Stable isotope studies of fluid inclusions in speleothems and their paleoclimatic significance

Fluid inclusions found trapped in speleothems (cave deposited travertine) are interpreted as samples of seepage water from which enclosing calcium carbonate was deposited. The inclusions are assumed to have preserved their D/H ratios since the time of deposition. Initial ¹⁸O/¹⁶O ratios can be inferred from δD because rain- and snow-derived seepage waters fall on the meteoric water line (δD = 8δ¹⁸O + 10). Estimates of temperature of deposition of the carbonate can be calculated from inclusion D/H ratios and δ¹⁸O of enclosing calcite in Pleistocene speleothems. For most speleothems investigated (0–200,000 yr old) δ¹⁸O of calcite appears to have decreased with increasing temperature of deposition indicating that the dominant cause of climate-dependent change in δ¹⁸O of calcite was the change in K_cw, the isotope fractionation equilibrium constant, with temperature; δ¹⁸O of meteoric precipitation generally increased with increasing temperature, but not sufficiently to compensate for the decrease in K_cw.     

Geometric similarity for the temperature field in the unstable atmospheric surface layer

Davenport's geometric similarity is applied to the temperature field in the unstable atmospheric surface layer for displacements in all three orthogonal directions. The decay constants for lateral displacements are over 50 times as large as for vertical displacements. Such large lateral decay constants mean that the measurement of longitudinal constants will be very difficult.Some of the assumptions inherent in geometric similarity were not satisfied. Two regimes, plume scales and larger scales, having different decay constants, were observed. The possibility of a similar scale dependency of the decay constants for the wind field is discussed.     

Hemispheric simulation of the Asian summer monsoon

A three-level, -plane, filtered model is used to simulate the Northern Hemisphere summer monsoon. A time-averaged initial state, devoid of sub-planetary scale waves, is integrated through 30 days on a 5° latitude-longitude grid. Day 25 through day 30 integrations are then repeated on a 2.5° grid. The planetary-scale waves are forced by time-independent, spatially varying diabatic heating. Energy is extracted via internal and surface frictional processes. Orography is excluded to simplify synoptic-scale energy sources.During integration the model energy first increases, but stabilizes near day 10. Subsequent flow patterns closely resemble the hemisphere summer monsoon. Climatological features remain quasi-stationary. At 200 mb high pressure dominates the land area, large-scale troughs are found over the Atlantic and Pacific Oceans, the easterly jet forms south of Asia, and subtropical jets develop in the westerlies. At 800 mb subtropical highs dominate the oceans and the monsoon trough develops over the Asian land mass. The planetary scales at all levels develop a realistic cellular structure from the passage of transient synoptic-scale features, e.g., a baroclinic cyclone track develops near 55°N and westward propagating waves form in the easterlies.Barotropic redistribution of kinetic energy is examined over a low-latitude zonal strip using a Fourier wave-space. In contrast to higher latitudes where the zonal flow and both longer and shorter waves are fed by barotropic energy redistribution from the baroclinically unstable wavelengths, the low-latitude waves have a planetary-scale kinetic energy source. Wave numbers 1 and 2 maintain both the zonal flow and all shorter scales via barotropic transfers. Transient and standing wave processes are examined individually and in combination.Wave energy accumulates at wave numbers 7 and 8 at 200 mb and at wave number 11 in the lower troposphere. The 800-mb waves are thermally indirect and in the mean they give energy to the zonal flow. These characteristics agree with atmospheric observation. The energy source for these waves is the three wave barotropic transfer. The implications of examining barotropic processes in a Fourier wave-space, vice the more common approach of separating the flow into a mean plus a deviation are discussed.     

Stress in the lithosphere: Inferences from steady state flow of rocks

Mechanical data and flow processes from steady state deformation experiments may be used to infer the state of stress in the lithosphere and asthenosphere. Extrapolations of flow equations to a representative geologic strain rate of 10^–14/sec. for halite, marble, quartzite, dolomite, dunite and enstatolite are now warranted because the steady state flow processes in the experiments are identical to those in rocks and because the geotherms are reasonably well established. More direct estimates are obtained from free dislocation densities, subgrain sizes and recrystallized grain sizes all of which are functions only of stress. Using the last of these techniques, we have estimated stress profiles as a function of depth from xenoliths in basalts and kimberlites, whose depths of equilibration were determined by pyroxene techniques, from four different areas of subcontinental and suboceanic upper mantle. The results are similar and indicate stress differences of about 200 to 300 bars at 40 to 50 km, decaying to a few tens of bars at depths betow 100 km. These stresses are reasonable and are in accord with extrapolations of the mechanical data provided that allowance is made for a general increase in strain rate and decrease in viscosity with depth.     

