Geochemical processes in the saltwater–freshwater transition zone: comparing results of a sand tank experiment with field data

Geochemical processes, occurring in a stable transition zone between saltwater and freshwater, were simulated in a 2D, multi-layer flow chamber experiment. Mixing, calcite dissolution, and oxidative degradation of organic matter were identified as the main controlling factors. The results of the chamber experiment were compared to field data and verified by thermodynamic modeling. Similarity in most ion distributions suggests the general applicability of the experimental method. Differences in the redox conditions between field and experiment were reflected by the oxidants involved in the mineralization of organic carbon; while field data show evidence of sulfate reduction, the presence of oxygen in the laboratory experiment resulted in the reoxidation of sulfides.     

A 50-year record of NO<Subscript>x</Subscript> and SO<Subscript>2</Subscript> sources in precipitation in the Northern Rocky Mountains,USA

Ice-core samples from Upper Fremont Glacier (UFG), Wyoming, were used as proxy records for the chemical composition of atmospheric deposition. Results of analysis of the ice-core samples for stable isotopes of nitrogen (δ¹⁵N, ) and sulfur (δ³⁴S, ), as well as and deposition rates from the late-1940s thru the early-1990s, were used to enhance and extend existing National Atmospheric Deposition Program/National Trends Network (NADP/NTN) data in western Wyoming. The most enriched δ³⁴S value in the UFG ice-core samples coincided with snow deposited during the 1980 eruption of Mt. St. Helens, Washington. The remaining δ³⁴S values were similar to the isotopic composition of coal from southern Wyoming. The δ¹⁵N values in ice-core samples representing a similar period of snow deposition were negative, ranging from -5.9 to -3.2 ‰ and all fall within the δ¹⁵N values expected from vehicle emissions. Ice-core nitrate and sulfate deposition data reflect the sharply increasing U.S. emissions data from 1950 to the mid-1970s.     

Lamprophyric lavas in the Colima graben,SW Mexico

The Colima graben, located in SW Mexico, is one of three grabens which intersect about 50 km SSW of Guadalajara, forming a triple junction. The 90 km long, 20–60 km wide Colima graben represents a N-S rift of the E-W trending Mexican Volcanic Belt. Since the Early Pliocene, the Colima graben has served as a locus for the eruption of alkaline lavas, the most recent of which are basanites and minettes erupted from Late Pleistocene cinder cones (Luhr and Carmichael 1981). In this paper, we report on older alkaline lavas which crop out in the graben's walls. These rocks include phlogopite- and hornblende-bearing lamprophyres, a phlogopite-kalsilite-ankaratrite, and high-K andesites. These lavas crop out throughout the Colima graben area, and are intimately associated with calc-alkaline lavas in the field. Compared to these, the alkaline rocks are strikingly enriched in the incompatible elements, particularly Ba, Sr, P, and the LREE. Unlike the younger Late Pleistocene alkaline cinder cone lavas, most of the graben wall lamprophyres and the high-K andesites represent magmas that appear to have undergone significant evolution since their generation, including fractionation, crustal contamination, and possible magma mixing. Least-squares modeling indicates that the cinder cone minettes represent reasonable parental magmas for the graben lamprophyres. The occurrence of these alkaline lavas in an active calc-alkaline volcanic arc is unusual, and we suggest that they are a manifestation of the rifting processes which produced the Colima graben.     

A statistical analysis applied to the Rf/φ method

A statistical analysis for the R_f/φ method is developed in the paper. The technique provides estimates of R_s, R_i and θ according to R_f and φ. Moreover, we can restore the pattern of initial orientations of marker objects by means of their frequency histogram, provided the strain is homogeneous. It is unnecessary to postulate random initial orientations if the principal directions of strain ellipsoid are known.     

Some aspects of the succession and structure in the lower palaeozoic rocks of the southern uplands of scotland

Lower Palaeozoic successions in the Southern Uplands are much thicker than previously supposed and sedimentation may have lasted well into Ludlow times. Volcanic rocks are Arenig and Glenkiln in age and are often interbedded with greywackes and shales. Lapworth's concept of the structure as an anticlinorium and a synclinorium is rejected and it is suggested that the rocks have been folded into a series of compound monoclines which face north-westwards. These are probably cut by strike faults which bring up the older beds to the north.

