Provincialism and correlations between some properties of vitrinites

Optical and chemical properties for hand-picked samples of vitrinite from a number of British coalfields are correlated and the correlations compared with previously published data. The form of the relationship found for the properties of British vitrinites is generally similar to that exhibited by a number of other sets of analyses, but some significant differences also exist in several of the correlations. For maximum reflectance as a function of carbon content, the present data indicate that at medium and low ranks, maximum reflectance is lower than the level suggested by most previous studies. The relationships of volatile-matter yield to reflectance and carbon content suggest that at low ranks, volatile-matter yield is strongly dependent upon the nature of the coalification history of the vitrinite. Furthermore, these correlations are likely to show provincialism, in that correlations which hold for one coalfield may not be representative of the relationship in other coalfields. Similarly, major differences in relationships involving bireflectance are associated with the tectonic setting at the time of effective coalification. The data presented here indicate that for low-rank coals at least, correlations between properties of vitrinites must take account of provincialism if they are to be sufficiently reliable to be useful. The measurement of a number of rank-sensitive variables can yield additional information about rank, as compared with the use of a single rank-sensitive variable.     

The Mobility of Rare Earth Elements and Redox Sensitive Elements in the Groundwater/Seawater Mixing Zone of a Shallow Coastal Aquifer

The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.     

Geochemical characteristics, Ar–Ar ages and original tectonic setting of the Band-e-Zeyarat/Dar Anar ophiolite, Makran accretionary prism, S.E. Iran

The Makran accretionary prism in southeastern Iran contains extensive Mesozoic zones of melange and large intact ophiolites, representing remnants of the Tethys oceanic crust that was subducted beneath Eurasia. To the north of the Makran accretionary prism lies the Jaz Murian depression which is a subduction-related back-arc basin. The Band-e-Zeyarat/Dar Anar ophiolite is one of the ophiolite complexes; it is located on the west side of the Makran accretionary prism and Jaz Murian depression, and is bounded by two major fault systems. The principal rock units of this complex are a gabbro sequence which includes low- and high-level gabbros, an extensive sheeted diabase dike sequence, late intrusive rocks which consist largely of trondhjemites and diorites, and volcanic rocks which are largely pillow basalts interbedded with pelagic sedimentary rocks, including radiolarian chert. Chondrite- and primitive-mantle-normalized incompatible trace element data and age-corrected Nd, Pb, and Sr isotopic data indicate that the Band-e-Zeyarat/Dar Anar ophiolite was derived from a midocean ridge basalt-like mantle source. The isotopic data also reveal that the source for basalts was Indian-Ocean-type mantle. Based on the rare earth element (REE) data and small isotopic range, all the rocks from the Band-e-Zeyarat/Dar Anar ophiolite are cogenetic and were derived by fractionation from melts with a composition similar to average E-MORB; fractionation was controlled by the removal of clinopyroxene, hornblende and plagioclase. Three ⁴⁰Ar–³⁹Ar plateau ages of 140.7±2.2, 142.9±3.5 and 141.7±1.0 Ma, and five previously published K–Ar ages ranging from 121±4 to 146±5 Ma for the hornblende gabbros suggest that rocks from this ophiolite were formed during the Late Jurassic–Early Cretaceous. Plate reconstructions suggest that the rocks of this complex appear to be approximately contemporaneous with the Masirah ophiolite which has crystallization age of (150 Ma). Like Masirah, the rocks from the Band-e-Zeyarat/Dar Anar ophiolite complex represent southern Tethyan ocean crust that was formed distinctly earlier than crust preserved in the 90–100 Ma Bitlis-Zagros ophiolites (including the Samail ophiolite).     

Geochemistry and Sm–Nd isotopic systematics of Ediacaran–Ordovician,sedimentary and bimodal igneous rocks in the western Acatlán Complex,southern Mexico: Evidence for rifting on the southern margin of the Rheic Ocean

Ordovician igneous rocks in the western Acatlán Complex (Olinalá area) of southern Mexico include a bimodal igneous suite that intrudes quartzites and gneisses of the Zacango Unit, and all these rocks were polydeformed and metamorphosed in the amphibolite facies during the Devono-Carboniferous. The Ordovician igneous rocks consist of the penecontemporaneous amphibolites, megacrystic granitoids and leucogranite, the latter dated at ca. 464 Ma. Geochemical and Sm–Nd data indicate that the amphibolites have a differentiated tholeiitic signature, and that its mafic protoliths formed in an extensional setting transitional between within-plate and ocean floor. The amphibolites are variably contaminated by a Mesoproterozoic crustal source, inferred to be the Oaxacan basement exposed in the adjacent terrane. The most primitive samples have εNdt (t = 465 Ma) values significantly below that of the contemporary depleted mantle and were probably derived from the sub-continental lithospheric mantle. The megacrystic granites were most probably derived by partial melting of an arc crustal source (similar to the Oaxacan Complex) and triggered by the ascent of mafic magma from the lithospheric mantle. Sm–Nd isotopic signatures suggest that metasedimentary rocks from Zacango Unit were derived from adjacent Oaxacan Complex. Trace elements relationships (e.g. La/Th vs. Hf) and REE patterns suggest provenance in felsic-intermediate igneous rocks with a calc-alkaline signature. The Ordovician bimodal magmatism is inferred to have resulted from rifting on the southern flank of the Rheic Ocean and is an expression of a major rifting event that occurred along much of the northern Gondwanan margin in the Ordovician.     

