Vulkanogene Glasscherben-Relikte in Kohlentonsteinen des Saar-Lothringer Oberkarbons sowie Herkunft und Menge der Pyroklastika

Zusammenfassung Obwohl Kohlentonsteine aus dem Saar-Lothringer Oberkarbon seit etwa 170 Jahren bekannt sind, gelang erst in jüngster Zeit der Nachweis und die Identifikation vulkanogener Relikte im petrographischen Stoffbestand. Diese befinden sich in Kohlentonsteinen des Stefan A: KTst 0=950; Westfal D: KTst 1=700; Westfal C: KTst 3 =400, KTst 4a=330, KTst 4aß=322, KTst 4=320, KTst 5=300 und im KTst 6=270. Das entspricht einem Anteil von ca. 18 % an der Gesamtzahl der in diesem limnischen Steinkohlenrevier beobachteten Kohlentonsteine, die hier große praktische und wissenschaftliche Bedeutung besitzen. Die pseudomorphen Relikte bestehen aus kleinen Splittern, kleinen und größeren Fragmenten mit teilweise gut erhaltenem blasigen Gefüge von Vitroklasten — sie zeigen die für Aschenschmelztuffe typisch verschweißte Scherbentextur. Die Glassubstanz ist meist zu mikrokristallinem Kaolinit devitrifiziert. Der eindeutige Nachweis dieser Relikte ist für die Genese bedeutungsvoll, liefern sie doch nun den sicheren Beweis, daß der primäre Stoffbestand aus aerisch abgelagertem pyroklastischen Material bestand, das intensive chemische Verwitterungs- und diagenetische Umbildungsprozesse erfahren hat. Für die 43 Kohlentonsteine des Saar-Lothringer Oberkarbons wird eine pyroklastische Eruptionsmenge von mindestens 8,2 km³ Festvolumen bzw. 20,5 km³ Lokkervolumen angenommen. Die Eruptionen erfolgten vermutlich aus der in der Nähe befindlichen Metz-Hunsrück-Südrand-Tiefenstörung, die nach Reflexionsseismik bis unter die Moho reicht.

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Tonsteins in the Carboniferous of the Saar-Lorraine basin are known since about 170 years. Volcanic glass remains, however, have been proven as constituents of the tonstein only recently. They occur in tonsteins of Stephanian A: KTst 0=950; Westphalian D: KTst 1=700; Westphalian C: KTst 3=400, KTst 4a=330, KTst 4aß= 322, KTst 4=320, KTst 5=300 and KTst 6=270. Tonsteins with volcanic glass fragments amount to 18% of the total tonsteins observed in the limnic Saar-Lorraine basin. They are important to applied geology, e.g. for seam identification and correlation, as well as for scientific reasons, namely for the determination of provenance and genesis of tonsteins.The volcanic remains consist of tiny glass splinters, glass fragments, and of fragments with well preserved gasbubble texture. The welded splinter texture is typical of welded pyroclastic ash deposits. Much of the glass has been devitrified to microcrystalline kaolinite. The indisputable evidence of volcanic remains is essential when considering the genesis of tonsteins, as they provide proof that tonsteins are primarily composed of eolian pyroclastic constituents which were altered by chemical weathering and diagenesis.For the 43 horizons of the coal tonsteins found in the Upper Carboniferous of the Saar-Lorraine basin, a pyroclastic eruption quantity of at least 8.2 km³ of solid volume or 20.5 km³ of bulk volume is assumed. The eruptions possibly took place along the nearby deep-seated Metz fault at the southern rim of the Hunsrück. This fault, reaches below the Moho according to reflection seismic.