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Zusammenfassung Die altpaläozoischen Schichtfolgen in den Südlichen Hochlanden sind viel mächtiger, als bisher angenommen wurde, und die Ablagerung kann bis ins Ludlow gereicht haben. Vulkanite haben Arenig- und Glenkiln-Alter; sie wechsellagern oft mit Grauwacken und Tonschiefern.Lapworths Vorstellung, der tektonische Bau sei ein Antiklinorium und ein Synklinorium, wird bestritten. Es wird angenommen, daß die Gesteine zu zusammengesetzten Monoklinen gefaltet wurden, deren steile Flügel nordwestwärts weisen. Sie werden wahrscheinlich durch streichende Verwerfungen zerschnitten, die die älteren Schichten im Norden herausheben.

     

Pseudoleucite in a Tinguaite from the Bearpaw Mountains, Montana

The article presents chemical analyses of the pseudoleuciteand groundmass of a pseudoleucite tinguaite, chemical analysesof the principal minerals, chemical estimates of the mode ofthe groundmass, and both chemical and micrometric modes of thepseudoleucite. The principal minerals are hedenbergitic acmite,a nepheline containing 2.3 per cent Fe₂O₃ and 7.9 per cent K₂O,and K-feldspar containing a little BaO and very little Na₂O.The micrometric mode of the pseudoleucite, in satisfactory agreementwith the chemical mode, is nepheline 29.8 per cent, K-feldspar66.2 per cent, acmite 3.0 per cent; the chemical mode of thegroundmass is nepheline 26.8 per cent, K-feldspar 46.6 per cent,and acmite 26.7 per cent. A new analysis of a nepheline fromthe Bancroft area, made to test the analytical procedure, isalso included.     

La tectogenèse hercynienne dans la partie occidentale du bassin de l'Ahnet et la région de Bled El-Mass, Sahara Algérien: un continuum de déformation

The study area is located in the north of the Hoggar Basement. It is bounded to the east by the Idjerane-Azaz north-south-trending structural system, the Azzel-Matti Ridge to the south and to the north by the Timimoun Basin. Distribution of the structural elements and the determination of deviatoric stress tensors indicate two main directions for major stress (σ1), one striking northeast-southwest and the other west-northwest-east-southeast. Structural evolution during the Hercynian Orogeny can be considered as a continuous strain rather than as two contrasting tectonic events. The structural features can be attributed to the association of wrench faulting and thrusting, which is compatible with a strain regime of combined pure and simple shear. The basement fabric features exerted a very strong control on the structural evolution during the Hercynian deformation.     

Anoxic carbon degradation in Arctic sediments: Microbial transformations of complex substrates

Complex substrates are degraded in anoxic sediments by the concerted activities of diverse microbial communities. To explore the effects of substrate complexity on carbon transformations in permanently cold anoxic sediments, four substrates—Spirulina cells, Isochrysis cells, and soluble high molecular weight carbohydrate-rich extracts of these cells (Spir-Ex and Iso-Ex)—were added to sediments collected from Svalbard. The sediments were homogenized, incubated anaerobically in gas-tight bags at 0°C, and enzyme activities, fermentation, and terminal respiration were monitored over a 1134 h time course. All substrate additions yielded a fraction (8%-13%) of carbon that was metabolized to CO₂ over the first 384 h of incubation. The timecourse of VFA (volatile fatty acid) production and consumption, as well as the suite of VFAs produced, was similar for all substrates. After this phase, pathways of carbon degradation diverged, with an additional 43%, 32%, 33%, and 8% of Isochrysis, Iso-Ex, Spirulina, and Spir-Ex carbon respired to CO₂ over the next 750 h of incubation. Somewhat surprisingly, the soluble, carbohydrate-rich extracts did not prove to be more labile substrates than the whole cells from which they were derived. Although Spirulina and Iso-Ex differed in physical and chemical characteristics (solid/soluble, C/N ratio, lipid and carbohydrate content), nearly identical quantities of carbon were respired to CO₂. In contrast, only 15% of Spir-Ex carbon was respired, despite the initial burst of activity that it fueled, its soluble nature, and its relatively high (50%) carbohydrate content. The microbial community in these cold anoxic sediments clearly has the capacity to react rapidly to carbon input; extent and timecourse of remineralization of added carbon is similar to observations made at much higher temperatures in temperate sediments. The extent of carbon remineralization from these specific substrates, however, would not likely have been predicted on the basis of general substrate characteristics.