激光拉曼光谱法分析多种显微组分荧光变化及其应用

利用激发488 nm激光的氩离子激光器作为RENISHAW inVia型激光拉曼光谱仪的光源,建立了多种显微组分荧光变化(FAMM)分析方法,并对镜质体反射率明显抑制的东营凹陷有效烃源岩进行了测定。结果表明,东营凹陷有效烃源岩的有机质类型越好,镜质体反射率抑制程度越高,有效烃源岩的真实成熟度应主要处于0.64%~1.30%,而不是实测镜质体反射率所反映的0.37%~1.10%。     

Distribution of Cd,Pb, Zn and Cu and their chemical speciations in soils from a peri-smelter area in northeast China

An exploratory study on soil contamination of heavy metals was carried out surrounding Huludao zinc smelter in Liaoning province, China. The distribution of total heavy metals and their chemical speciations were investigated. The correlations between heavy metal speciations and soil pH values in corresponding sites were also analyzed. In general, Cd, Zn, Pb, Cu and As presented a significant contamination in the area near the smelter, comparied with Environmental Quality Standards for Soils in China. The geoaccumulation index showed the degree of contamination: Cd > Zn > Pb > Cu > As. There was no obvious pollution of Cr and Ni in the studied area. The speciation analysis showed that the dominant fraction of Cd and Zn was the acid soluble fraction, and the second was the residual fraction. Pb was mostly associated with the residual fraction, which constituted more than 50% of total concentration in all samples. Cu in residual fraction accounted for a high percentage (40–80%) of total concentration, and the proportion of Cu in the oxidizable fraction is higher than that of other metals. The distribution pattern of Pb and Zn was obviously affected by soil pH. It seemed that Pb and Zn content in acid solution fraction increased with increasing soil pH values, while Cd content in acid soluble fraction accounted for more proportion in neutral and alkaline groups than acidic one. The fraction distribution patterns of Cu in three pH groups were very similar and independent of soil pH values. And the residual fraction of Cu took a predominant part (50%) of the total content.     

Experimental study on the deterioration and natural remediation of the Ariake Sea tidal mud caused by the sea laver treatment acid practice and the upward seepage of pore water liquid

This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly, series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud. With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased.     

Atomistic simulation of the mechanisms of noble gas incorporation in minerals

Atomistic simulations have been carried out to investigate the mechanisms of noble gas incorporation in minerals using both the traditional two-region approach and the “supercell” method. The traditional two-region approach has been used to calculate defect energies for Ne, Ar, Kr and Xe incorporation in MgO, CaO, diopside and forsterite in the static limit and at one atmosphere pressure. The possibilities of noble gas incorporation via both substitution and interstitial mechanisms are studied. The favored mechanism varies from mineral to mineral and from noble gas to noble gas. In all minerals studied, the variation of the solution energies of noble gas substitution with atomic radius appears approximately parabolic, analogous to those for 1⁺, 2⁺, 3⁺ and 4⁺ trace element incorporation on crystal lattice sites. Noble gas solution energies thus also fall on a curve, similar to those previously observed for cations with different charges, but with much lower curvature.The “supercell” method has been used to investigate the pressure dependence of noble gas incorporation in the same systems. Results indicate a large variation of the solubility of the larger noble gases, Kr and Xe with pressure. In addition, explicit simulation of incorporation at the (0 0 1) surface of MgO shows that the solubility of the heavier noble gases may be considerably enhanced by the presence of interfaces.     

等温微量热法在土壤微生物研究方面的进展

土壤微生物是陆地生态系统中分解者亚系统的主要组成部分, 参与了包括有机质降解、营养转化、 植物生长的促进或抑制以及各种土壤物理过程在内的一系列反应活动. 土壤微生物则是土壤质量重要的生物指标, 可以用来监控土壤质量的变化. 等温微量热法是一种简便、快速地测量微生物活性的方法, 在土壤微生物代谢热效应的研究领域中广泛应用. 就等温微量热法在土壤微生物活性中的研究进展进行综述: 等温微量热法的简介, 微量热方法与传统方法的比较, 等温微量热法在各种外界环境和土壤条件影响下的土壤微生物活性研究中的应用, 并对等温微量热法在土壤微生物和其它方面的研究进行了展望.     

Reduction of hydroelastic responses of a very-long floating structure by a floating oscillating-water-column breakwater system

The hydroelastic responses of a very-long floating structure (VLFS) placed behind a reverse T-shape freely floating breakwater with a built-in oscillating water column (OWC) chamber are analyzed in two dimensions. The Bernoulli–Euler beam equation is coupled with the equations of rigid and elastic motions of the breakwater and the VLFS. The interaction of waves between the floating rigid breakwater and the elastic VLFS is formulated in a consistent manner. It has been shown numerically that the structural deflections of the VLFS can be reduced significantly by a suitably designed reverse T-shape floating breakwater.     

鲁中南隆起区第四纪晚期断裂活动特征

根据野外调查，并综合前人的研究资料，对鲁中南地区第四纪晚期断裂活动进行了分析，研究表明，鲁中南隆起区第四纪断裂活动具有时空不均匀性，主要表现为第四纪时期断层活动强度变化和断裂活动的群集性以及第四纪晚期断裂活动段分布的局限性上。对于鲁中南地区而言，活动断层可以分为中更新世中期（500kaBP)至晚更新世初期（90kaBP)活断层和晚更新世中、晚期至全新世早期活断层两类；其中前一类（主要是中更新世断裂）断裂数量较多，分布较为广泛，而晚更新世晚期以来的活动断裂段的数量较少，分布较局限。它们对地震的控制能力不同，前者可控制5．5级左右的地震，而后一类可控制6－7级地震的发生。     

Numerical study of the motions and drift force of a floating OWC device

The motion and the drift force of a floating OWC (oscillating water column) wave energy device in regular waves are studied taking account of the oscillating surface-pressure due to the pressure drop across the duct of the air chamber. The potential problem inside the chamber is formulated by making use of the Green integral equation associated with the Rankine-type Green function while the outer problem with the Kelvin-type Green function. The added mass, wave damping and excitation coefficients as well as the motion and drift force of the OWC device are calculated for various values of parameter related to the pressure drop.     

秦山核电站邻近水域的流况分析

本文分析了秦山核电站邻近水域各测站的实测流、潮流和佘流分布及季节变化。结果表明:测区内潮流为非正规丰日浅海潮流,其运动形式呈往复流。核电站二期工程取水口附近(L_1,18站)为一大流速区,而一期工程出水口周围(L_2,L_2′站)有一相对小的流速区。大流速区落潮流历时大于涨潮流历时,而相对小流速区则相反;大流速区的余流较小,而小流速区的余流大。在四个季节中,涨潮流速秋季最大,春季次之,夏季最小;落潮流速秋季最大,夏季次之,春季最小。余流冬、秋两季较大。在实测流中以潮流为主,径流和季风的作用也相当显著。     

刀额新对虾幼体的培育及特点

在水温26～28℃,pH8.1～8.3,海水盐度27.6～29.7的条件下,刀额新对虾幼体从无节幼体第一期(N_1)培育至仔虾幼体第一期(P_1),历时10d,成活率81.9%;至仔虾幼体第8～10天(P_(8～10)),成活率为80%。刀额新对虾幼体发育具有许多不同于其他对虾类幼体的发育特点,其糠虾期身体仅稍倾斜而不呈倒悬状态,极少摄食丰年虫无节幼体,直至P_(3～4)摄食丰年虫幼体现象才较多见。