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Résumé Bien que des tonstein du Carbonifère supérieur de SarreLorraine soient connus depuis 170 ans c'est seulement il y a peu de temps que des fragments de verre volcanique y ont été identifiés. Ces fragments ont été rencontrés dans les niveaux de tonstein suivants: Stephanien A: KTst 0=950; Westphalien D: KTst 1=700; Westphalien C: KTst 3=400, KTst 4a=330, KTst 4aß=322, KTst 4=320, KTst 5=300 et KTst 6=270. Ces niveaux représentent une proportion de l'ordre de 18% dans le total des couches de tonstein carbonifère rencontrées dans ce bassin houiller limnique où elles présentent un grand intérêt tant au point de vue pratique que scientifique. Les verres se présentent en esquilles et en fragments de tailles diverses, montrant parfois une structure bulleuse bien conservée; ils présentent également les structures d'agglomération propres aux tufs soudés à chaud. Le verre est le plus souvent dévitrifié en kaolinite microcristalline. La présence de ces fragments est d'un intérêt particulier pour la genèse du dépôt puisqu'elle fournit la preuve que celui-ci était constitué de matériaux primaires pyroclastiques sédimentés dans l'air, matériaux qui ont subi ensuite des altérations chimiques et des transformations diagénétiques intenses.Pour l'ensemble des 43 horizons de tonstein du Carbonifère supérieur de la Sarre-Lorraine, on admet un volume de matières pyroclastiques d'au moins 8,2 km³ (volume à l'état monolithique) ou de 20,5 km³ (volume à l'état fragmenté). Ces éruptions ont probablement pour origine la faille de Metz, située à proximité, qui forme la limite sud du Hunsrück et que la sismique-réflexion permet de prolonger jusqu'au Moho.

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Das Thema dieser Arbeit war Gegenstand des KurzvortragesBurger &Wolf (1987) auf dem XI. ICC in Peking (31. 8. bis 4. 9. 1987). Vorliegende Bearbeitung stellt die originäre Fassung dar.     

Crustal structure of the Rhenish Massif: results of deep seismic reflection lines Dekorp 2-North and 2-North-Q

The reflection seismic line DEKORP 2-N reveals an almost complete cross section through the Rhenohercynian Zone, the most external part of the Variscan orogen in Europe.The northern part of DEKORP 2-N and a NE-directed branch (2-N-Q) reveal the Cretaceous of the Münsterland basin and the underlying folded Palaeozoic rocks. The northward decreasing intensity of folding is depicted in great detail by the highly reflective Late Carboniferous coal-measures and deeper reflections down to the level of the Givetian/Frasnian shallow-water carbonates.In the Devonian and older rocks of the Rhenish Massif, bedding is only represented by relatively weak, short and irregular reflections. These are truncated by stronger, southward dipping reflections, which exhibit the listric curvature and flat/ramp geometry characteristic of faults. In the northern part of the section, the thrusts appear to be blind. From the Ebbe Anticline southwards, prominent reflections can be correlated with important thrust faults known from the surface, such as the Ebbe-, Siegen-, Müsen- and Sackpfeife- Thrusts, as well as further important thrust faults in the Lahn- and Dill Synclines. The basal thrust of the extremely thin-skinned Giessen Nappe is only recognizable for a very short distance.At depth, the thrusts flatten out in a relatively transparent zone between 3–5 s TWT, with strongly reflective bands at its bottom and top. The transparent zone might correlate with a high-conductivity layer detected in a magnetotelluric survey; it represents either graphitic metapelites or a zone with an interconnected, brine-filled pore space. The seismic record relates either to lithological differences, or to rheological boundaries.The lower crust in the north is characterized by a relatively transparent zone, which wedges out towards south under the northern margin of the Siegen Anticline. Comparisons with a similar feature in the ECORS profile »Nord de la France« suggest that the transparent zones in both sections correspond to a pre-Palaeozoic basement, such as it underlies the Brabant Massif. Further south, the lower crust is increasingly reflective.The curvilinear, thrust-related reflections are cut by a conjugate set of much weaker, N- and S-dipping reflectors indicating a later deformation with pure shear. Displacement of some marker reflections suggests late- or post-Variscan compression.In an alternative interpretation, these straight and weak reflections represent the only thrust faults, while the curvilinear elements might relate to bedding.A southward rise of the Moho from approx. 11 to 8.5 s TWT is probably due to Tertiary rifting.

