Ion Implants as Matrix‐Appropriate Calibrators for Geochemical Ion Probe Analyses

Ion microprobe elemental and isotopic determinations can be precise but difficult to quantify. Error is introduced when the reference material and the sample to be analysed have different compositions. Mitigation of such ‘matrix effects’ is possible using ion implants. If a compositionally homogeneous reference material is available which is ‘matrix‐appropriate’ (i.e., close in major element composition to the sample to be analysed, but having an unknown concentration of the element, E, to be determined) then ion implantation can be used to introduce a known amount of an E isotope, calibrating the E concentration and producing a matrix‐appropriate calibrator. Nominal implant fluences (ions cm^?2) are inaccurate by amounts up to approximately 30%. However, ion implantation gives uniform fluences over large areas; thus, it is possible to ‘co‐implant’ an additional reference material of any bulk composition having known amounts of E, independently calibrating the implant fluence. Isotope ratio measurement standards can be produced by implanting two different isotopes, but permil level precision requires postimplant calibration of the implant isotopic ratio. Examples discussed include (a) standardising Li in melilite; (b) calibrating a ²⁵Mg implant fluence using NIST SRM 617 glass and (c) using Si co‐implanted with ²⁵Mg alongside NIST SRM 617 to produce a calibrated measurement of Mg in Si.     

Episodic intraplate deformation of stable continental margins: evidence from Late Neogene and Quaternary marine terraces,Cape Liptrap,Southeastern Australia

The Waratah Fault is a northeast trending, high angle, reverse fault in the Late Paleozoic Lachlan Fold Belt at Cape Liptrap on the Southeastern Australian Coast. It is susceptible to reactivation in the modern intraplate stress field in Southeast Australia and exhibits Late Pliocene to Late Pleistocene reactivation. Radiocarbon, optically stimulated luminescence (OSL), and cosmogenic radionuclide (CRN) dating of marine terraces on Cape Liptrap are used to constrain rates of displacement across the reactivated Waratah Fault. Six marine terraces, numbered Qt₆–Tt₁ (youngest to oldest), are well developed at Cape Liptrap with altitudes ranging from ～1.5 m to ～170 m amsl, respectively. On the lowest terrace, Qt₆, barnacles in wave-cut notches ～1.5 m amsl, yielded a radiocarbon age of 6090–5880 Cal BP, and reflect the local mid-Holocene sea level highstand. Qt₅ yielded four OSL ages from scattered locations around the cape ranging from ～80 ka to ～130 ka. It formed during the Last Interglacial sea level highstand (MIS 5e) at ～125 ka. Inner edge elevations (approximate paleo high tide line) for Qt₅ occur at distinctly different elevations on opposite sides of the Waratah Fault. Offsets of the inner edges across the fault range from 1.3 m to 5.1 m with displacement rates ranging from 0.01 mm/a to 0.04 mm/a. The most extensive terrace, Tt₄, yielded four Early Pleistocene cosmogenic radionuclide (CRN) ages: two apparent burial ages of 0.858 Ma ± 0.16 Ma and 1.25 Ma ± 0.265 Ma, and two apparent exposure ages of 1.071 Ma ± 0.071 Ma (¹⁰Be) and 0.798 Ma ± 0.066 Ma (²⁶Al). Allowing for muonic production effects from insufficient burial depths, the depth corrected CRN burial ages are 1.8 Ma ± 0.56 Ma and 2.52 Ma ± 0.88 Ma, or Late Pliocene. A Late Pliocene age is our preferred age. Offsets of Tt₄ across the Waratah Fault range from a minimum of ～20 m for terrace surface treads to a maximum of ～70 m for terrace bedrock straths. Calculated displacement rates for Tt₄ range from 0.01 mm/a to 0.04 mm/a (using a Late Pliocene age, ～2 Ma), identical to the rates calculated for the Last Interglacial terrace, Qt₅. This indicates that deformation at Cape Liptrap has been ongoing at similar time-averaged rates at least since the Late Pliocene. The upper terraces in the sequence, Tt₃ (～110 m amsl), Tt₂ (～140 m) and Tt₁ (～180 m) are undated, but most likely correlate to sea level highstands in the Neogene. Terraces Tt1–Tt4 show an increasing northward tilt with age.The Waratah Fault forms a prominent structural boundary in the Lachlan Fold Belt discernible from airborne magnetic and bouger gravity anomalies. Seismicity and deformation are episodic. Episodic movement on the Waratah Fault may be coincident with sea level highstands since the Late Pliocene, possibly from increased loading and elevated pore pressure within the fault zone. This suggests that intervals between major seismic events could be on the order of 100 ka.     

