Caldera morphology in the western Galápagos and implications for volcano eruptive behavior and mechanisms of caldera formation

Caldera morphology on the six historically active shield volcanoes that comprise Isabela and Fernandina islands, the two westernmost islands in the Galapagos archipelago, is linked to the dynamics of magma supply to, and withdrawal from, the magma chamber beneath each volcano. Caldera size (e.g., volumes 2–9 times that of the caldera of Kilauea, Hawai'i), the absence of well-developed rift zones and the inability to sustain prolonged low-volumetric-flow-rate flank eruptions suggest that magma storage occurs predominantly within centrally located chambers (at the expense of storage within the flanks). The calderas play an important role in the formation of distinctive arcuate fissures in the central part of the volcano: repeated inward collapse of the caldera walls along with floor subsidence provide mechanisms for sustaining radially oriented least-compressive stresses that favor the formation of arcuate fissures within 1–2 km outboard of the caldera rim. Variations in caldera shape, depth-to-diameter ratio, intra-caldera bench location and the extent of talus slope development provide insight into the most recent events of caldera modification, which may be modulated by the episodic supply of magma to each volcano. A lack of correlation between the volume of the single historical collapse event and its associated volume of erupted lava precludes a model of caldera formation linked directly to magma withdrawal. Rather, caldera collapse is probably the result of accumulated loss from the central storage system without sufficient recharge and (as has been suggested for Kilauea) may be aided by the downward drag of dense cumulates and intrusives.     

The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer

The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.     

The Hinode Spectro-Polarimeter

The joint Japan/US/UK Hinode mission includes the first large-aperture visible-light solar telescope flown in space. One component of the Focal Plane Package of that telescope is a precision spectro-polarimeter designed to measure full Stokes spectra with the intent of using those spectra to infer the magnetic-field vector at high precision in the solar photosphere. This article describes the characteristics of the flight hardware of the Hinode Spectro-Polarimeter, and summarizes its in-flight performance.     

Morphology of HCN and CN in Comet Hale-Bopp (1995 O1)

We compare images of Comet Hale-Bopp (1995 O1) in HCN and CN taken near perihelion (April 1, 1997) to determine the origin of CN in comets. We imaged the J=1→0 transition of HCN at λ=3 mm with the BIMA Array. Data from two weeks around perihelion were summed within four phase bins based on the rotational period of the comet. This increases both the signal-to-noise ratio and the u-v coverage while decreasing the smearing of the spatial features. The similarly phased narrowband CN images were taken at Lowell Observatory within the same range of dates as the HCN images. We find that there is a better correlation between HCN and CN than between HCN and the optically dominant dust. If the CN in jets does have a dust source it would have to have a very low albedo and/or small particle size. The production rates are consistent with HCN being a primary parent of CN, although there are discrepancies between the HCN destruction scalelength and the CN production scalelength which we discuss.     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.     

Age progressive volcanism in the Comores Archipelago, western Indian Ocean and implications for Somali plate tectonics

The Comores Islands together with the Tertiary volcanic province of northern Madagascar form a sublinear trend of alkali olivine basalt shield volcanoes across the northern entrance of the Mozambique Channel. Potassium-argon dating of shield-building lavas confirms an eastward increase in age of volcanism along the chain, consistent with a hotspot origin for the lineament. The velocity of the Somali plate over the mantle magma source is 50 mm/yr.

We use the distribution of ages along the Comores-Madagascar chain in conjunction with existing age data for the Reunion-Mascarene Plateau hotspot track to model the absolute motion of the Somali plate for the last 10 m.y. We calculate the relative motion across the East African Rift by subtracting the Somali plate absolute motion from African plate absolute motion during this period. The model predicts 320 km of total separation across the East African Rift during the past 10 m.y. which is greater than has been estimated from surface geological evidence

The geometry of older portions of the Comores and Reunion trends indicates that there was no significant relative motion between the African and Somali plates prior to about 10 m.y. ago.     

High‐frequency water quality monitoring in an urban catchment: hydrochemical dynamics,primary production and implications for the Water Framework Directive

This paper describes the hydrochemistry of a lowland, urbanised river‐system, The Cut in England, using in situ sub‐daily sampling. The Cut receives effluent discharges from four major sewage treatment works serving around 190 000 people. These discharges consist largely of treated water, originally abstracted from the River Thames and returned via the water supply network, substantially increasing the natural flow. The hourly water quality data were supplemented by weekly manual sampling with laboratory analysis to check the hourly data and measure further determinands. Mean phosphorus and nitrate concentrations were very high, breaching standards set by EU legislation. Although 56% of the catchment area is agricultural, the hydrochemical dynamics were significantly impacted by effluent discharges which accounted for approximately 50% of the annual P catchment input loads and, on average, 59% of river flow at the monitoring point. Diurnal dissolved oxygen data demonstrated high in‐stream productivity. From a comparison of high frequency and conventional monitoring data, it is inferred that much of the primary production was dominated by benthic algae, largely diatoms. Despite the high productivity and nutrient concentrations, the river water did not become anoxic, and major phytoplankton blooms were not observed. The strong diurnal and annual variation observed showed that assessments of water quality made under the Water Framework Directive (WFD) are sensitive to the time and season of sampling. It is recommended that specific sampling time windows be specified for each determinand, and that WFD targets should be applied in combination to help identify periods of greatest ecological risk. © 2015 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

Testing the credibility of historical newspaper reporting of extreme climate and weather events

In recent years, newspaper research has been streamlined by digitisation and online hosting by PapersPast. This paper tests the reliability and credibility of reporting of extreme weather and climatic events through PapersPast to determine if newspaper research of past climate can be further streamlined. Searches were conducted through four early‐20th‐century Auckland newspapers, where counts of articles returned by key‐word searches for particular periods were compared against periods of known extremes. We find that blind searches have only limited potential in identifying extreme weather and climatic events and that they are no substitute for thorough analyses of documentary sources.     

The radio frequency dielectric properties of the stratified UG1–UG2 geological unit in the Bushveld Complex

A new measurement technique enables the complex dielectric properties of the geological strata comprising the UG1–UG2 (Upper Group 1–Upper Group 2) unit of the Bushveld Complex in South Africa to be determined with unprecedented detail at radio frequencies (RF). Results of non-destructive laboratory measurements of representative diamond drill core samples from the UG1–UG2 unit are presented at 25 MHz. These data establish that the UG1 and UG2 chromitite layers are embedded in rock strata (norite, pyroxenite and anorthosite) which are translucent in the HF spectral band, whereas the chromitite layers themselves exhibit significant velocity contrast, making them good radar reflectors. The data presented here is useful for calibration of the radar system, and for predicting the range and resolution performance of borehole radars operating in both the hanging and footwalls of the economically important platiniferous UG2 reef.