Geochemical characteristics of the Río Verde Complex,Central Hispaniola: Implications for the paleotectonic reconstruction of the Lower Cretaceous Caribbean island-arc

New geochronological, trace element and Sr–Nd isotope data for metabasalts, dolerites and amphibolites from the Río Verde Complex, Central Hispaniola, are integrated with existing geochemical data for mafic volcanic rocks and metamorphic derivatives from the Los Ranchos, Amina and Maimón Formations, giving new insights into magma petrogenesis and paleotectonic reconstruction of the Lower Cretaceous Caribbean island-arc–back arc system. U–Pb and ⁴⁰Ar/³⁹Ar age data show that the Río Verde Complex protoliths were in part coeval with volcanic rocks of the Los Ranchos Formation (Upper Aptian to Lower Albian). The geochemical data establish the existence of gradients in trace element parameters (Nb/Yb, Th/Yb, Zr/Yb, Zr/Ba, and normalized Ti, Sm, Y and Yb abundances) and Nd isotope compositions from throughout Hispaniola, which reflect differences in the degree of mantle wedge depletion and contributions from the subducting slab. The Río Verde Complex mafic rocks and some mafic sills and dykes intruding in the Loma Caribe Peridotite, have a transitional IAT to N-MORB geochemistry and a weak subduction-related signature, and are interpreted to form in a rifted arc or evolving back-arc basin setting. The Los Ranchos, Amina and Maimón Formations volcanic rocks have arc-like characteristics and represent magmatism in the volcanic front. Trace element and Nd isotope modeling reproduce observed data trends from arc to back-arc and suggest that the variations in several geochemical parameters observed in a SW direction across the Caribbean subduction system can be explained from the progressively lower subduction flux into a progressively less depleted mantle source. The low Nb contents and high (ε_Nd)_i values in both arc and back-arc mafic rocks imply, however, the absence of a significant Lower Cretaceous plume enriched component. In order to explain these observations, a model of proto-Caribbean oceanic lithosphere subducting to the SW at least in the 120–110 Ma interval, is proposed to cause the observed magmatic variations in the Lower Cretaceous Caribbean island-arc–back-arc system. In this context, arc rifting and initial sea-floor spreading to form the Río Verde Complex protoliths occurred in the back-arc setting of this primitive island-arc, built on the NE edge of the Caribbean plate.     

Relationships between field-aligned currents and convection observed by EISCAT and implications concerning the mechanism that produces region-2 currents: Statistical study

Fluid theories explain the origin of region-2 field-aligned currents as the closure of the ring current, driven itself by the azimuthal pressure gradients generated in the magnetospheric ring plasma by the sunward convection. Although the structure of pressure gradients appears experimentally complex, observations confirm that a close connection exists between the region-2 field-aligned currents and the ring current. The fluid linear theory of the adiabatic transport by convection of the ring plasma gives a first estimate of this process, and leads ultimately to phase quadrature (in terms of magnetic local time) between the region-2 field-aligned currents and the convection potential. When significant non-adiabatic processes are taken into account, such as precipitations at auroral latitudes, the theoretical phase difference rotates toward opposition. We determine experimentally the phase relationship between the region-2 field-aligned currents and the convection potential from recent statistics, depending on the magnetic activity index K_p, and performed from the EISCAT data base. For geometrical reasons of sufficient probing of region 2, it is only computed in the case of a moderate magnetic activity corresponding to 2\leqK_p<4. Region-2 field-aligned currents are found to be in phase opposition with the convection electrostatic potential at auroral latitudes. This confirms the importance of non adiabatic processes, especially ion losses, in the generation of region-2 field-aligned currents, as theoretically suggested.     

Contribution of the 3-D visualization of acoustic borehole signals (full waveforms) to a quick formation evaluation

Logging and continuous coring are carried out when drilling and looking for materials such as gravels, sand, and clay or in order to evaluate the fracture state of a deep site intended for waste storage. However, in some cases of non-consolidated formations, the results may be disappointing because of the borehole conditions. Full waveforms, as seismic signals, provide information about physical parameters of the grounds crossed by the sonic tool, and this information is almost independent of borehole conditions. Traditional displays in variable area or density show the wave arrival times and the frequencies with depth; for variable density, a color scale permits to see clustered instantaneous phases.In order to determine precisely and simultaneously the three signal parameters (arrival time, frequency, and amplitude) in the depth-propagation time domain, a 3-D visualization software has been developed. The “view” parameters, which give a nice display of the 3-D→2-D projection of the signals in a parallel perspectives relative to depth, are estimated on the monitor screen in an interactive way. A larger size version of the software is available for displaying in detail the acoustic signals for the whole borehole. However, this program needs a large computer, and the maximum size of the drawing depends on the computer memory available for use.The comparison between traditional and 3-D displays shows that without previous preprocessing, the 3-D visualization (1) shows the very small and continuous variations of amplitude (and, therefore, of attenuation) with depth better; and (2) can bring out interferences and “energetic peaks” by simply changing the “view” parameters. As the attenuation of the different waves is directly determined, fresh zones can be distinguished immediately from fracture zones and hard ground from soft ground. The geometry of major fracturing can be deduced directly from graphical representation; i.e. open or closed, and horizontal or oblique fractures. The calculation of their “vertical thickness” is straightfoward. Microfractures, induced by drilling or otherwise, are not detected, but microfractured rocks are detectable.     