Variations in the content and distribution of n-alkanes in a series of carboniferous vitrinites and sporinites of bituminous rank

n-Alkanes in the soluble organic matter extracted from a series of vitrinite and sporinite concentrates have been analysed by gas chromatography. The macerals were isolated from coals ranging in rank from 77.1% to 86.6% carbon (vitrinite: dry, ash-free), and yields of n-alkanes ranged from 10 to 580 ppm for vitrinites and from 20 to 970 ppm for sporinites. The maximum yields were found at a rank of 85.4% C from vitrinites and 86.6% C from sporinites.Distribution maxima of the n-alkanes, as shown by gas chromatography, range from C₂₇ and C₂₉ at lower ranks to as low as C₁₆ at higher ranks. The distributions also show a progressive decrease in the preference of odd-carbon-number homologues with increasing rank. Virtually smooth distributions were attained in high-volatile bituminous A coals. Quantitative data show that the loss of the odd-carbon-number preference occurred, for the most part, while individual long-chain homologues increased in concentration.There is a progressive increase in the amounts of shorter-chain n-alkanes with increasing rank. It is suggested that sequential processes may have occurred whereby the rate of formation of long-chain n-alkanes in high-volatile bituminous A rank macerals becomes slower than their rate of subsequent fragmentation to shorter chain lengths. Consequently, assuming derivation from the insoluble maceral matrices, the chain-length distributions of parent n-alkyl structures within the insoluble material may retain characteristics pertaining more to the nature of the source organic matter at the time of deposition than do the extractable n-alkane patterns, especially at higher ranks.     

Occurrence of a regular C25 isoprenoid hydrocarbon in tertiary sediments representing a lagoonal-type,saline environment

A regular C₂₅ isoprenoid alkane (2,6,10,14,18-pentamethyleicosane) has been isolated from highly saline Tertiary sediments. The isolation utilized elution chromatography, urea adduction and gas chromatography; identification was based on the mass spectrum. This C₂₅ isoprenoid may represent a biological marker, possibly typical for a lagoonal-type, saline environment.     

Pleistocene climatic change in Southern Australia and its effect on speleothem deposition in some Nullarbor caves

Activity ratios of ²³⁴U/²³⁸U, ²³⁰Th/²³⁴U, and ²³⁰Th/²³²Th have been determined for calcite, gypsum and halite speleothems from caves of the Nullarbor Plain, mostly in the area N and NW of Mundrabilla Station, for the purpose of U-series dating. All calcite speleothems contain adequate amounts of uranium for dating, but some show an excess of ²³⁰Th. Stratigraphic relationships indicate that there were at least three phases of calcium carbonate deposition in the Nullarbor caves. The calcite samples, with one possible exception, have ages in excess of ca. 400000 yrs BP. This suggests that no significant amounts of calcium carbonate deposition have taken place during the last 400ka. At present, active deposition of speleothems is restricted almost entirely to gypsum and halite. The only gypsum speleothem dated was found to have a finite age of ca. 185 ka. Six dates on a small halite speleothem containing insect and arachnid remains indicate that it formed rapidly during Holocene time.     

Irregular Satellites of Jupiter: a study of the capture direction

The irregular satellites of Jupiter are believed to be captured asteroids or planetesimals. In the present work is studied the direction of capture of these objects as a function of their orbital inclination. We performed numerical simulations of the restricted three-body problem, Sun-Jupiter-particle, taking into account the growth of Jupiter. The integration was made backward in time. Initially, the particles have orbits as satellites of Jupiter, which has its present mass. Then, the system evolved with Jupiter losing mass and the satellites escaping from the planet. The reverse of the escape direction corresponds to the capture direction. The results show that the Lagrangian points L1 and L2 mainly guide the direction of capture. Prograde satellites are captured through these two gates with very narrow amplitude angles. In the case of retrograde satellites, these two gates are wider. The capture region increases as the orbital inclination increases. In the case of planar retrograde satellites the directions of capture cover the whole 360° around Jupiter. We also verified that prograde satellites are captured earlier in actual time than retrograde ones. This paper was presented at the Asteriods, Comets and Meteors meeting held at Búzios, Rio de Janeiro, Brazil in August 2005 and could not be included in the special issue related to that conference.     

Streambank dewatering for increased stability

Streambank erosion is often the dominant source of sediment leaving modified watersheds. Mass failure of high, steep banks is one of the most serious forms of streambank erosion. The risk of a given bank experiencing mass failure is a function of bank height, angle, and soil strength, which is governed by soil moisture. Two methods for bank dewatering were tested in adjacent sections of streambank bordering a deeply incised channel in northern Mississippi: a low‐cost pump system and subsurface horizontal drains. Pore water pressures (both positive and negative pressures, or matric suction) were continuously monitored for 2 years at the pumped site, at an adjacent untreated control section, and for 1 year at the site stabilized with horizontal drains. Resulting data were used to calculate a time series of the factor of safety using a computer model. Over the course of two wet seasons, average bank retreats for the control and pumped plots were 0·43 and 0·21 m, respectively. More limited monitoring revealed that the site with passive drains retreated about 0·23 m. At the pumped site pore water pressure was 3–4 kPa lower than at the control site during the most critical periods. Accordingly, computed factors of safety were above the failure threshold at the pumped site, but fell below unity at the control site on 11 occasions over the period of observation. Similarly, the drained site displayed generally lower pore water pressure and higher safety factors except for two events when drains were evidently overwhelmed with the volume of local surface and subsurface flows. These results suggest, but do not prove, that bank dewatering promoted lower rates of bank retreat and higher levels of stability since the three sites had slight differences in soils, geometry and boundary conditions. Initial cost of the dewatering treatments were significantly less than orthodox bank stabilization measures, but operation and maintenance requirements may be greater. Published in 2009 by John Wiley & Sons, Ltd.