Estimation of abl Parameters Using the Vertical Velocity Measurements of an Acoustic Sounder

The friction velocity, the surface heat flux and the height of the Atmospheric Boundary Layer (ABL) are important parameters. In this work, vertical velocity variance ( _w ² ) and wind velocity structure parameter (C _v ² ) profiles estimated by acoustic sounder measurements are used, along with similarity relations, to estimate these parameters in the unstable Atmospheric Boundary Layer and the friction velocity in the stable one. The data were collected by two acoustic sounders with different height range and resolution under various atmospheric conditions (stability) and at two experimental sites in different terrain. The C _v ² profiles are estimated using gate difference of the vertical velocity measurements and the assumption of local isotropy. The vertical velocity data are corrected for the significant effects of noisy measurements and sampling volume averaging on the _w ² and C _v ² estimations using original techniques that are presented in this work. The results of the similarity method using acoustic sounder data are compared against estimates of the corresponding atmospheric parameters obtained from direct measurements. The comparison confirms the ability of the method to provide reasonably accurate estimates of these parameters especially in the middle of the day.     

The estimation of acid dissociation constants in seawater media from potentionmetric titrations with strong base. I. The ionic product of water — Kw

The various assumptions implicit in the calculation of acid dissociation constants (based on ionic medium standard states) from potentiometric titrations using a cell with liquid junction (i.e. a pH measuring cell) have been examined. It was concluded that results can be obtained having an accuracy commensurate with the experimental precision. It has been shown that although the precise composition of the medium is a function of the hydrogen ion concentration (because of the protolytic nature of some of the ions in the media, e.g., sulphate and fluoride), the effect of such variations in the medium composition can be compensated for when defining the activity of hydrogen ion on an ionic medium standard state by defining the concentration of hydrogen ion as:

where β_HSO4 and β_HF are the relevant association constants and S_T and F_T are the total concentrations of sulphate and fluoride, respectively.This approach was used to obtain values for the ionic product of water (K_W) in artificial seawater media at various temperatures and ionic strengths. These were fitted to give the equation (molal concentration units):

$\text{pK}{}_{\mathrm{w}}\text{=}\text{3441.0}\text{T}\text{+2.256-0.7091}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(}\text{rms deviation 0.01}\text{)}$

where I is the formal ionic strength of the artificial seawater medium and T is the absolute temperature. The values obtained are in reasonable agreement with those found by previous workers.     

Igneous dykes and associated scour hollows of the North Channel,Irish Sea

A side-scan sonar survey with complete ground coverage has revealed the presence of numerous, straight, narrow ridges of NNW and NE trends in the North Channel, Irish Sea. They are interpreted as igneous dykes, probably of Tertiary age. The topographic expression of the dykes and their appearance on the sonographs provide indications of considerable erosion by tidal-current scour.     

Some basic notions in geographical synthesis

Modern geography is based on ecological thinking. In this paper some geoecological notions are discussed: the scales and levels regarding spatial magnitude and complexity, the “hierarchy” of landscape units and espcially the scale of time and the concept of the supper-imposing “stamps”. This last mentioned concept is very important in relation to the problem regarding regionalization and its possibilities. Three “stamps” are recognized: 1. the substrate, 2. the climatic conditions, 3. the human (noötic) influence. Holistic regionalization in which all elements (including the human influences) are telling to full advantage, is unsatisfactory.     

Lunar nomenclature: A dissenting note

This note reviews the nature of the traditional (Mädler) lunar nomenclature and the recent developments based on the use of more than 2000 named provinces. It appears that the new nomenclature is less efficient than the old in many cases and may lead to an impossible publication situation. The unnecessary break with the past is especially critized.     