Characterization of water in synthetic rhyolitic glasses and natural melt inclusions by Raman spectroscopy

Raman spectroscopy was used to analyze quantitatively water in silicate glasses and melt inclusions and to monitor H₂O–OH speciation. Calibration is based on synthetic glasses with various water contents (0.02–7.67% H₂O); water determination and OH–H₂O differentiation on the area of the Si–O broad band at 468 cm^–1 and the asymmetric O–H band at 3,550 cm^–1. Each Raman spectrum has been decomposed into four Gaussian + Lorentzian components centered at 3,330, 3,458, 3,560, and 3,626 cm^–1 using the Levenberg–Marquardt algorithm. These components are interpreted to be two different types of H₂O molecule sites. The influence of the temperature on the loss of water is more important for molecular water than for the hydroxyl groups. The H₂O–OH partition confirms the typical evolution of water speciation in rhyolitic glasses as a function of the bulk water content. Method limitations have been studied for the application to natural melt inclusions.Editorial responsibility: T.L Grove     

Mössbauer spectroscopic determination of Fe<Superscript>3+</Superscript>/Fe<Superscript>2+</Superscript> in synthetic basaltic glass: a test of empirical<Emphasis Type="Italic"> f</Emphasis>O<Subscript>2</Subscript> equations under superliquidus and subliquidus conditions

One of the most widely used methods to estimate magmatic oxygen fugacity involves the use of empirical equations relating fO₂ to the iron redox state in quenched silicate liquids; however none of the equations have been calibrated experimentally under subliquidus conditions at temperatures and oxygen fugacities that are relevant to natural magmas. To address this problem, we tested two empirical relationships [Eq. (1) in Kress and Carmichael 1991; Eq. (6) in Nikolaev et al. 1996] on synthetic glasses synthesized from a ferrobasaltic and a transitional alkali-basaltic composition at sub- to superliquidus temperatures (1,132–1,222°C) and controlled oxygen fugacities (FMQ=–2 to +1.4). Fe³⁺/Fe was determined using conventional and milliprobe Mössbauer spectroscopy, and verified using wet chemical analysis on selected samples. For the ferrobasaltic bulk composition SC1-P, both empirical models reproduce the Fe³⁺/Fe ratio of the quenched liquids generally within 0.03 for sub- as well as superliquidus temperatures, although agreement is worse at higher oxygen fugacities (FMQ>+1) at subliquidus temperatures. For the transitional alkali-basaltic composition 7159V-P, both models reproduce the Fe³⁺/Fe ratio of the quenched liquids generally within 0.04, although agreement is worse for both models at high oxygen fugacities (FMQ>+1). Such behaviour may be related to a change in melt structure, where a progressive change in Fe³⁺ coordination is inferred to occur as a function of Fe³⁺/Fe based on Mössbauer center shifts. Recasting the data in terms of oxygen fugacity shows that calculated oxygen fugacities deviate from those actually maintained during the equilibration of the sample material by generally no more than 0.5 log-bar unit, with maximum deviations that only rarely exceed one log-bar unit.Editorial responsibility: J. Hoefs     

Solar-Blind Diamond Detectors for Lyra, the Solar VUV Radiometer on Board Proba II

Fabrication, packaging and experimental results on the calibration of metal-semiconductor-metal (MSM) photodetectors made on diamond are reported. LYRA (Lyman- RAdiometer onboard PROBA-2) will use diamond detectors for the first time in space for a solar physics instrument. A set of measurement campaigns was designed to obtain the XUV-to-VIS responsivity of the devices and other characterizations. The measurements of responsivity in EUV and VUV spectral ranges (40–240 nm) have been carried out by the Physkalisch-Technische Bundesanstalt (PTB) in Germany at the electron storage ring BESSY II. The longer wavelength range from 210 to 1127 nm was measured with monochromatic light by using a Xe-lamp at IMO-IMOMEC. The diamond detectors exhibit a photoresponse which lie in the 35–65 mA/W range at 200 nm (corresponding to an external quantum efficiency of 20–40%) and indicate a visible rejection ratio (200–500 nm) higher than four orders of magnitude.     

Paléoclimat des Petites Antilles depuis 4000 ans BP : l'enregistrement de la lagune de Grand-Case à Saint-Martin

A 2.5-m-thick sequence of lake sediments at the Étang de Grand-Case, Saint Martin (French West Indies) is studied here. Significant hydrological budget fluctuations allows distinction of three main climatic periods: (1) an overall dry period (4200 BP–2300 BP), characterised by carbonated mud, gypsum and storm sand layers; (2) a wet phase (2300 BP–1150 BP) dominated by organic mud; and (3) a more complex phase (1150 BP to present), with detrital inputs due to human activities. Comparison with other regional high-resolution records shows that similar climate modifications typify the whole Mesoamerican and Caribbean area. The climatic phenomena that are implicated in the variations of both precipitation and hurricane frequency over the Lesser Antilles are due to the latitudinal displacement of the inter-tropical convergence zone. These data give new support to the hypothesis of the existence of a correlation between peopling phases and climate variations in the Caribbean as previously proposed by some archaeologists. To cite this article: P. Bertran et al., C. R. Geoscience 336 (2004).