Barbados

In the words of the noted Antillean geologist C.T. Trechmann (1937 , p.337), 'Barbados, 21 miles long, 14 miles wide, rising to 1101 feet, is probably the most considerable Pleistocene non-volcanic bleb on the face of our planet, at least in the Antillean region.' The island's geology shows a stark contrast between the allochthonous siliciclastic succession of an accretionary prism, deposited in water depths measurable in kilometres, and the autochthonous Pleistocene raised reef cap exposed over 90 per cent of Barbados.     

Dissociative recombination contributions to I(5577) and I(6300) [OI] and NmF2 enhancements resulting from moderate proton PCA events

We investigate the dissociative recombination contribution to I(5577) and I(6300) of [OI] as a function of low energy cutoff for two measured solar proton spectra. The volume ionization rate profiles used in the calculation are obtained using a detailed atomic cross section approach in the continuous slowing down approximation. The ratio of the dissociative recombination contribution to the direct impact contribution for both the 5577 Å and 6300 Å [OI] emissions is found to be dependent upon the low energy cutoff. This ratio has a nominal value of ～2.0 for the 5577 Å [OI] emission and ～0.25 for the 6300 Å [OI] emission. The I(5577)/I(3914) and I(6300)/I(3914) ratios including the direct and dissociative recombination contributions are strongly dependent upon the low energy cutoff of the spectrum. We have also investigated F-layer enhancements resulting from the low energy spectrum component. For the Mizera et al. (1972) spectrum with a low energy cutoff of 12.4 keV, we find an N_mF2 of ～4.5 × 10³ electrons/cm³ or about 10 per cent of the ionization required to maintain the dip pole at a value of 5 × 10⁴ electrons/cm³. Extension of the cutoff to 1 keV results in ～1 × 10⁴ electrons/cm³, or about 20 per cent of the required maintenance ionization.     

Determination of HBCD, PBDEs and MeO-BDEs in California sea lions (Zalophus californianus) stranded between 1993 and 2003

Blubber samples from male California sea lions (Zalphophus californianus) stranded between 1993 and 2003 were analyzed for 27 polybrominated diphenyl ether (PBDE) congeners, three isomers of hexabromocyclododecane (HBCD) and 14 methoxylated polybrominated diphenyl ether (MeO-BDE) congeners. Total PBDEs ranged from 450 ng/g to 4740 ng/g wet mass and total HBCD ranged from < 0.3 ng/g to 12 ng/g wet mass. The concentration of HBCD increased from 0.7 ng/g to12.0 ng/g wet mass in sea lion blubber between 1993 and 2003. However, no significant temporal trend was observed for any of the other brominated compounds over this 10 year period. Only one of the 14 MeO-BDE congeners was detected in the blubber samples, 6-methoxy-2,2',4,4'-tetrabromodiphenyl ether (6-MeO-BDE 47), and concentrations ranged from < 0.2 ng/g to 12 ng/g wet mass. A bromo-, chloro-heterocyclic compound, 1,1'-dimethyl-tetrabromo-dichloro-2,2'-bipyrrole (DBP-Br4Cl2), previously reported in marine species along the Pacific coast, was also identified in the sea lion blubber. DBP-Br4Cl2 ranged from 44 ng/g wet mass to 660 ng/g wet mass and was present at concentrations rivaling the dominant PBDE congener, BDE 47 (2,2',4,4'-tetrabromodiphenyl ether). Concentrations of DBP-Br4Cl2 were positively correlated with 6-MeO-BDE 47 (r = 0.7; p < 0.05). Both of these compounds have been identified in marine algae and sponges, and studies suggest they are both produced from natural sources. This study demonstrates that brominated compounds from both anthropogenic and biogenic sources can accumulate to similar levels in marine mammals. In addition, HBCD concentrations appear to be increasing in California sea lion populations, whereas PBDE concentrations, between 1993 and 2003, were highly variable.     

Notes on Mississippian echinoderms from Hurdlow,Derbyshire, central England

The fossil echinoderms of the Lower Carboniferous (Mississippian) of Derbyshire remain understudied, principally due to the nature of the preservation rather than any lack of biodiversity. Echinoids and crinoids are described in float blocks of limestone from near Hurdlow, Derbyshire, which have been etched naturally after many years of being washed by weakly acidic rain. Surface detail is variable, commonly poor, but rare specimens retain enough features for tentative identification. Two species of echinoids are identified from rare disarticulated plates, namely Melonechinus? sp. (ambulacral plates) and archaeocidarid sp. (interambulacral plate); more and superior material will be necessary to confirm this division. Crinoids include a cladid brachial ossicle sp. with a distinctive sculpture; a columnal of a monobathrid camerate platycrinitid sp.; Annulocolumnus (col.) sp. cf. A. annulus Donovan, a columnal morphotaxon with an unusually broad axial canal; and Cyclocyclicus (col.) spp. This is the tenth echinoid site to be recognized from the Mississippian of the White Peak. Examination of etched float blocks provides a further method of investigation of the echinoderm fauna of this and other limestone areas.