A Comparison of Sediment Varves (1950–2003 AD) in Two Adjacent Lakes in Northern Sweden

Koltjärnen and Nylandssjön are two closely situated lakes (<2 km apart) in northern Sweden. During the past century, distinct varved sediments have formed in these lakes. Nylandssjön has two varved, deep basins. Since lake and catchment characteristics superficially appear very similar for the two lakes and they are exposed to the same climate, one would expect the sediment varves to be similar. This investigation compares the varves in the two deep basins of Nylandssjön, and in the two lakes. The comparison of basins of Nylandssjön shows that varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1970–2003). The grey-scale curves are only clearly similar in about 50% of the varves. In the between-lake comparison varve thickness, water content and annual accumulation rates of organic matter and nitrogen are correlated for the period (1950–1996). However, the annual accumulation rates of dry mass, minerogenic matter and biogenic silica differ between the lakes, as well as within-varve successions in grey-scale. A general explanation to the differences is that the prerequisites for varve formation are not totally similar because of differences in catchment size, catchment- to-lake material fluxes, lake productivity and land-use influence. This study illustrates the complex relationships that exist between a lake, its catchment, in-lake productivity and formation of sediment varves. As a consequence, we must not apply a too simplistic view of the potential of varves as past climatic indicators, especially if the lakes are affected by land-use.     

Rb-Sr whole-rock dating of late diagenetic to anchimetamorphic,palaeozoic sediments in southern France (Montagne Noire)

Rb-Sr whole-rock and mineral analyses are reported from Early Paleozoic sediments of the southern rim of the French Central Massif (Montagne Noire). The sediments—mainly pelites, silt- and sandstones—can be separated into three different zones (A, B, and C) according to their varying degrees of deformation and transformation, which took place during the Hercynian (= Variscan) orogeny (Carboniferous). For the least deformed, folded but not schistose, fossiliferous Lower Ordovician sediments (zone A), a scatter of the data points resulted, at least partly due to the varying amount of detrital muscovites, which did not equilibrate their Sr isotopes with those of the clay minerals. Fossiliferous Middle Cambrian sediments (zone B), however, are colinear in an isochron plot. The rocks are also folded, and show a beginning schistosity in the pelitic layers. The age of 333±16 m.y. therefore does not correspond to the time of sedimentation, as one would expect from most of the interpretations given in the literature. It is, however, in close agreement with the stratigraphically known time of folding and anchimetamorphism. The same result, within analytical error, of 326±17 m.y. was obtained for Lower Ordovician sediments (zone C), which show a schistosity not only in the pelites but also in some psammitic layers. As for the sediments of zone B, this result indicates open whole-rock systems for Rb and/or Sr during folding and anchimetamorphism. Minerals extracted from psammites of zones B and C gave the following results: albite coincides with the isochrons; detrital muscovites do not coincide and yield ages of about 650 m.y. (Cadomian orogeny) for both zone B and C sediments; detrital chlorites from zone B sediments seem to be only partly reset by anchimetamorphism and therefore plot closer to the whole-rock isochron. From this it must be concluded that an increasing amount of these detrital micas could significantly shift the position of the total-rock points, as might be the case for zone A sediments. From the whole-rock results of zone B and C sediments and the mineralogical and petrological changes during diagenesis and anchimetamorphism we conclude that many of the isochrons obtained from stratigraphically uncontrollable Precambrian sediments should be reinterpreted in favour of metamorphic and not sedimentary ages, especially if the metamorphism reached greenschist facies conditions. Devonian and Cambrian limestones intercalated between the pelites, silstones and sandstones contain Sr of a variable and slightly radiogenic isotopic composition in contrast to the expected ancient sea water Sr. This fact is interpreted again in favour of open whole-rock systems during the postdepositional history of the rock, rather than primary scatter of ancient, radiogenic sea water Sr.     

Winter severity in Europe: The fourteenth century

The fourteenth century is known to include a period of winter cooling in Central and Western Europe, but its timing and magnitude are not clearly established. An attempt to obtain a coherent picture from verified documentary evidence yielded 2133 records from a region covering Central Europe and Northern Italy, mostly originating from the Monumenta Germaniae Historica. Temperatures were assessed using semi-quantitative indices on the basis of proxy information on snow-cover, ice and untimely activity of vegetation. Results: A run of cold winters from 1303 to 1328 was followed by a run of average winters up to 1354. Then winter temperatures were extremely variable up to 1375. For the rest of the century they fluctuated somewhat below the average of the twentieth century. The pattern in the first five decades is compared to that in the Late Maunder Minimum (1675–1715). The possible role of forcing factors (variations in solar output, North Atlantic Deep Water formation) is briefly discussed.