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Zusammenfassung Das reflexionsseismische Profil DEKORP 2-N stellt einen fast vollständigen Querschnitt durch das Rhenohercynikum dar.Der nördliche Teil des Profiles 2-N sowie ein SW/NE-verlaufender Abzweig (2-N-Q) zeigen die Transgression der Münsterländer Kreide und das unterlagernde gefaltete Paläozoikum. Schichtgebundene Reflektoren (flözführendes Karbon, devonischer Massenkalk) bilden das Ausklingen der variscischen Faltung nach NW detailliert ab.In den devonischen und vordevonischen Sedimenten des rechtsrheinischen Schiefergebirges erzeugt die Schichtung nur relativ schwache, kurze und unregelmäßige Reflexionen. Diese werden von stärkeren, südfallenden Reflektoren abgeschnitten, die aufgrund ihrer listrischen Krümmung und flat/ramp-Geometrie wahrscheinlich als Überschiebungen zu interpretieren sind. Im Nordteil des Schiefergebirges sind diese Überschiebungen offenbar blind, werden also nahe der Oberfläche durch Faltung kompensiert. Im Ebbe-Sattel und weiter südlich lassen sich die meisten der starken, südfallenden Reflektoren zweifelsfrei mit bekannten Großüberschiebungen korrelieren (Ebbe-, Siegen-, Müsen-, Sackpfeife-Ü, sowie weitere Überschiebungen in der Lahn- u. Dill-Mulde). Die Basisüberschiebung der Giessen-Decke wird nur teilweise abgebildet.Zur Tiefe hin zeigen die Überschiebungen ein zunehmend flacheres Einfallen, und verschwinden in einer relativ transparenten Zone zwischen 3 und 5 s TWT, die im Hangenden und Liegenden durch dünne, stark reflektive Zonen begrenzt ist. Diese transparente Zone entspricht möglicherweise einer Zone hoher integrierter Leitfähigkeit, die in einem begleitenden magnetotellurischen Experiment nachgewiesen worden ist; es handelt sich entweder um einen Graphit-führenden Phyllit-Horizont oder eine mächtigere permeable Zone mit Elektrolyt-gefülltem Porenraum. Die hochreflektiven Bänder über und unter der transparenten Zone entsprechen entweder lithologischen Kontrasten oder rheologischen Grenzen, die vermutlich von einer scherenden Verformung überprägt worden sind.Die Unterkruste im N-Teil des Profiles enthält einen relativ transparenten Bereich, der nach Süden hin unter dem Nordteil des Siegener Sattels keilförmig ausläuft. Ein ähnliches Bild zeigt der Nordteil des ECORS-Profiles »Nord de la France«. Die transparenten Bereiche beider Profile entsprechen wahrscheinlich einem prä-paläozoischen kristallinen Basement, das das Brabanter Massif unterlagert und sich rechtsrheinisch fortsetzt. Südlich des transparenten Keiles wird die Unterkruste zunehmend reflexionsreicher. Die listrisch gekrümmten, an Überschiebungen gebundenen Reflektoren werden von einem konjugierten System schwächerer, N- u. S-fallender Reflektoren abgeschnitten, die auf eine jüngere, bruchhafte Verformung durch reine Scherung hindeuten. Der Versatz einiger älterer Reflektoren deutet auf spät- oder postvariscische Kompression hin.In einer alternativen Interpretation werden nur diese jüngeren Reflektoren als Überschiebungen gedeutet; die älteren, gekrümmten Elemente müßten dann primären lithologischen Grenzen entsprechen.Die Moho steigt von ca. 11 s TWT im N auf 8.5 s TWT unter dem Taunus an. Die Krustenverdünnung im Süden geht wahrscheinlich auf Dehnung im Tertiär zurück.

