Storm pulse chemographs of saturation index and carbon dioxide pressure: implications for shifting recharge sources during storm events in the karst aquifer at Fort Campbell,Kentucky/Tennessee,USA

Continuous records of discharge, specific conductance, and temperature were collected through a series of storm pulses on two limestone springs at Fort Campbell, western Kentucky/Tennessee, USA. Water samples, collected at short time intervals across the same storm pulses, were analyzed for calcium, magnesium, bicarbonate, total organic carbon, and pH. Chemographs of calcium, calcite saturation index, and carbon dioxide partial pressure were superimposed on the storm hydrographs. Calcium concentration and specific conductance track together and dip to a minimum either coincident with the peak of the hydrograph or lag slightly behind it. The CO₂ pressure continues to rise on the recession limb of the hydrograph and, as a result, the saturation index decreases on the recession limb of the hydrograph. These results are interpreted as being due to dispersed infiltration through CO₂-rich soils lagging the arrival of quickflow from sinkhole recharge in the transport of storm flow to the springs. Karst spring hydrographs reflect not only the changing mix of base flow and storm flow but also a shift in source of recharge water over the course of the storm.

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Resumen Se ha registrado en continuo la descarga, conductancia específica y temperatura de una serie de episodios de tormenta en dos manantiales en calizas ubicados en Fort Campbell, en el oeste de Kentucky/Tennessee (Estados Unidos de América). Se ha analizado muestras de agua recogidas en breves intervalos de tiempo durante los episodios de tormenta, determinando el calcio, magnesio, bicarbonato, carbono orgánico total y pH. Se ha superpuesto quimiogramas de calcio, índice de saturación en calcita y presión parcial de dióxido de carbono en los hidrogramas de las tormentas. La concentración de calcio y la conductancia específica se comportan de forma similar y presentan un mínimo que coincide también con un pico del hidrograma o que se retrasa ligeramente con respecto a él. La presión de dióxido de carbono sigue aumentando en la rama de recesión del hidrograma y, como consecuencia, disminuye el índice de saturación de la rama de recesión del hidrograma. Se interpreta que estos resultados son debidos a la infiltración dispersa a través de suelos enriquecidos en dióxido de carbono que retrasan el flujo rápido desde la recarga en los sumideros hasta su afloramiento en los manantiales. Los hidrogramas en manantiales kársticos reflejan no sólo la mezcla cambiante del flujo de base y el de tormenta, sino también el cambio en el origen del agua de recarga durante el curso de la tormenta.

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Résumé Lenregistrement en continu du débit, de la conductivité et de la température de leau a été réalisé au cours dune série de crues à deux sources émergeant de calcaires, à Fort Campbell (Kentucky occidental, Tennessee, États-Unis). Des échantillons deau, prélevés à de courts pas de temps lors de ces crues, ont été analysés pour le calcium, le magnésium, les bicarbonates, le carbone organique total et le pH. Les chimiogrammes de calcium, dindice de saturation de la calcite et de la pression partielle en CO₂ ont été superposés aux hydrogrammes de crue. La concentration en calcium et la conductivité de leau se suivent bien et passent par un minimum correspondant au pic de lhydrogramme ou légèrement retardé. La pression partielle en CO₂ continue de croître au cours de la récession de lhydrogramme de même que lindice de saturation de la calcite décroît. Ces résultats sont interprétés comme étant dus à linfiltration dispersée au travers de sols riches en CO₂, décalée par rapport à larrivée de lécoulement rapide provenant de la recharge, à partir dune perte, de lécoulement de crue vers les sources. Les hydrogrammes de sources karstiques ne reflètent pas seulement le mélange variable de lécoulement de base et de lécoulement de crue, mais également un changement dorigine de leau de la recharge au cours de lépisode de crue.

     

THE TROUBLE WITH ANTITHESES: THE CASE OF G. K. GILBERT,GEOGRAPHER AND EDUCATOR

Accounts of the paradigmatic history of twentieth century American geomorphology traditionally describe Gilbert and Davis in anthithetical terms. That characterization partially misrepresents Gilbert, who was a geographer and an educator as well as a geologist and an investigator. Viewing the Gilbertian paradigm as the antithesis of the outmoded Davisian paradigm may have facilitated the acceptance of Gilbert's approach, but extending the dichotomous generalization to other aspects of Gilbert and Davis impedes full appreciation of Gilbert's contributions.     

