳质泥岩和泥岩等富有机质细粒沉积.为了研究其沉积有机相的类型及煤和油页岩形成的控制因素,本文通过岩心观察、工业分析结合有机地球化学测试分析等方法将含煤段细粒沉积物划分为了类型A(三角洲平原沉积环境)、B(三角洲前缘-浅湖沉积环境)、C1(湖沼非油页岩亚相)及C2(湖沼油页岩亚相)四种类型,其中类型C1沉积物中发育煤,类型C2中发育油页岩,且煤较油页岩具有更高的含油率、水分、挥发分以及发热量值.有机质类型特征方面,沉积有机相类型A、B及C1沉积物有机质类型均为Ⅱ2-Ⅲ型、有机质来源均以陆源和混合来源两种有机质来源为主,而类型C2中主要为Ⅱ2型,以混合有机质来源为主;类型A及C2其沉积物有机质均处于未成熟阶段,而类型B和C1中有机质均处于未成熟-低成熟阶段;有机质保存条件方面,类型A沉积物主要形成于缺氧的淡水环境,类型B主要形成于贫氧-缺氧的淡水-半咸水环境,类型C1形成于贫氧-缺氧的淡水-半咸水环境,而类型C2则主要形成于缺氧的淡水-半咸水环境.其中类型B较类型A,类型C2较类型C1,其沉积物均形成于更为还原且盐度更高的水体环境中.石门沟组含煤段是煤和油页岩的形成层位,稳定的沉积环境、丰富的湖泊有机质来源、良好的保存条件及较少的陆源碎屑的稀释共同促进了类型C2中油页岩的形成,而丰富的陆源植物供给及良好的保存条件则促进了类型C1中煤层的形成.     

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.