Extraction and recovery of precious metals from electronic waste printed circuit boards by bioleaching acidophilic fungi

Printed circuit boards contain precious metals. They are produced in large volumes, rendering them an important component of the electronic waste. In view of the heterogeneity of the metals present, reprocessing of electronic waste is a heinous task. The present study focused on leaching of valuable metals from electronic waste printed circuit boards using Aspergillus niger DDNS1. The adaptation phases began at 0.1, 0.5 and 1.0% of fine powder of printed circuit boards with 10% inoculum and were optimized with three effective factors, viz. initial pH, particle size and pulp density, to achieve the maximum simultaneous recovery of the valuable metals. The interactions of these metals were also deciphered using scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, Fourier transform infrared spectrum and atomic absorption spectroscopy. The results indicated that extraction of the precious metals was accomplished mainly through the unique organic acids originating from A. niger DDNS1. The initial pH played an important role in the extraction of the precious metals and the metals precipitate formation. The leaching rate of the metals was generally higher at low powder dosage of printed circuit boards. The toxicity of the printed circuit boards had little effect on two-step bioleaching at the pulp density of 0.1% compared to one-step bioleaching. The two-step bioleaching process was followed under organic acid-forming conditions for the maximum mobilization of metals. Thus, the precious metals from printed circuit boards could be mobilized through fungal bioleaching which promises an important industrial application in recycling of electronic wastes.     

Rare earth elements in the clay fraction of coaliferous sediments of the Arkagalinskoe (Magadan district) and Dolinskoe (Sakhalin Island) coalfields

The study of REE distribution in the clay fraction of sedimentary rocks from two coalfields made it possible to distinguish several types of REE distribution, which correlate with their mineral composition. It is shown that the REE fractionation was related to the mineral reconstruction of the primary clay fraction and some detrital minerals in the course of postsedimentary transformations of rocks during diagenesis, early catagenesis, and beginning of late catagenesis. These transformations were governed by several factors, such as the composition of sediments; hydrochemical features of accumulation environment; the chemical composition, dynamics, and feeding sources of pore solutions; the porosity and permeability of sediments and rocks; and the content of organic matter and its reaction ability.     

A 2D finite volume model for bebris flow and its application to events occurred in the Eastern Pyrenees

FLATModel is a 2D finite volume code that contains several original approaches to improve debris-flow simulation. Firstly, FLATModel incorporates a ＂stop-and-go＂ technique in each cell to allow continuous collapses and remobilizations of the debris-flow mass. Secondly, flow velocity and consequently yield stress is directly associated with the type of rheology to improve boundary accuracy. Thirdly, a simple approach for entrainment is also included in the model to analyse the effect of basal erosion of debris flows. FLATMODEL was tested at several events that occurred in the Eastern Pyrenees and simulation results indicated that the model can represent rather well the different characteristics observed in the field.     

Rock-weathering rates as functions of time

The scarcity of documented numerical relations between rock weathering and time has led to a common assumption that rates of weathering are linear. This assumption has been strengthened by studies that have calculated long-term average rates. However, little theoretical or empirical evidence exists to support linear rates for most chemical-weathering processes, with the exception of congruent dissolution processes. The few previous studies of rock-weathering rates that contain quantitative documentation of the relation between chemical weathering and time suggest that the rates of most weathering processes decrease with time. Recent studies of weathering rinds on basaltic and andesitic stones in glacial deposits in the western United States also clearly demonstrate that rock-weathering processes slow with time. Some weathering processes appear to conform to exponential functions of time, such as the square-root time function for hydration of volcanic glass, which conforms to the theoretical predictions of diffusion kinetics. However, weathering of mineralogically heterogeneous rocks involves complex physical and chemical processes that generally can be expressed only empirically, commonly by way of logarithmic time functions. Incongruent dissolution and other weathering processes produce residues, which are commonly used as measures of weathering. These residues appear to slow movement of water to unaltered material and impede chemical transport away from it. If weathering residues impede weathering processes then rates of weathering and rates of residue production are inversely proportional to some function of the residue thickness. This results in simple mathematical analogs for weathering that imply nonlinear time functions. The rate of weathering becomes constant only when an equilibrium thickness of the residue is reached. Because weathering residues are relatively stable chemically, and because physical removal of residues below the ground surface is slight, many weathering features require considerable time to reach constant rates of change. For weathering rinds on volcanic stones in the western United States, this time is at least 0.5 my.     