Selected topics in arctic atmosphere and climate

This paper summarizes the main elements of four IPY projects that examine the Arctic Atmosphere. All four projects focus on present conditions with a view to anticipating possible climate change. All four investigate the Arctic atmosphere, ocean, ice, and land interfacial surfaces. One project uses computer models to simulate the dynamics of the Arctic atmosphere, storms, and their interactions with the ocean and ice interface. Another project uses statistical methods to infer transports of pollutants as simulated in large-scale global atmospheric and oceanic models verifying results with available observations. A third project focuses on measurements of pollutants at the ice-ocean?Catmosphere interface, with reference to model estimates. The fourth project is concerned with multiple, high accuracy measurements at Eureka in the Canadian Archipelago. While these projects are distinctly different, led by different teams and interdisciplinary collaborators, with different technical approaches and methodologies, and differing objectives, they all strive to understand the processes of the Arctic atmosphere and climate, and to lay the basis for projections of future changes. Key findings include: ? Decreased sea ice leads to more intense storms, higher winds, reduced surface albedo, increased surface air temperature, and enhanced vertical mixing in the upper ocean. ? Arctic warming may affect toxic chemicals by remobilizing persistent organic pollutants and augmenting mercury deposition/retention in the environment. ? Changes in sea ice can dramatically change processes in and at the ice surface related to ozone, mercury and bromine oxide and related chemical/physical properties. ? Structure and properties of the Arctic atmospheric??troposphere to stratosphere??and tracking of transport of pollution and smoke plumes from mid-latitudes to the poles.     

Climate and vegetation history from a 14,000-year peatland record, Kenai Peninsula, Alaska

Analysis of pollen, spores, macrofossils, and lithology of an AMS ¹⁴C-dated core from a subarctic fen on the Kenai Peninsula, Alaska reveals changes in vegetation and climate beginning 14,200 cal yr BP. Betula expansion and contraction of herb tundra vegetation characterize the Younger Dryas on the Kenai, suggesting increased winter snowfall concurrent with cool, sunny summers. Remarkable Polypodiaceae (fern) abundance between 11,500 and 8500 cal yr BP implies a significant change in climate. Enhanced peat preservation and the occurrence of wet meadow species suggest high moisture from 11,500 to 10,700 cal yr BP, in contrast to drier conditions in southeastern Alaska; this pattern may indicate an intensification and repositioning of the Aleutian Low (AL). Drier conditions on the Kenai Peninsula from 10,700 to 8500 cal yr BP may signify a weaker AL, but elevated fern abundance may have been sustained by high seasonality with substantial snowfall and enhanced glacial melt. Decreased insolation-induced seasonality resulted in climatic cooling after 8500 cal yr BP, with increased humidity from 8000 to 5000 cal yr BP. A dry interval punctuated by volcanic activity occurred between 5000 and 3500 cal yr BP, followed by cool, moist climate, coincident with Neoglaciation. Tsuga mertensiana expanded after ~ 1500 cal yr BP in response to the shift to cooler conditions.     

Measurement of the lunar neutron density profile

Anin situ measurement of the lunar neutron density from 20 to 400 g cm^?2 depth below the lunar surface was made by the Apollo 17 Lunar Neutron Probe Experiment (LNPE) using particle tracks produced by the¹⁰B (n,α)⁷Li reaction. Both the absolute magnitude and the depth profile of the neutron density are in good agreement with theoretical calculations by Lingenfelter, Canfield, and Hampel. However, relatively small deviations between experiment and theory in the effect of Cd absorption on the neutron density and in the relative¹⁴⁹Sm to¹⁵⁷Gd capture rates reported previously (Russet al., 1972) imply that the true lunar¹⁵⁷Gd capture rate is about one half of that calculated theoretically.     

