Die Ladungsbilanz für eine verfeinerte Kristallstruktur von Stranskiit,Zn2 Cu(AsO4)2

Zusammenfassung Die Kristallstruktur des Stranskiits wurde mit neuen Meßdaten, die an einer aus Tsumeb stammenden Probe gewonnen worden waren, bis zuR=0,034 für 1239 unabhängige beobachtete Reflexe verfeinert. Von der verfeinerten Struktur wurde die Ladungsbilanz aufgestellt und besonders im Hinblick auf die Ladungsdeformation des Cu²⁺ diskutiert. Eine Mikrosondenanalyse derselben Probe ergab, daß die tatsächliche Zusammensetzung der angegebenen Formel entspricht.

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Charge balance of a refined crystal structure of stranskiite, Zn₂Cu (AsO₄)₂

Summary The crystal structure of stranskiite was refined with new intensity data obtained from a specimen from Tsumeb toR=0.034 for 1234 observed independent reflections. The charge balance was calculated and discussed particularly with respect of the charge deformation of Cu²⁺. An electron probe microanalysis gave the result that the actual composition of the specimen corresponds to the given formula.

     

Dehydration melting of a basaltic composition amphibolite at 1.5 and 2.0 GPa: implications for the origin of adakites

This study presents the results of dehydration melting experiments on a basaltic composition amphibolite under conditions appropriate to a hot slab geotherm (1.5 and 2.0 GPa and temperatures of 850 to 1150° C). Dehydration melting produces an omphacitic augite and garnet bearing residue coexisting with rhyolitic to andesitic composition melts. At 1.5 GPa, the amphibolite melts in two stages between 800 and 1025° C. The 2.0 GPa data also define two melting stages. At 2.0 GPa, the first stage involves nearly modal melting of the original amphibolite minerals (qtz, pl, amp) to produce melt + cpx + grt. During the second stage, the eclogite restite melts non-modally (0.86 cpx + 0.14 grt = 1 melt). The experimental results were combined with data from the literature to generate a composite P-T phase diagram for basaltic composition amphibolites over the 800 to 1100° C temperature range for pressures up to 2.0 GPa. Comparison of the major element compositions of the experimentally produced melts with compositions of presumed slab melts (adakites) shows that partial melting of amphibolite at conditions appropriate to a hot-slab geotherm produces melts similar to andesitic and dacitic adakites except for significant MgO and CaO depletions. Trace element modelling of amphibolite dehydration melting using the 2.0 GPa melting reactions produces REE abundances similar to those of adakites at 10–15 wt% batch melting, but the models do not reproduce the high Sr/Y ratios characteristic of adakites. Taken together, the major and trace element results are not consistent with the derivation of adakites by dehydration melting of the subducted slab with little or no interaction with the mantle wedge or crust. If adakites are partial melts of the subducted slab, they must undergo significant interaction with the mantle and/or crust, during which they acquire a number of their distinctive characteristics.     

The vulnerability of the European air traffic network to spatial hazards

The 2010 eruption of the Eyjafjallajökull volcano had a devastating effect on the European air traffic network, preventing air travel throughout most of Europe for 6 days (Oroian in ProEnvironment 3:5–8, 2010). The severity of the disruption was surprising as previous research suggests that this type of network should be tolerant to random hazard (Albert et al. in Nature 406(6794):378–382, 2000; Strogatz in Nature 410(6825):268–276, 2001). The source of this hazard tolerance lies in the degree distribution of the network which, for many real-world networks, has been shown to follow a power law (Albert et al. in Nature 401(6749):130–131, 1999; Albert et al. in Nature 406(6794):378–382, 2000). In this paper, we demonstrate that the ash cloud was unexpectedly disruptive because it was spatially coherent rather than uniformly random. We analyse the spatial dependence in air traffic networks and demonstrate how the combination of their geographical distribution and their network architectures jeopardises their inherent hazard tolerance.     

