A study on the flux,speciation, and budget of mercury in controlled experimental ecosystems

The lowest addition of mercury (0.1 ug Hg 1⁻¹) was used in CEEs for research on mercury flux, speciation and budget. The removal behavior of mercury by phytoplankton in water columns of CEEs can be described by first order kinetic equations for total and particulate mercury in the CEE spiked by mercury. The removal rate of mercury in water columns depends on the size and productivity of phytoplanton in a water column to which mercuric ions were added. A 4.4 day half-life time and a 2.8 day half-life time for total and particulate mercury respectively was obtained in diatom bloom. During microflagellate bloom a 30 day total mercury half-life time was estimated with increase of particulate mercury in the water column. The 0.010 ug Hg cm⁻²y⁻¹ mercury flux rate that was attained in the control bag agreed with the values from field measurements in Saanich Inlet where the bags were launched. The proportion of total mercury to dissolved and particulate mercury depended also on the size, productivity, and concentration of mercury in a water column. A more or less constant distribution of mercury species in the control bag was observed as follows: dissolved Hg 0.73, particulate Hg 0.27, inorganic Hg 0.42, dissolved organic Hg 0.31. After spiking with mercury, the particulate mercury rose rapidly and reached to over 70% of the total mercury. The concentration factor of mercury by phytoplankton in the CEEs in the order of 10⁵ was consistent with the results from field measurements in Saanich Inlet. The mercury recovery from the water column, sediment, water with sediment, and the CEE bag walls was only 52.3% of total mercury spiked in the CEE. The losses of mercury by vaporization into the ambient air and diffusion through the wall of the enclosure should be considered. This paper was published in Chinese inOcean. Limn. Sinica,17(4):307–317, 1986.     

Structural modeling and testing of a concrete canoe

A finite element model is set up and experimental tests are performed to help understand the behavior of a concrete canoe and subsequently optimize its design. First, the performance criteria that must be satisfied to participate at the annual ASCE/Master Builders competition are described. Then, the finite element model and the different loading cases that were studied are presented. Results from these loading cases are discussed and used to optimize the material properties as well as the thickness of the hull and the dimensions of the gunwale and reinforcing ribs. Static and dynamic experimental tests were also conducted to validate the results of the finite element analyses. The results indicate that the main stresses and strains are caused by the static load cases. The additional stresses caused during races are small.     

Preliminary attempt to characterize the rotation of seafloor in the Pito Deep area of the Easter Microplate using a submersible magnetometer

Several mechanisms have been proposed to account for the rotation of the nearly north-south abyssal hill fabric formed on the East Pacific Rise north of the Easter Microplate to the nearly east-west trends in the northern microplate interior. Proposed mechanisms include rigid microplate rotation, transform fault – parallel shear, and bookshelf faulting during the transfer of lithosphere from the Nazca Plate to the microplate. We used a submersible magnetometer on a NAUTILE dive program to measure the magnetic vector rotation of a pillow basalt and dike spur near Pito Deep, the present location of the tip of the propagating rift system that created the microplate. Our results, although too limited to draw strong conclusions from, suggest clockwise rotations of the seafloor magnetic vectors inconsistent with the transform-parallel shear model, and larger than can be explained solely by rigid microplate rotation.     

Problems with biogenic silica measurement in marginal seas

Surface sediment samples from the Bohai, Yellow Sea, and the Pacific were used to assess biogenic silica (BSi) content and to study uncertainties in BSi measurements. The contents of BSi in the Bohai and Yellow Sea are all less than 1%. The dissolution of BSi in sediments from the Bohai and Yellow Sea is very important to maintain high levels of silicate in the water column. The non-biogenic silica from clay minerals has an obvious effect on BSi of sediment samples in the Bohai and Yellow Sea with low BSi and high clay minerals. The solid to solution ratio was found to have a great influence on BSi measurement, which can induce uncertainties up to 75%. The effect of loss by sorption and centrifugation is negligible. Interlaboratory comparison of techniques for BSi measurement by the wet alkaline extraction technique of Mortlock and Froelich [Deep-Sea Res. 36 (1989) 1415-1426] with clay correction was suggested to give no significant differences. However, differences in sediment compositions and reagent to sample ratio may limit the application of the wet alkaline extraction method.     

Successful sidetracking of a well onshore Germany by integration of 3D vertical seismic profiling technology – a case study

The exploration for and exploitation of deep Lower Rotliegend gasfields onshore in North Germany often suffers from poor surface seismic imaging. This is owing to the depth of the reservoirs and a thick and complex Zechstein salt overburden. RWE Dea conducted a 3D vertical seismic profile (VSP) survey in a low‐performing production well after the borehole was plugged near total depth. Our main objective was to improve the seismic image of the reservoir zone in the vicinity of the well to determine a new landing point for a planned sidetrack. Because acquisition was in a densely populated and also partially environmentally protected area, there were surface restrictions concerning source deployment. Additionally, due to the complex geological setting, we conducted two 2D VSP field tests and thorough pre‐survey modelling to achieve the best results in terms of seismic imaging, environmental impact and reasonable cost. Deformation bands in the drill core suggest that the initial well was drilled close to a major fault, which was regarded as the main reason for the disappointing production rate. Therefore, we put special emphasis on fault detection in our processing and interpretation. Our interpretation approach used an enhanced structural mapping workflow that helped to design a sidetrack. When the sidetrack was drilled two years later, it ended up being one of the most productive wells in the field.     