Manganese(III) binding to a pyoverdine siderophore produced by a manganese(II)-oxidizing bacterium

The possible roles of siderophores (high affinity chelators of iron(III)) in the biogeochemistry of manganese remain unknown. Here we investigate the interaction of Mn(III) with a pyoverdine-type siderophore (PVD_MnB1) produced by the model Mn(II)-oxidizing bacterium Pseudomonas putida strain MnB1. PVD_MnB1 confirmed typical pyoverdine behavior with respect to: (a) its absorption spectrum at 350-600 nm, both in the absence and presence of Fe(III), (b) the quenching of its fluorescence by Fe(III), (c) the formation of a 1:1 complex with Fe(III), and (d) the thermodynamic stability constant of its Fe(III) complex. The Mn(III) complex of PVD_MnB1 had a 1:1 Mn:pvd molar ratio, showed fluorescence quenching, and exhibited a light absorption spectrum (A_max = 408-410 nm) different from that of either PVD_MnB1-Fe(III) or uncomplexed PVD_MnB1. Mn(III) competed strongly with Fe(III) for binding by PVD_MnB1 in culture filtrates (pH 8, 4°C). Equilibration with citrate, a metal-binding ligand, did not detectably release Mn from its PVD_MnB1 complex at a citrate/PVD_MnB1 molar ratio of 830 (pH 8, 4°C), whereas pyrophosphate under the same conditions removed 55% of the Mn from its PVD_MnB1 complex. Most of the PVD_MnB1-complexed Mn was released by reaction with ascorbate, a reducing agent, or with EDTA, a ligand that is also oxidized by Mn(III). Data on the competition for binding to PVD_MnB1 by Fe(III) vs. Mn(III) were used to determine a thermodynamic stability constant (nominally at 4°C) for the neutral species MnHPVD_MnB1 (log K = 47.5 ± 0.5, infinite dilution reference state). This value was larger than that determined for FeHPVD_MnB1 (log K = 44.6 ± 0.5). This result has important implications for the metabolism, solubility, speciation, and redox cycling of manganese, as well as for the biologic uptake of iron.     

Economic restructuring, housing policy and Maori housing in Northland, New Zealand

Since 1984 the New Zealand economy has experienced a significant phase of economic restructuring which has had a differential impact on various sectors, regions and social groups within the economy. This paper examines the extent to which economic change has affected the marginalized status of Maori households in the predominantly rural region of Northland. The social implications of economic restructuring are assessed by focusing on the housing circumstances of this indigenous people. Using a newly developed Maori housing database, we argue that relatively progressive housing policies, developed in the 1980s, have failed to address the housing problems of Maori and that the recent reliance on ‘market’ mechanisms to meet housing needs is likely to exacerbate problems of housing access and cost.     

The shoreline preservation index as a relative-age dating tool for late pleistocene shorelines: An example from the bonneville basin,U.S.A.

This paper evaluates the utility of the shoreline preservation index (s.p.i.) for estimating the age of late Pleistocene palaeolake shorelines, the relative influence of various factors on shoreline preservation, and whether shoreline preservation varies significantly with shoreline aspect. Sampled shorelines from the 3300 km² study area, which includes the Skull, Tule and Puddle Valley portions of the Lake Bonneville basin, range in age from approximately 26 to 12 ka. Their total s.p.i. values range from 23 to 69 per cent, average 46 per cent, and do not vary significantly with shoreline aspect. The data from Skull and Tule Valleys, where studied shorelines are of known age, are analysed first in order to determine if there are statistically significant associations between variables representing shoreline preservation, age, degree of geomorphic development and duration of subaerial exposure. Pairwise correlation is then repeated using observations from all three valleys in order to determine how data from the Puddle Valley shorelines, whose hypothesized ages are not supported by radiocarbon analyses, affect the results. Results show that s.p.i. is useful as a relative-age dating tool, that the postulated ages of the Puddle Valley shorelines are ordinally correct, and that geomorphic development is not an important influence on the preservation of these late Pleistocene shorelines. The relative importance of shoreline age and the relative unimportance of duration of subaerial exposure with respect to shoreline preservation suggest that subaqueous processes play a more substantial role in shoreline obliteration than is generally suggested.