Improvements in height datum transfer expected from the GOCE mission

 One of the aims of the Earth Explorer Gravity Field and Steady-State Ocean Circulation (GOCE) mission is to provide global and regional models of the Earth's gravity field and of the geoid with high spatial resolution and accuracy. Using the GOCE error model, simulation studies were performed in order to estimate the accuracy of datum transfer in different areas of the Earth. The results showed that with the GOCE error model, the standard deviation of the height anomaly differences is about one order of magnitude better than the corresponding value with the EGM96 error model. As an example, the accuracy of the vertical datum transfer from the tide gauge of Amsterdam to New York was estimated equal to 57 cm when the EGM96 error model was used, while in the case of GOCE error model this accuracy was increased to 6 cm. The geoid undulation difference between the two places is about 76.5 m. Scaling the GOCE errors to the local gravity variance, the estimated accuracy varied between 3 and 7 cm, depending on the scaling model. Received: 1 March 2000 / Accepted: 21 February 2001     

Modelling landscape evolution

Geomorphology is currently in a period of resurgence as we seek to explain the diversity, origins and dynamics of terrain on the Earth and other planets in an era of increased environmental awareness. Yet there is a great deal we still do not know about the physics and chemistry of the processes that weaken rock and transport mass across a planet's surface. Discovering and refining the relevant geomorphic transport functions requires a combination of careful field measurements, lab experiments, and use of longer‐term natural experiments to test current theory and develop new understandings. Landscape evolution models have an important role to play in sharpening our thinking, guiding us toward the right observables, and mapping out the logical consequences of transport laws, both alone and in combination with other salient processes. Improved quantitative characterization of terrain and process, and an ever‐improving theory that describes the continual modification of topography by the many and varied processes that shape it, together with improved observation and qualitative and quantitative modelling of geology, vegetation and erosion processes, will provide insights into the mechanisms that control catchment form and function. This paper reviews landscape theory – in the form of numerical models of drainage basin evolution and the current knowledge gaps and future computing challenges that exist. Copyright © 2010 John Wiley & Sons, Ltd.     

Effect of adsorbed metal ions on the transport of Zn- and Ni-EDTA complexes in a sand and gravel aquifer

Adsorption, complexation, and dissolution reactions strongly influenced the transport of metal ions complexed with ethylenediaminetetraacetic acid (EDTA) in a predominantly quartz-sand aquifer during two tracer tests conducted under mildly reducing conditions at pH 5.8 to 6.1. In tracer test M89, EDTA complexes of zinc (Zn) and nickel (Ni), along with excess free EDTA, were injected such that the lower portion of the tracer cloud traveled through a region with adsorbed manganese (Mn) and the upper portion of the tracer cloud traveled through a region with adsorbed Zn. In tracer test S89, Ni- and Zn-EDTA complexes, along with excess EDTA complexed with calcium (Ca), were injected into a region with adsorbed Mn. The only discernable chemical reaction between Ni-EDTA and the sediments was a small degree of reversible adsorption leading to minor retardation. In the absence of adsorbed Zn, the injected Zn was displaced from EDTA complexes by iron(III) [Fe(III)] dissolved from the sediments. Displacement of Zn by Fe(III) on EDTA became increasingly thermodynamically favorable with decreasing total EDTA concentration. The reaction was slow compared to the time-scale of transport. Free EDTA rapidly dissolved aluminum (Al) from the sediments, which was subsequently displaced slowly by Fe. In the portion of tracer cloud M89 that traveled through the region contaminated with adsorbed Zn, little displacement of Zn complexed with EDTA was observed, and Al was rapidly displaced from EDTA by Zn desorbed from the sediments, in agreement with equilibrium calculations. In tracer test S89, desorption of Mn dominated over the more thermodynamically favorable dissolution of Al oxyhydroxides. Comparison with results from M89 suggests that dissolution of Al oxyhydroxides in coatings on these sediment grains by Ca-EDTA was rate-limited whereas that by free EDTA reached equilibrium on the time-scale of transport. Rates of desorption are much faster than rates of dissolution of Fe oxyhydroxides from sediment-grain surfaces and, therefore, adsorbed metal ions can strongly influence the speciation of ligands like EDTA in soils and sediments, especially over small temporal and spatial scales.     

