The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer

The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.     

Tourmaline in Proterozoic Massive Sulfide Deposits from Rajasthan, India

We have analyzed the chemical composition and boron isotope composition of tourmaline from tourmalinites, granite and a quartz-tourmaline vein from the Deri ore zone and from a pegmatitic band in the Rampura-Agucha ore body. These two Proterozoic massive sulfide deposits occur in the Aravalli-Delhi orogenic belt, Rajasthan, northwest India. Tourmaline from stratiform tourmalinites closely associated with the massive sulfides in the Deri deposit have preserved their original chemical compositions despite regional and thermal metamorphism in the area. These tourmalines have low Fe/(Fe + Mg) ratios (0.19–0.30; mean 0.26) that suggest formation close to the sediment-sea water interface. The δ¹¹B values (−15.5 and −16.4‰) are compatible with boron derived from leaching of argillaceous sediments and/or felsic volcanics underlying the original massive sulfide deposit during its formation. Boron isotope compositions measured in tourmaline from a post-ore granite and quartz-tourmaline vein in the Deri deposit indicate that boron in these tourmalines was derived from the tourmalinites produced during ore formation. The boron isotope systematics of a coarse brown tourmaline crystal from a pegmatitic band on the hanging wall contact of the Rampura-Agucha deposit indicate that 45 ± 25% of the boron within the original tourmaline was lost during upper amphibolite facies regional metamorphism. Received: 3 April 1996 / Accepted: 11 April 1996     

Mitigating the Effects of Climate Change on the Water Resources of the Columbia River Basin

The potential effects of climate change on the hydrology and water resources of the Columbia River Basin (CRB) were evaluated using simulations from the U.S. Department of Energy and National Center for Atmospheric Research Parallel Climate Model (DOE/NCAR PCM). This study focuses on three climate projections for the 21st century based on a `business as usual' (BAU) global emissions scenario, evaluated with respect to a control climate scenario based on static 1995 emissions. Time-varying monthly PCM temperature and precipitation changes were statistically downscaled and temporally disaggregated to produce daily forcings that drove a macro-scale hydrologic simulation model of the Columbia River basin at 1/4-degree spatial resolution. For comparison with the direct statistical downscaling approach, a dynamical downscaling approach using a regional climate model (RCM) was also used to derive hydrologic model forcings for 20-year subsets from the PCM control climate (1995–2015) scenario and from the three BAU climate(2040–2060) projections. The statistically downscaled PCM scenario results were assessed for three analysis periods (denoted Periods 1–3: 2010–2039,2040–2069, 2070–2098) in which changes in annual average temperature were +0.5,+1.3 and +2.1 °C, respectively, while critical winter season precipitation changes were –3, +5 and +1 percent. For RCM, the predicted temperature change for the 2040–2060 period was +1.2 °C and the average winter precipitation change was –3 percent, relative to the RCM controlclimate. Due to the modest changes in winter precipitation, temperature changes dominated the simulated hydrologic effects by reducing winter snow accumulation, thus shifting summer streamflow to the winter. The hydrologic changes caused increased competition for reservoir storage between firm hydropower and instream flow targets developed pursuant to the Endangered Species Act listing of Columbia River salmonids. We examined several alternative reservoir operating policies designed to mitigate reservoir system performance losses. In general, the combination of earlier reservoir refill with greater storage allocations for instream flow targets mitigated some of the negative impacts to flow, but only with significant losses in firm hydropower production (ranging from –9 percent in Period1 to –35 percent for RCM). Simulated hydropower revenue changes were lessthan 5 percent for all scenarios, however, primarily due to small changes inannual runoff.     

Geochemical characteristics, Ar–Ar ages and original tectonic setting of the Band-e-Zeyarat/Dar Anar ophiolite, Makran accretionary prism, S.E. Iran

The Makran accretionary prism in southeastern Iran contains extensive Mesozoic zones of melange and large intact ophiolites, representing remnants of the Tethys oceanic crust that was subducted beneath Eurasia. To the north of the Makran accretionary prism lies the Jaz Murian depression which is a subduction-related back-arc basin. The Band-e-Zeyarat/Dar Anar ophiolite is one of the ophiolite complexes; it is located on the west side of the Makran accretionary prism and Jaz Murian depression, and is bounded by two major fault systems. The principal rock units of this complex are a gabbro sequence which includes low- and high-level gabbros, an extensive sheeted diabase dike sequence, late intrusive rocks which consist largely of trondhjemites and diorites, and volcanic rocks which are largely pillow basalts interbedded with pelagic sedimentary rocks, including radiolarian chert. Chondrite- and primitive-mantle-normalized incompatible trace element data and age-corrected Nd, Pb, and Sr isotopic data indicate that the Band-e-Zeyarat/Dar Anar ophiolite was derived from a midocean ridge basalt-like mantle source. The isotopic data also reveal that the source for basalts was Indian-Ocean-type mantle. Based on the rare earth element (REE) data and small isotopic range, all the rocks from the Band-e-Zeyarat/Dar Anar ophiolite are cogenetic and were derived by fractionation from melts with a composition similar to average E-MORB; fractionation was controlled by the removal of clinopyroxene, hornblende and plagioclase. Three ⁴⁰Ar–³⁹Ar plateau ages of 140.7±2.2, 142.9±3.5 and 141.7±1.0 Ma, and five previously published K–Ar ages ranging from 121±4 to 146±5 Ma for the hornblende gabbros suggest that rocks from this ophiolite were formed during the Late Jurassic–Early Cretaceous. Plate reconstructions suggest that the rocks of this complex appear to be approximately contemporaneous with the Masirah ophiolite which has crystallization age of (150 Ma). Like Masirah, the rocks from the Band-e-Zeyarat/Dar Anar ophiolite complex represent southern Tethyan ocean crust that was formed distinctly earlier than crust preserved in the 90–100 Ma Bitlis-Zagros ophiolites (including the Samail ophiolite).     

Characterizing and classifying urban watersheds with compositional and structural attributes

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.     

Unlocking the applications of automated mineral analysis

Identifying and quantifying the relative abundance of minerals is a fundamental part of many aspects of both pure and applied geology. Historically, quantitative mineralogy could be achieved using optical microscopy and point counting. This is a slow and operator dependent process, and practically impossible to achieve in, for example, very fine grained samples. Over the last decade a range of automated mineralogy technologies have arisen from the global mining industry and are being increasingly used in other branches of geology. These technologies, based on scanning electron microscopy with linked energy dispersive spectrometers, have the potential to revolutionise how we quantify mineralogy. In addition, during measurement, the sample textures are also captured, providing a wealth of valuable data for the geologist. In this article we review the current state of automated mineralogy and highlight the many areas of application for this technology.