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Résumé Le profil sismique par réflexion DEKORP-2-N représente une transversale quasiment complète à travers la zone rhénohercynienne. La partie septentrionale du DEKORP-2-N ainsi qu'une branche de direction SW-NE (2-N-Q) mettent en évidence la transgression du Crétacé du Münsterland sur le Paléozoïque sous-jacent plissé. Des réflecteurs liés à la stratification (à savoir: le Houiller et les calcaires de plate-forme dévoniens) illustrent de façon détaillée la diminution vers le nord de l'intensité du plissement varisque.Dans les sédiments dévoniens et pré-dévoniens du Massif Rhénan à l'est du Rhin, la stratification ne fournit que que des réflexions relativement faibles, courtes et irrégulières. Elles sont tronquées par des réflecteurs plus intenses, à pendage sud qui, en raison de leur courbure listrique et de leur géométrie en «flat/ramp», doivent être interprétés comme des chevauchements. Dans la partie septentrionale du Massif, ces chevauchements sont apparemment aveugles, c'est-à-dire qu'ils sont compensés, près de la surface, par le plissement. Dans l'anticlinal d'Ebbe, ainsi que plus au sud, la plupart des réflecteurs intenses à plongement sud peuvent être corrélés avec des chevauchements majeurs connus, tels ceux de Ebbe, Siegen, Müsen, Sackpfeife et d'autres encore dans les synclinaux de la Lahn et de la Dill. Le chevauchement basai de la nappe de Giessen n'est que partiellement représenté.Les chevauchements deviennent de plus en plus plats en profondeur pour disparaître dans une zone relativement transparente qui se situe entre 3–5 sec TWT. Celle-ci est prise en sandwich par des zones minces à forte réflectivité. La zone transparente correspond probablement à une zone de conductivité intégrée élevée dont l'existence a par ailleurs été démontrée dans un essai magnétotellurique mené parallèlement. Il s'agit soit d'un horizon phyllitique graphiteux, soit d'une zone perméable plus épaisse dont les pores sont remplis d'électrolyte. Les bandes à haute réflectivité au-dessus et en-dessous de la zone transparente correspondent soit à des contrastes lithologiques, soit à des limites rhéologiques probablement accentuées par la déformation cisaillante.La croûte inférieure dans la partie septentrionale du profil comporte un domaine relativement transparent qui s'amincit vers le S et se termine, en dessous de la partie nord de l'anticlinal de Siegen, en forme de coin. La partie nord du profil ECORS «Nord de la France» montre une image semblable.Les domaines transparents des deux profils correspondent vraisemblablement à un soubassement cristallin pré-paléozoïque qui est sousjacent au Paléozoïque du Massif du Brabant et se prolonge vers l'est au-delà du Rhin. Au sud du coin transparent, la réflectivité de la croûte inférieure va en augmentant. Les réflecteurs listriques liés à des chevauchements sont recoupés par un système conjugué de réflecteurs plus faibles à plongement nord et sud qui indiquent des failles plus récentes. Le déplacement de quelques réflecteurs plus anciens suggère l'effet d'une compression tardiou post-varisque.Dans une interprétation alternative, seuls ces réflecteurs plus récents sont considérés comme correspondant à des chevauchements. Dans ce cas, les éléments courbes plus anciens devraient représenter des limites lithologiques primaires.Le Moho s'élève à partir de 11 sec TWT environ au nord jusqu'à 8.5 sec TWT en-dessous du Taunus. L'amincissement crustal au sud résulterait du régime de distension survenu au Tertiaire.

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DEKORP 2 Nord. x-t- ray-tracing'a. 6,0 6,6 /, — 7,0 8,2 /. 6,25 /. 28 30 . , .

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Abbreviations MORB Mid-Ocean Ridge Basalt - TWT two-way travel time, seconds (s) - CMP common mid-point - VP vibration point - SNR signal to noise ratio     

Equatorial disturbances,monsoons, and 1982–1983 ENSO

Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T _* ). Normal atmospheric monsoon circulations are defined by long-term average winds (u _n,v _n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u _L,v _L); 7–20 day filtered winds (u _M,v _M); and 2–6 day filtered winds (u _S,v _S). Three-month running mean anomaly kinetic energy (signified asK _L , K _M , andK _S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK _L , K _M , andK _S perturbations propagate slowly eastward with same phase speed (0.3 ms^–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K _L , K _M , K _S ) and interannualu (OLR) modes. Namely, (K _L , K _M , K _S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K _L , K _M , K _S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T _* 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT _* variations on interannual time scales. HighestT _* occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT _* variations are also controlled by the prevailing monsoonal zonal windsu _n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.     

On mountain wave drag over complex terrain

Summary Mountain wave drag is calculated for rotating, stratified, nonhydrostatic Boussinesq flow over a mountain ridge using linear theory for a variety of mountain profiles representing complex/irregular terrain. The inclusion of a sinusoidal corrugation to the familiar witch-of-Agnesi profile creates a stegosaurus profile. The associated drag is greatly enhanced for mesoscale mountains when the corrugation wave-number matches that for the dominant inertia-gravity wave contribution to the cross-mountain surface pressure gradient. Similarly, increasing the jaggedness (by decreasing the exponentb) increases the drag for mesoscale mountains whose topographic spectral intensity,M(k), has the form of a power law:M(k)=mk ^–b wherek is the zonal wavenumber.Spectral analysis of one-kilometer resolution topographic data for the Appalachian Mountains suggests that a power law profile withb=1.7 accurately represents the topographic spectral intensity and that it yields good estimates of the drag.The application of these results to the parameterization of mountain wave drag in general circulation models is discussed.With 7 Figures     