使用微机的自动气象站

本文综述了应用微型计算机作为自动气象站的核心部分应考虑的要点。阅读本文并不要求读者掌握微机的基本知识。本文所描述的原理涉及来自气象感应元件的信号处理、计算机硬件性能的选择、编制程序的语言和技术、最终结果的输出方法等。作为一个实例,本文介绍了一个用于向公众展示当天气象要素及气候统计资料的自动气象站。     

Non-uniform interhemispheric temperature trends over the past 550 years

The warming trend over the last century in the northern hemisphere (NH) was interrupted by cooling from ad 1940 to 1975, a period during which the southern hemisphere experienced pronounced warming. The cause of these departures from steady warming at multidecadal timescales are unclear; the prevailing explanation is that they are driven by non-uniformity in external forcings but recent models suggest internal climate drivers may play a key role. Paleoclimate datasets can help provide a long-term perspective. Here we use tree-rings to reconstruct New Zealand mean annual temperature over the last 550 years and demonstrate that this has frequently cycled out-of-phase with NH mean annual temperature at a periodicity of around 30–60 years. Hence, observed multidecadal fluctuations around the recent warming trend have precedents in the past, strongly implicating natural climate variation as their cause. We consider the implications of these changes in understanding and modelling future climate change.     

Neoproterozoic—Early Paleozoic evolution of peri-Gondwanan terranes: implications for Laurentia-Gondwana connections

Neoproterozoic tectonics is dominated by the amalgamation of the supercontinent Rodinia at ca. 1.0 Ga, its breakup at ca. 0.75 Ga, and the collision between East and West Gondwana between 0.6 and 0.5 Ga. The principal stages in this evolution are recorded by terranes along the northern margin of West Gondwana (Amazonia and West Africa), which continuously faced open oceans during the Neoproterozoic. Two types of these so-called peri-Gondwanan terranes were distributed along this margin in the late Neoproterozoic: (1) Avalonian-type terranes (e.g. West Avalonia, East Avalonia, Carolina, Moravia-Silesia, Oaxaquia, Chortis block that originated from ca. 1.3 to 1.0 Ga juvenile crust within the Panthalassa-type ocean surrounding Rodinia and were accreted to the northern Gondwanan margin by 650 Ma, and (2) Cadomian-type terranes (North Armorica, Saxo-Thuringia, Moldanubia, and fringing terranes South Armorica, Ossa Morena and Tepla-Barrandian) formed along the West African margin by recycling ancient (2–3 Ga) West African crust. Subsequently detached from Gondwana, these terranes are now located within the Appalachian, Caledonide and Variscan orogens of North America and western Europe. Inferred relationships between these peri-Gondwanan terranes and the northern Gondwanan margin can be compared with paleomagnetically constrained movements interpreted for the Amazonian and West African cratons for the interval ca. 800–500 Ma. Since Amazonia is paleomagnetically unconstrained during this interval, in most tectonic syntheses its location is inferred from an interpreted connection with Laurentia. Hence, such an analysis has implications for Laurentia-Gondwana connections and for high latitude versus low latitude models for Laurentia in the interval ca. 615–570 Ma. In the high latitude model, Laurentia-Amazonia would have drifted rapidly south during this interval, and subduction along its leading edge would provide a geodynamic explanation for the voluminous magmatism evident in Neoproterozoic terranes, in a manner analogous to the Mesozoic-Cenozoic westward drift of North America and South America and subduction-related magmatism along the eastern margin of the Pacific ocean. On the other hand, if Laurentia-Amazonia remained at low latitudes during this interval, the most likely explanation for late Neoproterozoic peri-Gondwanan magmatism is the re-establishment of subduction zones following terrane accretion at ca. 650 Ma. Available paleomagnetic data for both West and East Avalonia show systematically lower paleolatitudes than predicted by these analyses, implying that more paleomagnetic data are required to document the movement histories of Laurentia, West Gondwana and the peri-Gondwanan terranes, and test the connections between them.     

Age progressive volcanism in the Comores Archipelago, western Indian Ocean and implications for Somali plate tectonics

The Comores Islands together with the Tertiary volcanic province of northern Madagascar form a sublinear trend of alkali olivine basalt shield volcanoes across the northern entrance of the Mozambique Channel. Potassium-argon dating of shield-building lavas confirms an eastward increase in age of volcanism along the chain, consistent with a hotspot origin for the lineament. The velocity of the Somali plate over the mantle magma source is 50 mm/yr.