The biogeochemical expression of deeply buried uranium mineralization in Saskatchewan, Canada

Ten kilometres from the eastern edge of the Athabasca Sandstone, near McClean Lake, uranium mineralization (locally up to 27% U₃O₈) lies 150 m beneath the surface at the unconformity between the Athabasca and crystalline basement.A biogeochemical survey of the area sampled A_H and B_F soil horizons, peat moss, and plant organs from the dominant species, viz. black spruce (Picea mariana), jack pine (Pinus banksiana), labrador tea (Ledum groenlandicum), and leather leaf (Chamaedaphne calyculata). Uranium concentrations in the ash of various media are surprisingly high: spruce twigs up to 154 ppm U; labrador tea and leather leaf stems around 100 ppm U. Conversely, labrador tea roots yield < 5 ppm U and spruce trunk wood usually < 1 ppm U. Soils give values of 1–3 ppm U. Contoured U values reveal that highest concentrations occur in plants growing above, but laterally displaced from the mineralization. Track-Etch data show a similar pattern. Upward migration of ions along steeply inclined fractures is invoked to explain the phenomenon. Other elements are present in varying concentrations, depending upon the plant species and the plant organ. High concentrations of several elements are recorded, most notably Cd and Ag in the conifers.     

Metasomatic alteration of coarse-grained igneous calcium-aluminum-rich inclusions from CK3 carbonaceous chondrites

We report on the primary and secondary mineralogies of three coarse-grained igneous calcium-aluminum-rich inclusions (CAIs) (Compact Type A [CTA], Type B [B], and forsterite-bearing type B [FoB]) from the Northwest Africa (NWA) 5343 (CK3.7) and NWA 4964 (CK3.8) carbonaceous chondrites, compare them with the mineralogy of igneous CAIs from the Allende (CV3.6) chondrite, and discuss the nature of the alteration processes that affected the CK and CV CAIs. The primary mineralogy and mineral chemistry of the CK3 CAIs studied are similar to those from Allende; however, primary melilite and anorthite are nearly completely absent. Although the secondary minerals identified in CK CAIs (Al-diopside, andradite, Cl-apatite, clintonite, forsterite, ferroan olivine, Fe,Ni-sulfides, grossular, ilmenite, magnetite, plagioclase, spinel, titanite, and wadalite) occur also in the Allende CAIs, there are several important differences: (i) In addition to melilite and anorthite, which are nearly completely replaced by secondary minerals, the alteration of CK CAIs also affected high-Ti pyroxenes (fassaite and grossmanite) characterized by high Ti³⁺/Ti⁴⁺ ratio and spinel. These pyroxenes are corroded and crosscut by veins of Fe- and Ti-bearing grossular, Fe-bearing Al,Ti-diopside, titanite, and ilmenite. Spinel is corroded by Fe-bearing Al-diopside and grossular. (ii) The secondary mineral assemblages of grossular + monticellite and grossular + wollastonite, commonly observed in the Allende CAIs, are absent; the Fe-bearing grossular + Fe-bearing Al-diopside ± Fe,Mg-spinel, Fe-bearing grossular + Fe,Mg-olivine ± Fe,Mg-spinel, and Ca,Na-plagioclase + Fe-bearing Al-diopside + Fe-bearing grossular assemblages are present instead. These mineral assemblages are often crosscut by veins of Fe-bearing Al-diopside, Fe,Mg-olivine, Fe,Mg-spinel, and Ca,Na-plagioclase. The coarse-grained secondary grossular and Al-diopside often show multilayered chemical zoning with distinct compositional boundaries between the layers; the abundances of Fe and Ti typically increase toward the grain edges. (iv) Sodium-rich secondary minerals, nepheline and sodalite, commonly observed in the peripheral portions of the Allende CAIs, are absent; Ca,Na-plagioclase is present instead. We conclude that coarse-grained igneous CAIs from CK3.7–3.8 s and Allende experienced an open-system multistage metasomatic alteration in the presence of an aqueous solution–infiltration metasomatism. This process resulted in localized mobilization of all major rock-forming elements: Si, Ca, Al, Ti, Mg, Fe, Mn, Na, K, and Cl. The metasomatic alteration of CK CAIs is more advanced and occurred under higher temperature and higher oxygen fugacity than that of the Allende CAIs.     

