Bioaccumulation depuration kinetics and effects of benzo(a)anthracene on Mytilus galloprovincialis

Polycyclic aromatic hydrocarbons (PAHs) are important environmental pollutants due to their persistence and bioaccumulation potential both in organisms and in sediments. In this study, bioaccumulation and depuration experiments were performed employing local Mediterranean mussel species, Mytilus galloprovincialis, with two biomarkers: filtration rate and lysosomal stability (neutral red retention) assay. Benzo(a)anthracene (BaA) was chosen as the model PAH compound due to its common presence in several matrices in the marine environment. Bioconcentration Factors (BCFs) for the mussels exposed to different BaA concentrations were calculated from both kinetic rate constants and from the experimental data and found between 27-3184 and 16-2745, respectively. Experimental QSAR values were found comparable to the previous QSAR models created for BaA. The effect of BaA exposure on the mussels showed a more clear dose-response relationship according to the results of lysosomal stability compared to the filtration rate.     

哥伦比亚马钦火山热液系统:2011～2013年期间观测到的新岩浆信号

近年来(2009～2013年)哥伦比亚马钦火山出现了新的地震活动。为了改善火山监测系统,本文通过分析该地区火山喷气孔和温泉的化学成分及同位素组成,研究了火山排放的流体地球化学特征。由于火山喷气孔中下部液相分离,导致穹丘中上部的喷气孔亏损δD和δ~(18)O(与大气降雨补给的流体相比)。在2011～2013年期间,发现喷气孔有很明显的岩浆成因He,同时排放的液体中岩浆的贡献量也有所增加,证实了地震活动性的增强。地球化学和地震资料都显示马钦火山已经苏醒,说明该火山仍然处于活跃期,值得我们对其活动性进行重点监测。     

Cloning of a chub metallothionein cDNA and development of competitive RT-PCR of chub metallothionein mRNA as a potential biomarker of heavy metal exposure

Metallothionein has been assayed in a range of aquatic animal tissues as an indicator of metal exposure. We sequenced chub (Leuciscus cephalus) metallothionein cDNA which showed over 90% homology to common carp, goldfish and stone loach and 77% homology to rainbow trout sequences for metallothionein. We then used the extended primer method to develop an accurate quantitative competitive RT-PCR assay for metallothionein mRNA. RT-PCR was used to measure metallothionein mRNA in feral chub from a range of field sites, with different levels of heavy metal pollution, in the West Midlands, UK. Measurements were complemented by analysis of liver and gill metallothionein protein by capillary electrophoresis. There was no significant difference in the metallothionein protein levels between fish of different rivers and there was no evidence of elevation of mRNA at the sites of highest metal exposure. The level of metal exposure (e.g. zinc, nickel and cadmium each ranging between 15 and 28 microg/l ) at the pH (7.5-8.5) of these rivers appears insufficient to elevate hepatic or gill metallothionein in chub. A lack of elevation of hepatic metallothionein mRNA in chub exposed to zinc, copper and manganese for 24 h and 10 days in the laboratory also suggests a non-responsiveness of this species.     

Polybrominated diphenyl ethers and their methoxylated analogs in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) from Bizerte Lagoon, Tunisia

Concentrations of ten polybrominated diphenyl ethers (PBDEs) and eight methoxylated polybrominated diphenyl ethers (MeO-PBDEs) in mullet (Mugil cephalus) and sea bass (Dicentrarchus labrax) collected from the Bizerte Lagoon and the Mediterranean Sea were investigated. To the best of our knowledge, this is the first report of these compounds in marine fishes from Tunisia. The PBDE mean concentrations in fish from Bizerte Lagoon were 45.3 and 96.2 ng g(-1) lw respectively in mullet and sea bass, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea were 7.80 and 27.9 ng g(-1) lw respectively. MeO-PBDE concentrations in mullet and sea bass from Bizerte Lagoon ranged from 6.46 to 286 ng g(-1) lw and from 49.4 to 798 ng g(-1) lw respectively, while the concentrations of these compounds in mullet and sea bass from Mediterranean Sea ranged from 190 to 401 ng g(-1) lw and from 353 to 578 ng g(-1) lw respectively. The total PBDEs and total MeO-PBDEs concentration in fish from Bizerte Lagoon were similar or slightly lower than those reported for other species from other locations around the world.     

Lead contamination of small cetaceans in European waters--the use of stable isotopes for identifying the sources of lead exposure

Lead concentrations and isotopic composition have been measured in bone and teeth of small cetaceans belonging to three species (Delphinus delphis, Phocoena phocoena and Stenella coeruleoalba), to evaluate the toxicological risk and to determine sources of lead in the European waters. Lead concentrations, far lower than threshold value inducing toxic effects in human, were higher in teeth than in bones, but highly correlated between the two tissues (r=0.92, p<0.001). Large variations of 206Pb/207Pb values in bone tissue showed that cetaceans must be submitted to various atmospheric influences. No geographical differences appeared which is consistent with studies on their distribution indicating seasonal movements between Brittany waters and the Bay of Biscay. The negative correlation between 206Pb/207Pb ratios and age of the individuals reflected the decrease in the production of alkyl lead in Europe, i.e., the increasing use of unleaded gasoline.     