Assessment of boundary-element method for modelling a free-floating sloped wave energy device. Part 1: Numerical modelling

The boundary-element method has been widely used as a design tool in the offshore and ship building industry for more than 30 years. Its application to wave energy conversion is, however, more recent. This paper deals with the numerical modelling of a free-floating sloped wave energy device. The power take-off mechanism of the device consists of an immersed tube with a piston sliding inside. The modelling is done using the boundary-element method package WAMIT. The model is first worked out for the case where the axis of the tube is vertical. It is then derived for the tube inclined and successfully verified against numerical benchmark data. A companion paper presents results of a detailed comparison with a physical model study.     

Role of the subducted slab,mantle wedge and continental crust in the generation of adakites from the Andean Austral Volcanic Zone

 All six Holocene volcanic centers of the Andean Austral Volcanic Zone (AVZ; 49–54°S) have erupted exclusively adakitic andesites and dacites characterized by low Yb and Y concentrations and high Sr/Y ratios, suggesting a source with residual garnet, amphibole and pyroxene, but little or no olivine and plagioclase. Melting of mafic lower crust may be the source for adakites in some arcs, but such a source is inconsistent with the high Mg# of AVZ adakites. Also, the AVZ occurs in a region of relatively thin crust (<35 km) within which plagioclase rather than garnet is stable. The source for AVZ adakites is more likely to be subducted oceanic basalt, recrystallized to garnet-amphibolite or eclogite. Geothermal models indicate that partial melting of the subducted oceanic crust is probable below the Austral Andes due to the slow subduction rate (2 cm/year) and the young age (<24 Ma) of the subducted oceanic lithosphere. Geochemical models for AVZ adakites are also consistent with a large material contribution from subducted oceanic crust (35–90% slab-derived mass), including sediment (up to 4% sediment-derived mass, representing approximately 15% of all sediment subducted). Variable isotopic and trace-element ratios observed for AVZ adakites, which span the range reported for adakites world-wide, require multistage models involving melting of different proportions of subducted basalt and sediment, as well as an important material contribution from both the overlying mantle wedge (10–50% mass contribution) and continental crust (0–30% mass contribution). Andesites from Cook Island volcano, located in the southernmost AVZ (54°S) where subduction is more oblique, have MORB-like Sr, Nd, Pb and O isotopic composition and trace-element ratios. These can be modeled by small degrees (2–4%) of partial melting of eclogitic MORB, yielding a tonalitic parent (intermediate SiO₂, CaO/Na₂O>1), followed by limited interaction of this melt with the overlying mantle (≥90% MORB melt, ≤10% mantle), but only very little (≤1%) or no participation of either subducted sediment or crust. In contrast, models for the magmatic evolution of Burney (52°S), Reclus (51°S) and northernmost AVZ (49–50°S) andesites and dacites require melting of a mixture of MORB and subducted sediment, followed by interaction of this melt not only with the overlying mantle, but the crust as well. Crustal assimilation and fractional crystallization (AFC) processes and the mass contribution from the crust become more significant northwards in the AVZ as the angle of convergence becomes more orthogonal. Received: 1 March 1995 / Accepted: 13 September 1995     

Constraints of stable isotopes on the origin of alunite from advanced argillic alteration systems in Bulgaria

Voluminous areas of advanced argillic alteration (AAA) constitute major exploration targets for surficial Cu–Au epithermal and potentially underlying porphyry-type deposits. In Bulgaria, more than 30 alunite occurrences are recognised, few of them being associated with a mineralised system. A mineralogical study combined with a stable isotopic (O, H, S) study has been carried out on nine alunite occurrences of advanced argillic zones hosted by volcanic rocks of Late Cretaceous age in the Srednogorie belt and of Oligocene age in the Rhodopes belt. This work was realised in order to constrain the origin of alunite and to define criteria to discriminate alunite from ore deposits and alunite from large barren alteration systems.Mineralogy of the nine occurrences consists of alunite + quartz + minor alumino-phospho-sulphates, associated with more or less kaolinite, dickite, pyrophyllite, diaspore and zunyite, depending on formation temperature. Alunite generally occurs as tabular crystals but is also present as fine-crystalline pseudocubic phases at Boukovo and Sarnitsa, in Eastern Rhodopes. In the advanced argillic alterations associated with economic ore, the presence of zunyite in the deeper parts indicates acid–fluorine–sulphate hydrothermal systems, whereas it is absent in uneconomic and barren advanced argillic alteration. All occurrences are formed at temperatures between 200 and 300 °C.(H, O, S) isotopic signatures of alunite combined with mineralogical features from all the studied occurrences, whatever their type, show characteristics of magmatic-hydrothermal systems. Sulphur data indicate essentially a magmatic origin for sulphur. Oxygen and hydrogen data suggest that hydrothermal fluids result from a mixing between magmatic fluids and an external component, which is identified as seawater-derived fluids or meteoric water in the vicinity of a sea. In most of the alunite occurrences, magmatic fluids are dominant and H₂S/SO₄ ratios are estimated to be higher than 2. Two exceptions exist in the Rhodopes. At Boukovo and Sarnitsa, where the estimated formation temperatures of alunite are the lowest, the external fluids are dominant and H₂S/SO₄ratios are estimated to be lower than or close to 1.At this stage of the work, the mineralogical and isotopic criteria do not enable a clear distinction between economic and uneconomic systems. However, some features are common in the economic ore deposits: the presence of zunyite in the deeper part of the system, the relatively high temperatures suggested by the zunyite + pyrophyllite + alunite + diaspore assemblages, the (O, H, S) signature of alunite, which is characteristic of dominant magmatic–hydrothermal acid–sulphate–fluorine systems.     