Attitudes to Diversity: new perspectives on the ethnic geography of Brisbane,Australia

As a consequence of changing immigration policy over the past 50 years, contemporary Australia has a culturally diverse population. Focusing on Brisbane, one of Australia's smaller immigrant-receiving cities but where some 19 per cent of the population is born overseas, this study examines attitudes to and perceptions of culturally different ethnic (non-Anglo) immigrant groups. Emphasis is placed on patterns of tolerance and intolerance for the city as a whole, both in areas of contact and in areas of minimal contact. Findings show that variations in attitudes vary somewhat from commonly accepted socio-economic and age-based correlations (the lower the status or the older people are the less tolerant), depending on the particular mix of ethnic birthplace groups present. They also show levels of intolerance in areas of minimal contact, which is implicitly attributed to mass media influences. In light of these findings, a concluding plea is made for anti-intolerance strategies to be developed for cities that pay regard to the geography of attitude-forming contexts.     

Application Procedures for the Electromagnetic Borehole Flowmeter in Shallow Unconfined Aquifers

It is increasingly common for the electromagnetic borehole flowmeter (EBF) to he used to measure hydraulic conductivity (K) distributions in subsurface flow systems. Past applications involving the EBF have been made mostly in confined aquifers (Kabala 1994; Boman et al. 1997; Podgorney and Ritzi 1997; Ruud and Kabala 1997a, 1997b; Flach et al. 2000), and it has been common to set up a flow field around a test well using a small pump that is located near the top of the well screen (Mob, and Young 1993). In thin, unconfined aquifers that exhibit ground water tables near the ground surface and that undergo drawdown during pumping, such a configuration can be problematical because pumping and associated drawdown may effectively isolate the upper portion of the aquifer from the flowmeter. In these instances, a steady-state flow field in the vicinity of the test well may be created using injection rather than pumping, allowing for testing in the otherwise isolated upper portion of the aquifer located near the initial water table position. Using procedures developed by Molz and Young (1993), which were modified for an injection mode application, testing was conducted to determine whether or not the injection mode would provide useful information in a shallow, unconfined aquifer that required the collection of data near the initial water table position. Results indicated that the injection mode for the EBF was well suited for this objective.     

The diet of deepwater sharks and the benefits of using DNA identification of prey

Stomachs from the sharks Dalatias licha, Centrophorus squamosus, Centroscymnus owstoni, Centroselachus crepidater, Proscymnodon plunketi, and Galeorhinus galeus were sampled from three research trawl surveys on Chatham Rise, east of New Zealand. Between 14 and 50 stomachs were examined for each species, of which 8–62% were empty. Prey were visually identified in 80 stomachs, and by DNA barcoding in a further 28 stomachs. The use of DNA methods allowed the identification of chunks of flesh found in the stomachs of D. licha and P. plunketi, and nearly doubled the rate of data accumulation for D. licha, C. squamosus, and C. owstoni. Between 84 and 223 stomachs were estimated to be needed to measure 90% of the extrapolated total prey richness. The prey of D. licha, C. squamosus, and P. plunketi were predominantly benthic or demersal fishes and cephalopods. The prey of C. owstoni and C. crepidater were predominantly mesopelagic fishes and squids. G. galeus foraged throughout the water column. Scavenging of discards from commercial fishing vessels was likely in C. squamosus, P. plunketi, and G. galeus. The diet of all species except C. crepidater was dominated by the commercially important benthopelagic species hoki Macruronus novaezelandiae.