Continental ridges in the Arctic Ocean: Lorex constraints

Recent multidisciplinary geophysical measurements over the Lomonosov Ridge close to the North Pole support the widely held belief that it was formerly part of Eurasia. The known lithologies, ages, P-wave velocity structure and thickness of the crust along the outer Barents and Kara continental shelves are similar to permitted or measured values of these parameters newly acquired over the Lomonosov Ridge. Seismic, gravity and magnetic data in particular show that the ridge basement is most likely formed of early Mesozoic or older sedimentary or low-grade metasedimentary rocks over a crystalline core that is intermediate to basic in composition. Short-wavelength magnetic anomaly highs along the upper ridge flanks and crest may denote the presence of shallow igneous rocks. Because of the uncertain component of ice-rafted material, seafloor sediments recovered from the ridge by shallow sampling techniques cannot be clearly related to ridge basement lithology without further detailed analysis. The ridge is cut at the surface and at depth by normal faults that appear related to the development of the Makarov Basin. This and other data are consistent with the idea that the Makarov Basin was formed by continental stretching rather than simple seafloor spreading. Hence the flanking Alpha and Lomonosov ridges may originally have been part of the same continental block. It is suggested that in Late Cretaceous time this block was sheared from Eurasia along a trans-Arctic left-lateral offset that may have been associated with the opening of Baffin Bay. The continental block was later separated from Eurasia when the North Altantic rift extended into the Arctic region in the Early Tertiary. The data suggest that the Makarov Basin did not form before the onset of rifting in the Artic.     

Effects of climate change on the groundwater system in the Grote-Nete catchment,Belgium

The effects of climate change on the groundwater systems in the Grote-Nete catchment, Belgium, covering an area of 525 km², is modeled using wet (greenhouse), cold or NATCC (North Atlantic Thermohaline Circulation Change) and dry climate scenarios. Low, central and high estimates of temperature changes are adopted for wet scenarios. Seasonal and annual water balance components including groundwater recharge are simulated using the WetSpass model, while mean annual groundwater elevations and discharge are simulated with a steady-state MODFLOW groundwater model. WetSpass results for the wet scenarios show that wet winters and drier summers are expected relative to the present situation. MODFLOW results for wet high scenario show groundwater levels increase by as much as 79 cm, which could affect the distribution and species richness of meadows. Results obtained for cold scenarios depict drier winters and wetter summers relative to the present. The dry scenarios predict dry conditions for the whole year. There is no recharge during the summer, which is mainly attributed to high evapotranspiration rates by forests and low precipitation. Average annual groundwater levels drop by 0.5 m, with maximum of 3.1 m on the eastern part of the Campine Plateau. This could endanger aquatic ecosystem, shrubs, and crop production.     

Anthropogenic subsidence in the Mexicali Valley,Baja California,Mexico, and slip on the Saltillo fault

Deep fluid extraction in the Cerro Prieto geothermal field (CPGF) has caused subsidence and induced slip on tectonic faults in the Mexicali Valley (Baja California, Mexico). The Mexicali Valley is located in the southern part of the Salton Trough, at the boundary between the Pacific and North American plates. The Valley is characterized by being a zone of continuous tectonic deformation, geothermal activity, and seismicity. Within the Cerro Prieto pull-apart basin, seismicity is concentrated mainly in swarms, while strong earthquakes have occurred in the Imperial and Cerro Prieto transform faults, that are the eastern and western bound of the basin. Since 1973, fluid extraction at the CPGF has influenced deformation in the area, accelerating the subsidence and causing rupture (frequently as vertical slip or creep) on the surface traces of tectonic faults. Both subsidence and fault slip are causing damage to infrastructure like roads, railroad tracks, irrigation channels, and agricultural fields. Currently, accelerated extraction in the eastern part of CPGF has shifted eastwards the area of most pronounced subsidence rate; this accelerated subsidence can be observed at the Saltillo fault, a southern branch of the Imperial fault in the Mexicali Valley. Published leveling data, together with field data from geological surveys, geotechnical instruments, and new InSAR images were used to model the observed deformation in the area in terms of fluid extraction. Since the electricity production in the CPGF is an indispensable part of Baja California economy, extraction is sure to continue and may probably increase, so that the problem of damages caused by subsidence will likely increase in the future.     

A Shear Model Accounting Scale Effect in Rock Joints Behavior

Understanding the scale effect on the mechanical behavior of a single rock joint is still very important in rock engineering. Rock joints can be classified into three different categories depending on their scale: the “micro scale” which is the scale of the asperities; the “meso scale” is the scale of the specimens tested in laboratory; and the “macro scale” which is the scale of the rock mass. The purpose of this paper is to propose an effective way to model rock joints at both the meso and macro scale. An original constitutive mechanical model, in which parameters are deduced from experimental results, has been developed. This model is then extended to simulate the discontinuities occurring at a larger size. At the macro scale, the constitutive modeling was carried out for both small and large relative displacements. Large displacements lead to substantial changes in dilation. For both cases, the peak shear stress vanishes for joints longer than 2 m.