Changes in temperature and precipitation extremes in the CMIP5 ensemble

Twenty-year temperature and precipitation extremes and their projected future changes are evaluated in an ensemble of climate models participating in the Coupled Model Intercomparison Project Phase 5 (CMIP5), updating a similar study based on the CMIP3 ensemble. The projected changes are documented for three radiative forcing scenarios. The performance of the CMIP5 models in simulating 20-year temperature and precipitation extremes is comparable to that of the CMIP3 ensemble. The models simulate late 20th century warm extremes reasonably well, compared to estimates from reanalyses. The model discrepancies in simulating cold extremes are generally larger than those for warm extremes. Simulated late 20th century precipitation extremes are plausible in the extratropics but uncertainty in extreme precipitation in the tropics and subtropics remains very large, both in the models and the observationally-constrained datasets. Consistent with CMIP3 results, CMIP5 cold extremes generally warm faster than warm extremes, mainly in regions where snow and sea-ice retreat with global warming. There are tropical and subtropical regions where warming rates of warm extremes exceed those of cold extremes. Relative changes in the intensity of precipitation extremes generally exceed relative changes in annual mean precipitation. The corresponding waiting times for late 20th century extreme precipitation events are reduced almost everywhere, except for a few subtropical regions. The CMIP5 planetary sensitivity in extreme precipitation is about 6 %/°C, with generally lower values over extratropical land.     

Petrology and geochemistry of Northwest Africa 5480 diogenite and evidence for a basin‐forming event on Vesta

We performed a petrological and geochemical study of an olivine diogenite, Northwest Africa (NWA) 5480. NWA 5480 is a crystalline stone, but shows a heterogeneous texture. Olivine aggregates and grains of olivine and chromite display resorption textures set in a crystalline pyroxene matrix. Large olivine aggregates are penetrated by pyroxene matrix. Flow textures are observed near olivine aggregates. Olivine, chromite, and pyroxene show minor chemical zoning, implying relatively rapid cooling. NWA 5480 contains a significant amount of platinum group elements with chondritic relative proportions. All this evidence supports that NWA 5480 is an impact‐melt breccia from a target composed of olivine and pyroxene‐rich lithologies. Such impact melt would have formed by melting crustal materials, possibly during one of the impacts that formed the South Pole basins on Vesta.     

The born-again (very late thermal pulse) scenario revisited: the mass of the remnants and implications for V4334 Sgr

We present 1D numerical simulations of the very late thermal pulse (VLTP) scenario for a wide range of remnant masses. We show that by taking into account the different possible remnant masses, the observed evolution of V4334 Sgr (a.k.a. Sakurai's object) can be reproduced within the standard 1D mixing length theory (MLT) stellar evolutionary models without the inclusion of any ad hoc reduced mixing efficiency. Our simulations hint at a consistent picture with present observations of V4334 Sgr. From energetics, and within the standard MLT approach, we show that low-mass remnants  ( M ≲ 0.6 M_⊙)  are expected to behave markedly differently from higher mass remnants  ( M ≳ 0.6 M_⊙)  in the sense that the latter remnants are not expected to expand significantly as a result of the violent H-burning that takes place during the VLTP. We also assess the discrepancy in the born-again times obtained by different authors by comparing the energy that can be liberated by H-burning during the VLTP event.     

On the eigenvalues of kinematic α-effect dynamos

The kinematic α-effect dynamo problem is investigated in the case of an exterior perfect conductor. It is shown that certain approximate symmetries discovered in the numerical analysis of ROBERTS (1972) are exact for this case. As an illustration, an exact solution is given in a cylindrical geometry, where the equations can be written in terms of one variable. The implications for the earth's dynamo are discussed.     

Radio spectra of some markarian galaxies

Radio spectra of 16 Markarian galaxies are studied between 2.7 and 15.5 GHz. The Seyfert-type galaxies have power-law spectra with an average spectral index of -0.82, except for MRK 348, which is an active galaxy with a complex spectrum. The galaxies with featureless optical spectra have rather flat radio spectra, similar to BL Lac-type objects.     

A new semi-quantitative Surface-Enhanced Raman Spectroscopy (SERS) method for detection of maleimide (2,5-pyrroledione) with potential application to astrobiology

Nitrogen-containing heterocyclic compounds are fundamental biochemical components of all life on Earth and, presumably, life elsewhere in our solar system. Dete...