Land–sea heating contrast in an idealized Asian summer monsoon

Mechanisms determining the tropospheric temperature gradient that is related to the intensity of the Asian summer monsoon are examined in an intermediate atmospheric model coupled with a mixed-layer ocean and a simple land surface model with an idealized Afro–Eurasian continent and no physical topography. These include processes involving in the influence of the Eurasian continent, thermal effects of the Tibetan Plateau and effects of sea surface temperature. The mechanical effect on the large-scale flow induced by the Plateau is not included in this study. The idealized land–sea geometry without topography induces a positive meridional tropospheric temperature gradient thus a weak Asian summer monsoon circulation. Higher prescribed heating and weaker surface albedo over Eurasia and the Tibetan Plateau, which mimic effects of different land surface processes and the thermal effect of the uplift of the Tibetan Plateau, strengthens the meridional temperature gradient, and so as cold tropical SST anomalies. The strengthened meridional temperature gradient enhances the Asian summer monsoon circulation and favors the strong convection. The corresponding monsoon rainbelt extends northward and northeastward and creates variations of the monsoon rainfall anomalies in different subregions. The surface albedo over the Tibetan Plateau has a relatively weak inverse relation with the intensity of the Asian summer monsoon. The longitudinal gradient of ENSO-like SST anomalies induces a more complicated pattern of the tropospheric temperature anomalies. First, the positive (negative) longitudinal gradient induced by the El Niño (La Niña)-like SST anomalies weakens (strengthens) the Walker circulation and the circulation between South Asia and northern Africa and therefore the intensity of the Asian summer monsoon, while the corresponding monsoon rainbelt extends northward (southward). The El Niño (La Niña)-like SST anomalies also induces colder (warmer) tropospheric temperature over Eurasia and warmer (colder) tropospheric temperature over the Indian Ocean. The associated negative (positive) meridional gradient of the tropospheric temperature anomalies is consistent with the existence of the weak (strong) Asian summer monsoon.     

Electoral behaviour behind the gates: partisanship and political participation among Canadian gated community residents

Gated communities have been characterised as representing processes of 'forting up' and 'civic secession', in which their residents use gating as a strategy for withdrawing from political life and from taking collective responsibility for others. The assumption is that the residents of private gated communities should be less likely to participate in political life, and/or be more likely to support political parties on the right who advocate privatisation, reduced government expenditures and lower taxes. If the act of living in a gated community is associated with either greater support for parties and policies on the right of the political spectrum, or limited political participation, then the growth of such forms of privatised communities has potential implications for the future of urban politics and even for national political systems. However, despite surveys that have dealt with social attitudes 'behind the gates', insufficient attention has been paid to the politics of gated community residents. This paper fills this gap through a comparative analysis of electoral behaviour during the 2006 federal election at the level of the polling station. Electoral participation and partisanship in 27 gated communities in three Canadian metropolitan areas is compared against that of non-gated residents. Regression analysis is conducted in order to determine whether gated community residents differ from their non-gated counterparts in the way they vote and their levels of electoral turnout, after controlling for social composition. The potential implications of this research are then discussed.     

A new analytical solution estimating the flexural rigidity in the Central Andes

We present a new 2-D analytical solution of the fourth-order differential equation, which describes the flexure of a thin elastic plate.
The new analytical solution allows the differential equation for an elastic plate to be solved for any irregular shaped topography with a high spatial resolution. We apply the new method to the Central Andes. The flexural rigidity distribution calculated by this technique correlates well with tectonic units and the location of fault zones, for example, the Central Andean Gravity High correlates with the presence of a rigid, high-density body.