Occurrence of naphthalenesulfonates and their condensates with formaldehyde in a landfill leachate and their transport behavior in groundwater of the Upper Rhine Valley, Germany

. Naphthalenesulfonates and their condensation products with formaldehyde are manufactured in the chemical industry for broad application as tanning agents, dispersing agents, and as superplasticizers for concrete. With the disposal of waste they have found their way into the aquatic environment. Five monomeric naphthalenesulfonates and a group of dimeric sulfonated naphthalene-formaldehyde condensates (SNFC) were identified in the leachate and in groundwater observation wells downstream in the plume of the Karlsruhe-West landfill, situated in the Upper Rhine Valley in southwest Germany. For the main monomer of technical SNFC products, 2-naphthalenesulfonate (2-NS), the concentration in the leachate was 170 µg l^–1, which decreased to 9.5 µg l^–1 at a distance of about 300 m from the boundary of the landfill. In the Merdingen tracer test field, the transport of these compounds was studied under more controlled conditions in two tracer experiments with (1) two model compounds, and (2) a technical SNFC product and uranine as a reference tracer. In these experiments, the monomeric naphthalenesulfonates and the SNFC with n=2 behave as conservative tracers. Thus, the findings of the landfill study were supported by these results. Higher molecular SNFC were strongly retarded, which is attributed to adsorption to soil particles. The results of the second tracer experiment suggest a degradation of 2-NS and 2,6-naphthalenedisulfonate (2,6-NDS) after adaptation of the microorganisms in the groundwater aquifer as a consequence of the first tracer experiment.     

Inelastic dynamic analysis of RC bridges accounting for spatial variability of ground motion,site effects and soil–structure interaction phenomena. Part 1: Methodology and analytical tools

During strong ground motion it is expected that extended structures (such as bridges) are subjected to excitation that varies along their longitudinal axis in terms of arrival time, amplitude and frequency content, a fact primarily attributed to the wave passage effect, the loss of coherency and the role of local site conditions. Furthermore, the foundation interacts with the soil and the superstructure, thus significantly affecting the dynamic response of the bridge. A general methodology is therefore set up and implemented into a computer code for deriving sets of appropriately modified time histories and spring–dashpot coefficients at each support of a bridge with account for spatial variability, local site conditions and soil–foundation–superstructure interaction, for the purposes of inelastic dynamic analysis of RC bridges. In order to validate the methodology and code developed, each stage of the proposed procedure is verified using recorded data, finite‐element analyses, alternative computer programs, previous research studies, and closed‐form solutions wherever available. The results establish an adequate degree of confidence in the use of the proposed methodology and code in further parametric analyses and seismic design. Copyright © 2003 John Wiley & Sons, Ltd.     

Inelastic dynamic analysis of RC bridges accounting for spatial variability of ground motion,site effects and soil–structure interaction phenomena. Part 2: Parametric study

The methodology for dealing with spatial variability of ground motion, site effects and soil–structure interaction phenomena in the context of inelastic dynamic analysis of bridge structures, and the associated analytical tools established and validated in a companion paper are used herein for a detailed parametric analysis, aiming to evaluate the importance of the above effects in seismic design. For a total of 20 bridge structures differing in terms of structural type (fundamental period, symmetry, regularity, abutment conditions, pier‐to‐deck connections), dimensions (span and overall length), and ground motion characteristics (earthquake frequency content and direction of excitation), the dynamic response corresponding to nine levels of increasing analysis complexity was calculated and compared with the ‘standard’ case of a fixed base, uniformly excited, elastic structure for which site effects were totally ignored. It is concluded that the dynamic response of RC bridges is indeed strongly affected by the coupling of the above phenomena that may adversely affect displacements and/or action effects under certain circumstances. Evidence is also presented that some bridge types are relatively more sensitive to the above phenomena, hence a more refined analysis approach should be considered in their case. Copyright @ 2003 John Wiley & Sons, Ltd.     

Intercomparison of Stratospheric Chemistry Models under Polar Vortex Conditions

Several stratospheric chemistry modules from box, 2-D or 3-D models, have been intercompared. The intercomparison was focused on the ozone loss and associated reactive species under the conditions found in the cold, wintertime Arctic and Antarctic vortices. Comparisons of both gas phase and heterogeneous chemistry modules show excellent agreement between the models under constrained conditions for photolysis and the microphysics of polar stratospheric clouds. While the mean integral ozone loss ranges from 4–80% for different 30–50 days long air parcel trajectories, the mean scatter of model results around these values is only about ±1.5%. In a case study, where the models employed their standard photolysis and microphysical schemes, the variation around the mean percentage ozone loss increases to about ±7%. This increased scatter of model results is mainly due to the different treatment of the PSC microphysics and heterogeneous chemistry in the models, whereby the most unrealistic assumptions about PSC processes consequently lead to the least representative ozone chemistry. Furthermore, for this case study the model results for the ozone mixing ratios at different altitudes were compared with a measured ozone profile to investigate the extent to which models reproduce the stratospheric ozone losses. It was found that mainly in the height range of strong ozone depletion all models underestimate the ozone loss by about a factor of two. This finding corroborates earlier studies and implies a general deficiency in our understanding of the stratospheric ozone loss chemistry rather than a specific problem related to a particular model simulation.