An approach to using snow areal depletion curves inferred from MODIS and its application to land surface modelling in Alaska

Snowcover areal depletion curves inferred from the moderate resolution imaging spectroradiometer (MODIS) are validated and then applied in NASA's catchment‐based land surface model (CLSM) for numerical simulations of hydrometeorological processes in the Kuparuk River basin (KRB) of Alaska. The results demonstrate that the MODIS snowcover fraction f derived from a simple relationship in terms of the normalized difference snow index compares well with Landsat values over the range 20 ≤ f ≤ 100%. For f < 20%, however, MODIS 500 m subpixel data underestimate the amount of snow by up to 13% compared with Landsat at spatial resolutions of 30 m binned to equivalent 500 m pixels. After a bias correction, MODIS snow areal depletion curves during the spring transition period of 2002 for the KRB exhibit similar features to those derived from surface‐based observations. These results are applied in the CLSM subgrid‐scale snow parameterization that includes a deep and a shallow snowcover fraction. Simulations of the evolution of the snowpack and of freshwater discharge rates for the KRB over a period of 11 years are then analysed with the inclusion of this feature. It is shown that persistent snowdrifts on the arctic landscape, associated with a secondary plateau in the snow areal depletion curves, are hydrologically important. An automated method is developed to generate the shallow and deep snowcover fractions from MODIS snow areal depletion curves. This provides the means to apply the CLSM subgrid‐scale snow parameterization in all watersheds subject to seasonal snowcovers. Improved simulations and predictions of the global surface energy and water budgets are expected with the incorporation of the MODIS snow data into the CLSM. Copyright © 2005 John Wiley & Sons, Ltd.     

SUMMARY OF SEVERAL RECENT CHONDRITE FINDS FROM THE TEXAS PANHANDLE

Eleven recent chondrite finds from the Texas Panhandle have been examined and classified according to mineralogical and petrological criteria: five H's, five L's, and one LL chondrite. Five are distinct from nearby finds, while three remain ambiguous and three are related to previously reported chondrites. In addition, data are provided to classify the Muleshoe, Silverton, and Vigo Park chondrites, all of which were previously undescribed in the literature.     

K-coronal enhancements and chromospheric plages

A systematic investigation was made of the K-corona immediately overlying the positions of the brightest and most isolated chromospheric plages during the years 1964–1967. In all cases, the corona was found to be enhanced with peak brightness proportional to the plage area. In the absence of plages, the K-coronal brightness remained at a quiet level which was essentially the same thoughout this part of the solar cycle.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

Coronal holes

Coronal holes are extensive regions of extremely low density in the solar corona within 60° of latitude from the equator. (They are not to be confused with the well-known coronal cavities which surround quiescent prominences beneath helmet streamers.) We have superposed maps of the calculated current-free (potential) coronal magnetic field with maps of the coronal electron density for the period of November 1966, and find that coronal holes are generally characterized by weak and diverging magnetic field lines. The chromosphere underlying the holes is extremely quiet, being free of weak plages and filaments. The existence of coronal holes clearly has important implications for the energy balance in the transition region and the solar wind.The National Center for Atmospheric Research is sponsored by the National Science Foundation.     

An integrated zircon geochronological and geochemical investigation into the Miocene plutonic evolution of the Cyclades, Aegean Sea, Greece: part 2—geochemistry

Zircons from 14 compositionally variable granitic rocks were examined in detail using CL image-guided micro-analysis to unravel the complex magmatic history above the southward retreating Hellenic subduction zone system in the Aegean Sea. Previously published U–Pb ages document an episodic crystallisation history from 17 to 11?Ma, with peraluminous (S-type) granitic rocks systematically older than closely associated metaluminous (I-type) granitic rocks. Zircon O- and Hf isotopic data, combined with trace element compositions, are highly variable within and between individual samples, indicative of open-system behaviour involving mantle-derived melts and evolved supracrustal sources. Pronounced compositional and thermal fluctuations highlight the role of magma mixing and mingling, in accord with field observations, and incremental emplacement of distinct melt batches coupled with variable degrees of crustal assimilation. In the course of partial fusion, more fertile supracrustal sources dominated in the earlier stages of Aegean Miocene magmatism, consistent with systematically older crystallisation ages of peraluminous granitic rocks. Differences between zircon saturation and crystallisation temperatures (deduced from zircon Ti concentrations), along with multimodal crystallisation age spectra for individual plutons, highlight the complex and highly variable physico-compositional and thermal evolution of silicic magma systems. The transfer of heat and juvenile melts from the mantle varied probably in response to episodic rollback of the subducting lithospheric slab, as suggested by punctuated crystallisation age spectra within and among individual granitic plutons.