We use the distribution of ages along the Comores-Madagascar chain in conjunction with existing age data for the Reunion-Mascarene Plateau hotspot track to model the absolute motion of the Somali plate for the last 10 m.y. We calculate the relative motion across the East African Rift by subtracting the Somali plate absolute motion from African plate absolute motion during this period. The model predicts 320 km of total separation across the East African Rift during the past 10 m.y. which is greater than has been estimated from surface geological evidence

The geometry of older portions of the Comores and Reunion trends indicates that there was no significant relative motion between the African and Somali plates prior to about 10 m.y. ago.     

Correlated Nd,Sr and Pb isotope variation in Walvis Ridge basalts and implications for the evolution of their mantle source

Basement intersected in DSDP holes 525A, 528 and 527 on the Walvis Ridge consists of submarine basalt flows and pillows with minor intercalated sediments. These holes are situated on the crest and mid and lower northwest flank of a NNW-SSE-trending ridge block which would have closely paralleled the paleo mid-ocean ridge [13, 14]. The basalts were erupted approximately 70 m.y. ago, an age equivalent to that of immediately adjacent oceanic crust in the Angola Basin and consistent with formation at the paleo mid-ocean ridge [14]. The basalt types vary from aphyric quartz tholeiites on the ridge crest to highly plagioclase phyric olivine tholeiites on the ridge flank. These show systematic differences in incompatible trace element and isotopic composition. Many element and isotope ratio pairs form systematic trends with the ridge crest basalts at one end and the highly phyric ridge flank basalts at the other.The low ¹⁴³Nd/¹⁴⁴Nd (0.51238), ²⁰⁶Pb/²⁰⁴Pb (17.54), ²⁰⁸Pb/²⁰⁴Pb (15.47), ²⁰⁸Pb/²⁰⁴Pb (38.14) and high⁸⁷Sr/⁸⁶Sr (0.70512) ratios of the ridge crest basalts suggest derivation from an old Nd/Sm-, Rb/Sr- and Pb/U-enriched mantle source. This isotopic signature is similar to that of alkaline basalts on Tristan de Cunha but offset to significantly lower Nd and Pb isotopic ratios. The isotopic ratio trends may be extrapolated beyond the ridge flank basalts with higher¹⁴³Nd/¹⁴⁴Nd (0.51270), ²⁰⁶Pb/²⁰⁴Pb (18.32), ²⁰⁷Pb/²⁰⁴Pb (15.52), ²⁰⁸Pb/²⁰⁴Pb (38.77) and lower ⁸⁷Sr/⁸⁶Sr (0.70417) ratios in the direction of increasingly Nd/Sm-, Rb/Sr- and Pb/U-depleted source compositions. These isotopic correlations are equally consistent with mixing od depleted and enriched end member melts or partial melting of an inhomogenous, variably enriched mantle source. However, observe ZrBaNbY interelement relationships are inconsistent with any simple two-component model of magma mixing, as might result from the rise of a lower mantle plume through the upper mantle. Incompatible element and Pb isotopic systematics also preclude extensive involvement of depleted (N-type) MORB material or its mantle sources. In our preferred petrogenetic model the Walvis Ridge basalts were derived by partial melting of mantle similar to an enriched (E-type) MORB source which had become heterogeneous on a small scale due to the introduction of small-volume melts and metasomatic fluids.     

Characterizing and classifying urban watersheds with compositional and structural attributes

Current land-use classifications used to assess urbanization effects on stream water quality date back to the 1980s when limited information was available to characterize watershed attributes that mediate non-point source pollution. With high resolution remote sensing and widely used GIS tools, there has been a vast increase in the availability and precision of geospatial data of built environments. In this study, we leverage geospatial data to expand the characterization of developed landscapes and create a typology that allows us to better understand the impact of complex developed landscapes across the rural to urban gradient. We assess the ability of the developed landscape typology to reveal patterns in stream water chemistry previously undetected by traditional land-cover based classification. We examine the distribution of land-cover, infrastructure, topography and geology across 3876 National Hydrography Dataset Plus catchments in the Piedmont region of North Carolina, USA. From this dataset, we generate metrics to evaluate the abundance, density and position of landscape features relative to streams, catchment outlets and topographic wetness metrics. While impervious surfaces are a key distinguishing feature of the urban landscape, sanitary infrastructure, population density and geology are better predictors of baseflow stream water chemistry. Unsupervised clustering was used to generate a distinct developed landscape typology based on the expanded, high-resolution landscape feature information. Using stream chemistry data from 37 developed headwater catchments, we compared the baseflow water chemistry grouped by traditional land-cover based classes of urbanization (rural, low, medium and high density) to our composition and structure-based classification (a nine-class typology). The typology based on 22 metrics of developed landscape composition and structure explained over 50% of the variation in NO₃⁻-N, TDN, DOC, Cl⁻, and Br⁻ concentration, while the ISC-based classification only significantly explained 23% of the variation in TDN. These results demonstrate the importance of infrastructure, population and geology in defining developed landscapes and improving discrete classes for water management.