Extending Service Life of Household Water Filters by Mixing Metallic Iron with Sand

The use of metallic iron filters (Fe⁰ filters) has been discussed as a promising low‐cost option for safe drinking water production at household level. Filter clogging due to the volumetric expansive nature of iron corrosion has been identified as the major problem of Fe⁰ filters. Mixing Fe⁰ and sand (yielding Fe⁰/sand filters) has been proposed as a tool to extent filter service life. However, no systematic discussion rationalizing Fe⁰/sand mixtures is yet available. This communication theoretically discussed suitable Fe⁰/sand proportions for efficient filters. Results suggested that Fe⁰/sand filters should not contain more that 50 vol% Fe⁰ (25 wt% when Fe⁰ is mixed with quartz). The actual Fe⁰ percentage in a filter will depend on its intrinsic reactivity.     

A thick dacitic debris flow sequence, Lake of the Woods greenstone terrane, central Canada: resedimented products of Archean vulcanian, plinian and dome-building eruptions

A 4-km thick, vertically dipping, south-facing, homoclinal, intermediate to felsic, volcaniclastic sequence in central Lake of the Woods, is underlain and overlain by subaqueous, tholeiitic basalt flows. Volcaniclastic lithologies comprise a lower tuff-breccia and lapilli-tuff assemblage, an upper turbiditic greywacke formation, and three lenticular, upward-fining, conglomerate formations interspersed within other units. Tuff-breccia and lapilli-tuff are characterized by very thick, poorly defined beds, pronounced heterogeneity, mostly angular blocks and lapilli, and a plagioclase+quartz crystal component that, in places, is incompatible with phenocryst populations in fragments. These appear to be subaqueous debris flow deposits that resulted from multistage mixing, during downslope mass transport, of fragments produced by subaerial phreatomagmatic vulcanian-type eruptions. Anomalous crystal contents represent intermixing of subaerial subplinian or plinian ash. Conglomerate formations comprise very thick, poorly defined beds composed almost entirely of well rounded, fine- to medium-grained trondhjemite. They are also subaqueous debris flow deposits but were apparently derived from wave erosion of large, flank dome complexes that periodically blocked normal transport of volcanic debris from higher on the volcano. The upper greywacke represents a shift in eruptive processes to largely plinian or subplinian eruptions.     

Effect of Pumice and Sand on the Sustainability of Granular Iron Beds for the Aqueous Removal of CuII,NiII, and ZnII

Current knowledge of the basic principles underlying the design of Fe⁰ beds is weak. The volumetric expansive nature of iron corrosion was identified as the major factor determining the sustainability of Fe⁰ beds. This work attempts to systematically verify developed concepts. Pumice and sand were admixed to 200 g of Fe⁰ in column studies (50:50 volumetric proportion). Reference systems containing 100% of each material have been also investigated. The mean grain size of the used materials (in mm) were 0.28 (sand), 0.30 (pumice), and 0.50 (Fe⁰). The five studied systems were characterized (i) by the time dependent evolution of their hydraulic conductivity (permeability) and (ii) for their efficiency for aqueous removal of Cu^II, Ni^II, and Zn^II (about 0.3 mM of each). Results showed unequivocally that (i) quantitative contaminant removal was coupled to the presence of Fe⁰, (ii) additive admixture lengthened the service life of Fe⁰ beds, and (iii) pumice was the best admixing agent for sustaining permeability while the Fe⁰/sand column was the most efficient for contaminant removal. The evolution of the permeability was well‐fitted by the approach that the inflowing solution contained dissolved O₂. The achieved results are regarded as starting point for a systematic research to optimize/support Fe⁰ filter design.