Todays knowledge of the solar EUV output and the future needs for more accurate measurements for aeronomy

In recent years discrepancies arose in the determination of the solar EUV output. It is difficult and often impossible to remove these discrepancies from the observational data reported so far. However, the EUV data show evidence for a strong variability during the Solar Cycle 20. The measuring methods applied so far create uncertainties of the order of ± 30% or less. Therefore, new methods have to be developed for more accurate measurements. Two approaches offer the possibility of overcoming todays shortcomings. With these methods the EUV indices will be measured with an accuracy better than 10%, using a simple spectrometer on a free-flying long-term mission with recalibration factors provided by short-term mission results e.g. from Soyuz or Spacelab.     

TRANSALP—deep crustal Vibroseis and explosive seismic profiling in the Eastern Alps

The TRANSALP consortium, comprising institutions from Italy, Austria and Germany, carried out deep seismic reflection measurements in the Eastern Alps between Munich and Venice in 1998, 1999 and 2001. In order to complement each other in resolution and depth range, the Vibroseis technique was combined with simultaneous explosive source measurements. Additionally, passive cross-line recording provided three-dimensional control and alternative north–south sections. Profits were obtained by the combination of the three methods in sectors or depths where one method alone was less successful.The TRANSALP sections clearly image a thin-skinned wedge of tectonic nappes at the northern Alpine front zone, unexpected graben or half-graben structures within the European basement, and, thick-skinned back-thrusting in the southern frontal zone beneath the Dolomite Mountains. A bi-vergent structure at crustal scale is directed from the Alpine axis to the external parts. The Tauern Window obviously forms the hanging wall ramp anticline above a southward dipping, deep reaching reflection pattern interpreted as a tectonic ramp along which the Penninic units of the Tauern Window have been up-thrusted.The upper crystalline crust appears generally transparent. The lower crust in the European domain is characterized by a 6–7 km thick laminated structure. On the Adriatic side the lower crust displays a much thicker or twofold reflective pattern. The crustal root at about 55 km depth is shifted around 50 km to the south with respect to the main Alpine crest.     

Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).     

Results from a Multi-disciplinary Sedimentary Pilot Study of Tectonic Lake Iznik (NW Turkey) – Geochemistry and Paleolimnology of the Recent Past

A limnogeological reconnaissance study was carried out on Lake Iznik, located in the southeast of the Marmara region of Turkey, involving a seismic survey and collection of short sediment cores. This lake is located on the middle branch of the North Anatolian Fault Zone (NAFZ), a transform plate boundary between the Eurasian and Anatolian Plates. It is, therefore, tectonically active and offers an opportunity to investigate the interplay of sedimentary and seismo-tectonic processes, as well as climate change and human impact in the region. Short cores of the three sub-basins, maximum length of 35.5 cm, recovered non-laminated, blackish clays and silts with varying amounts of biogenic and minerogenic (allochthonous, autochthonous) material, which documented almost the last 80 years of deposition and environmental history. High sedimentation rates in the deeper core sections are accompanied by changes in land use (conversion of woodland to farmland) in the northern areas of Lake Iznik, which caused the deposition of more weathered material (high K/Na ratios) and higher contents of Mn in the lake. A tendency towards eutrophic conditions within the last 20 years is indicated by high nutrient content (N, TOC, P), decreasing C/N-ratios, and characteristic diatom and cladoceran associations. Also increased pollution is revealed by higher Pb, Cu, and Zn contents and increased supply of human and animal faeces (high coprostanol content) during the last two decades. But simultaneous lower sedimentation rates towards the core tops complicate the reconstruction of recent and past eutrophication and pollution states of Lake Iznik. This requires an extension of the pilot study and deeper sediment cores, to recover non-anthropogenic influenced sediment levels.     

Decision-support systems for groundwater protection: innovative tools for resource management

Governmental authorities are forced by law to make decisions within the framework of European, national and regional directives in the fields of spatial planning, groundwater and environmental protection. These tasks can be supported by a decision-support system, which integrates data from various sources and helps to make decision processes more effective and transparent. Basic work for such a decision support system has been done in a transnational and interdisciplinary project (Interreg II C: KATER), including metadata definition, metadata system, cartographic tools and GIS tools. The direct integration of these tools and information in the decision process will be implemented in the next few years (project KATER II).