Decadal‐Scale Changes of the Ödenwinkelkees,Central Austria,Suggest Increasing Control of Topography and Evolution Towards Steady State

Small mountain glaciers have short mass balance response times to climate change and are consequently very important for short‐term contributions to sea level. However, a distinct research and knowledge gap exists between (1) wider regional studies that produce overview patterns and trends in glacier changes, and (2) in situ local scale studies that emphasise spatial heterogeneity and complexity in glacier responses to climate. This study of a small glacier in central Austria presents a spatiotemporally detailed analysis of changes in glacier geometry and changes in glaciological behaviour. It integrates geomorphological surveys, historical maps, aerial photographs, airborne LiDAR data, ground‐based differential global positioning surveys and Ground Penetrating Radar surveys to produce three‐dimensional glacier geometry at 13 time increments spanning from 1850 to 2013. Glacier length, area and volume parameters all generally showed reductions with time. The glacier equilibrium line altitude increased by 90 m between 1850 and 2008. Calculations of the mean bed shear stress rapidly approaching less than 100 kPA, of the volume–area ratio fast approaching 1.458, and comparison of the geometric reconstructions with a 1D theoretical model could together be interpreted to suggest evolution of the glacier geometry towards steady state. If the present linear trend in declining ice volume continues, then the Ödenwinkelkees will disappear by the year 2040, but we conceptualise that non‐linear effects of bed overdeepenings on ice dynamics, of supraglacial debris cover on the surface energy balance, and of local topographically driven controls, namely wind‐redistributed snow deposition, avalanching and solar shading, will become proportionally more important factors in the glacier net balance.     

Strength and stiffness variation of frozen soilsaccording to confinement during freezing

When water between soil particles is frozen, the strength and stiffness behavior of soils significantly change. Thus, numerous experimental studies in the laboratory have been carried out to characterize the strength and stiffness of frozen soils. The goals of this study are to evaluate the strength characteristics of frozen soils, which underwent confinement in freezing and shearing stages, and to estimate the stiffness variation by shear wave velocity during shear phase. The specimens are prepared in a brass cell by mixing sand and silt with 10% degree of saturation at a relative density of 60%. The applied normal stresses as confining stresses are 5, 10, 25 and 50 k Pa. When the temperature of the specimens is lowered up to-5 °C, direct shear tests are carried out. Furthermore, shear waves are continuously measured through bender elements during shearing stage for the investigation of stiffness change. Test results show that shear strength and stiffness are significantly affected by the confining stress in freezing and shearing phases. This study suggests that the strength and stiffness of frozen soils may be dependent on the confining stresses applied during freezing and shearing.     

The Northwest Africa (NWA) 5790 meteorite: A mesostasis‐rich nakhlite with little or no Martian aqueous alteration

Northwest Africa (NWA) 5790 is the most recently discovered member of the nakhlite group. Its mineralogy differs from the other nakhlites with a high abundance mesostasis (38.1 ± 3.6 vol%) and scarcity of olivine (4.0 ± 2.2 vol%). Furthermore, zoning of augite phenocrysts, and other petrographic and chemical characteristics suggest that NWA 5790 samples the chilled margin of its parent lava flow/sill. NWA 5790 contains calcite and rare clay minerals that are evidence for its exposure to liquid water. The calcite forms a cement to coatings of dust on the outer surface of the find and extends into the interior of the meteorite within veins. The presence of microbial remains within the coating confirms that the dust and its carbonate cement are terrestrial in origin, consistent with the carbon and oxygen isotope composition of the calcite. The clay minerals are finely crystalline and comprise ~0.003 vol% of the meteorite. δD values of the clay minerals range from ?212 ± 109‰ to ?96 ± 132‰, and cannot be used to distinguish between a terrestrial or Martian origin. As petrographic results are also not definitive, we conclude that secondary minerals produced by Martian groundwaters are at best very rare within NWA 5790. The meteorite has therefore sampled a region of the lava flow/sill with little or no exposure to the aqueous solutions that altered other nakhlites. This isolation could relate to the scarcity of olivine in NWA 5790 because dissolution of olivine in other nakhlites by Martian groundwaters enhanced their porosity and permeability, and provided solutes for secondary minerals.     

Improvement of daily precipitation estimations using PRISM with inverse-distance weighting

Improved daily precipitation estimations were attempted using the parameter-elevation regressions on a parameter-elevation regression on independent slopes model (PRISM) with inverse-distance weighting (IDW) and a precipitation-masking algorithm for precipitation areas. The PRISM (PRISM_ORG) suffers two overestimation problems when the daily precipitation is estimated: overestimation of the precipitation intensity in mountainous regions and overestimation of the local precipitation areas. In order to solve the problem of overestimating the precipitation intensity, we used the IDW technique that employs the same input stations as those used in the PRISM regression (PRISM_IDW). A precipitation-masking algorithm that selectively masks the precipitation estimation grid points was additionally applied to the PRISM_IDW results (PRISM_MSK). For 6 months from March to August 2012, daily precipitation data were produced in a horizontal resolution of 1 km based on the above two experiments and PRISM_ORG. Afterwards, each experiment was evaluated for improvements. The monthly root mean squared errors (RMSEs) of PRISM_IDW and PRISM_MSK were reduced by 0.83 mm/day and 0.86 mm/day, respectively, compared to PRISM_ORG.     

Photochemical characteristics of high and low ozone episodes observed in the Taehwa Forest observatory (TFO) in June 2011 near Seoul South Korea

We present a comprehensive discussion on what cause high ozone episodes at a suburban photochemical observation site of the Seoul Metropolitan Area (population ～23 million). The observational site, Taehwa Research Forest (TRF), is situated ～30 km from the center of Seoul. In June 2011, we observed two very distinctive ozone periods-high ozone (peak up to 120 ppbv) and low ozone (peak up to 60 ppbv) in the mid and early month, respectively. The trace gas measurement dataset, especially CO and NO _X clearly indicate that less anthropogenic influences during the high ozone period. Volatile organic compound (VOC) measurement results show that at the observational site, biogenic VOCs (mostly isoprene) contribute most of chemical reactivity towards OH, although toluene from anthropogenic activities was observed in higher concentrations. Back-trajectory analysis indicates that air-masses from the forest part of Korea Peninsula were dominant influences during the high ozone episode event. On the other hand, Aged air masses from China were the dominant influence during the low ozone episode event. Model calculations conducted using the University of Washington Chemical Mechanism (UWCM) box model, also consistently show that BVOC, especially isoprene photochemistry, can be the significantly contribution to local ozone formation in the given photochemical environments of TRF. These research results strongly suggest that ozone control strategy in the Eastern Asian megacities, mostly situated in surrounding forest areas should be based on the comprehensive scientific understanding in BVOC photochemistry and interplays between anthropogenic and biogenic interactions.