海洋底质图

根据第一个五年国民经济发展计划所拟定的关于扩大巴伦支海工业渔捞场的计划,在三十年代初期给苏维埃海洋地质学提供了编制底质图的任务。同时,为了支援我国的工业及保证航海的需要,也提出了控制苏联富饶的海洋资源的任务。 还在上古时代、在航海的早期,就萌发了对海底成分和特性的兴趣。我国在十八世纪、开始编制标有底质特性的原始航行图。以后,在所有国家的航行图上,通常注明底质的名称和它的颜色、或者其它特点的标记;这种底质标记的方法,目前还在采用,但它的缺     

The Properties of Supernova 1997cy Associated with GRB 970514

The extraordinary SN 1997cy associated with GRB 970514 has been observed photometrically and spectroscopically for nearly 2 yr. At the time of discovery, SN 1997cy was the brightest supernova (SN) ever observed (MV相似文献   

Macrofauna impact on Ulva rigida C. Ag. production and relationship with environmental variables in the lagoon of Venice

The grazing pressure of the macrofaunal invertebrates associated with the biomass of Ulva rigida in the Venice lagoon, their species composition and relationship with environmental variables have been studied. Fifteen sampling campaigns were carried out during different seasons both in the central basin of the lagoon, dominated by macroalgae (especially U. rigida C. Ag.) and in the southern basin, prevalently populated by seagrasses (especially Zostera marina L.). Replicate experiments were conducted in the field by exposing Ulva fronds in net cages of 10 and 1 mm (control) mesh-sizes to allow or prevent grazer entrance. The grazing pressure was determined as Ulva growth rate difference in the cages. In the absence of invertebrate herbivores, Ulva exhibited per cent relative growth rates (%RGRs) ranging from 1.5 to 9.5% day(-1), whereas in their presence the %RGRs were significantly lower (from -2.5 to 3.4% day(-1)) and frequently negative, especially in the station dominated by macroalgae. In this area, peak grazing rates and macrofauna biomasses of up to 8.6% day(-1) and 1,480 g m(-2) fwt (84.4 ash-free dry weight), respectively, were found. On the whole, during in field experiments in the Ulva-dominated station, herbivores removed an amount of biomass whose percentage ranged from 59 to 165% (mean: 103%) of the biomass yield (grazers excluded) found in the cages. These results suggest the possibility that grazers could act as an important factor affecting Ulva production in the Venice lagoon. Macrofauna populations were analysed by means of multivaliate techniques applied to biological variables only and biological and environmental variables together. Data of individual abundance, after a log(x + 1) transformation and the calculation of the Bray-Curtis matrix, were classified using the Cluster Analysis and ordinated by means of the Non-Metric Multidimensional Scaling (MDS) technique, in accordance with the strategies used in the study of multispecies distributions. Finally, biological and environmental variables were analysed together by means of correlation matrices and the Principal Component Analysis.     

http://www.sciencedirect.com/science/article/pii/S1674987114001601

Data from a migmatised metapelite raft enclosed within charnockite provide quantitative constraints on the pressure-temperature-time[P-T-t) evolution of the Nagercoil Block at the southernmost tip of peninsular India.An inferred peak metamorphic assemblage of garnet,K-feldspar.sillimanite,plagioclase,magnetite,ilmenite,spinel and melt is consistent with peak metamorphic pressures of 6-8 kbar and temperatures in excess of 900℃.Subsequent growth of cordierite and biotite record high-temperature retrograde decompression to around 5 kbar and 800 C.SHRIMP U-Pb dating of magmatic zircon cores suggests that the sedimentary protoliths were in part derived from felsic igneous rocks with Palaeoproterozoic crystallisation ages.New growth of metamorphic zircon on the rims of detrital grains constrains the onset of melt crystallisation,and the minimum age of the metamorphic peak,to around560 Ma.The data suggest two stages of monazite growth.The first generation of REE-enriched monazite grew during partial melting along the prograde path at around 570 Ma via the incongruent breakdown of apatite.Relatively REE-depleted rims,which have a pronounced negative europium anomaly,grew during melt crystallisation along the retrograde path at around 535 Ma.Our data show the rocks remained at suprasolidus temperatures for at least 35 million years and probably much longer,supporting a long-lived high-grade metamorphic history.The metamorphic conditions,timing and duration of the implied clockwise P-T-t path are similar to that previously established for other regions in peninsular India during the Ediacaran to Cambrian assembly of that part of the Gondwanan supercontinent.     

汶川地震断裂作用研究新认识

2008年汶川地震后,人们不得不思考问题是:大地震是如何发生的?下一次大地震什么时候发生?也就是涉及地质学家和地球物理学家一直未解决的科学问题:断层是如何破裂的?震后断裂是如何愈合的?我们试图通过对汶川地震断裂带结构、断裂摩擦行为和断裂愈合过程的研究来回答这些问题。本文将介绍通过对地表露头和汶川地震断裂科学钻探一号孔(WFSD)岩心中汶川地震主滑移带的详细研究,以及钻孔中长期温度监测来分析有关汶川地震断裂动态弱化和摩擦行为,并结合钻孔中长期水文监测计算所得断裂带渗透率变化,分析震后断裂愈合过程,进而探讨和认识汶川地震断裂作用所涉及的上述问题。经过详细研究,确定了汶川地震断裂带(映秀—北川断裂带)宽105~240 m、具有五个不同断裂岩组合的内部结构,是一条经常发生大地震、具多种弱化机制的断裂带;发现了汶川地震不仅具有同震石墨化作用,而且测量到目前世界上最低的动态摩擦系数(≤0.02),同时首次记录到大地震后断裂快速愈合信息。这些研究结果不仅直接回答了一直困扰在地震地质和地震物理学领域几十年的关键问题,而且对完善地震断裂理论和认识汶川地震机制具有极其重要的意义,为防震减灾提供了理论依据。