Current state and trends in Canadian Arctic marine ecosystems: I. Primary production

During the International Polar Year (IPY), large international research programs provided a unique opportunity for assessing the current state and trends in major components of arctic marine ecosystems at an exceptionally wide spatio-temporal scale: sampling covered most regions of the Canadian Arctic (IPY-Canada??s Three Oceans project), and the coastal and offshore areas of the southeastern Beaufort Sea were monitored over almost a full year (IPY-Circumpolar Flaw Lead project). The general goal of these projects was to improve our understanding of how the response of arctic marine ecosystems to climate warming will alter the productivity and structure of the food web and the ecosystem services it provides to Northerners. The present paper summarizes and discusses six key findings related to primary production (PP), which determines the amount of food available to consumers. (1) Offshore, the warming and freshening of the surface layer is leading to the displacement of large nanophytoplankton species by small picophytoplankton cells, with potentially profound bottom-up effects within the marine food web. (2) In coastal areas, PP increases as favourable winds and the deeper seaward retreat of ice promote upwelling. (3) Multiple upwelling events repeatedly provide food to herbivores throughout the growth season. (4) A substantial amount of pelagic PP occurs under thinning ice and cannot be detected by orbiting sensors. (5) Early PP in the spring does not imply a trophic mismatch with key herbivores. (6) The epipelagic ecosystem is very efficient at retaining carbon in surface waters and preventing its sedimentation to the benthos. While enhanced PP could result in increased fish and marine mammal harvests for Northerners, it will most likely be insufficient for sustainable large-scale commercial fisheries in the Canadian Arctic.     

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.     

Incorporating variable source area hydrology into a curve-number-based watershed model

Many water quality models use some form of the curve number (CN) equation developed by the Soil Conservation Service (SCS; U.S. Depart of Agriculture) to predict storm runoff from watersheds based on an infiltration-excess response to rainfall. However, in humid, well-vegetated areas with shallow soils, such as in the northeastern USA, the predominant runoff generating mechanism is saturation-excess on variable source areas (VSAs). We reconceptualized the SCS–CN equation for VSAs, and incorporated it into the General Watershed Loading Function (GWLF) model. The new version of GWLF, named the Variable Source Loading Function (VSLF) model, simulates the watershed runoff response to rainfall using the standard SCS–CN equation, but spatially distributes the runoff response according to a soil wetness index. We spatially validated VSLF runoff predictions and compared VSLF to GWLF for a subwatershed of the New York City Water Supply System. The spatial distribution of runoff from VSLF is more physically realistic than the estimates from GWLF. This has important consequences for water quality modeling, and for the use of models to evaluate and guide watershed management, because correctly predicting the coincidence of runoff generation and pollutant sources is critical to simulating non-point source (NPS) pollution transported by runoff. Copyright © 2007 John Wiley & Sons, Ltd.     

A New Method for C k -Surface Approximation from a Set of Curves, with Application to Ship Track Data in the Marianas Trench

We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C⁰, C¹, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.     

A late Triassic 40Ar/39Ar age for the El Hammam high-REE fluorite deposit (Morocco): mineralization related to the Central Atlantic Magmatic Province?

El Hammam is the only fluorite mine in Morocco (production 100,000 t/year). The fluorite mineralization is in an array of fluorite–calcite veins and is characterized by unusually high REE content in carbonate minerals (1,400 ppm in calcite; up to 2,000 ppm in siderite) and in fluorite (about 600 ppm). Since the 1960s, the genesis of the deposit has been attributed to a mesothermal hydrothermal event connected with late-Variscan granitic intrusions. Precise ⁴⁰Ar/³⁹Ar dating of hydrothermal K-feldspar yields an age of formation of the El Hammam deposit at 205 ± 1 Ma. Its genesis is therefore associated in time and space with the development of the Triassic–Jurassic basins and the associated anorogenic continental flood basalts of the Moroccan Mesetian Middle Atlas. The source of the hydrothermal mineralization (magmatic and/or metamorphic) is discussed.     

Morphotectonic evolution of the New Caledonia ridge (Pacific Southwest) from post-obduction tectonosedimentary record

The tectonostratigraphic and geomorphic study of two post-obduction fluvial sedimentary systems on mainland New Caledonia and imaged offshore on seismic reflection lines provides a new perspective on the post-orogenic evolution of the New Caledonia ridge. Relations between sedimentary sequence boundaries, erosion surfaces and faults, both on land and on offshore seismic reflection profiles indicate that an episode of extensional tectonics initiated in the Early Neogene led to the disruption and collapse of the island landsurface previously shaped during a Latest Oligocene phase of planation. Microtectonic analysis further suggests early slip on the normal faults was associated with ridge-normal extension. A later set of faults accompanied ridge-parallel to ridge-oblique extension that is interpreted to result from a shift toward a transtensional regime driven by the initiation of east-verging subduction of the Australian plate beneath the Pacific plate starting at least in the late Mid-Miocene.     

Effects of hydrostatic pressure on microbial alteration of sinking fecal pellets

We used a new experimental device called PASS (PArticle Sinking Simulator) during MedFlux to simulate changes in in situ hydrostatic pressure that particles experience sinking from mesopelagic to bathypelagic depths. Particles, largely fecal pellets, were collected at 200 m using a settling velocity NetTrap (SV NetTrap) in Ligurian Sea in April 2006 and incubated in high-pressure bottles (HPBs) of the PASS system under both atmospheric and continuously increasing pressure conditions, simulating the pressure change experienced at a sinking rate of 200 m d⁻¹. Chemical changes over time were evaluated by measuring particulate organic carbon (POC), carbohydrates, transparent exopolymer particles (TEP), amino acids, lipids, and chloropigments, as well as dissolved organic carbon (DOC) and dissolved carbohydrates. Microbial changes were evaluated microscopically, using diamidinophenylindole (DAPI) stain for total cell counts and catalyzed reporter deposition-fluorescence in situ hybridization (CARD-FISH) for phylogenetic distinctions. Concentrations (normalized to POC) of particulate chloropigments, carbohydrates and TEP decreased under both sets of incubation conditions, although less under the increasing pressure regime than under atmospheric conditions. By contrast, dissolved carbohydrates (normalized to DOC) were higher after incubation and significantly higher under atmospheric conditions, suggesting they were produced at the expense of the particulate fraction. POC-normalized particulate wax/steryl esters increased only under pressure, suggesting biochemical responses of prokaryotes to the increasing pressure regime. The prokaryotic community initially consisted of 43% Bacteria, 12% Crenarchaea and 11% Euryarchaea. After incubation, Bacteria dominated (90%) the prokaryote community in all cases, with γ-Proteobacteria comprising the greatest fraction, followed by the Cytophaga–Flavobacter cluster and α-Proteobacteria group. Using the PASS system, we obtained chemical and microbial evidence that degradation by prokaryotes associated with fecal pellets sinking through mesopelagic waters is limited by the increasing pressure they experience.     

Contribution of the 3-D visualization of acoustic borehole signals (full waveforms) to a quick formation evaluation

Logging and continuous coring are carried out when drilling and looking for materials such as gravels, sand, and clay or in order to evaluate the fracture state of a deep site intended for waste storage. However, in some cases of non-consolidated formations, the results may be disappointing because of the borehole conditions. Full waveforms, as seismic signals, provide information about physical parameters of the grounds crossed by the sonic tool, and this information is almost independent of borehole conditions. Traditional displays in variable area or density show the wave arrival times and the frequencies with depth; for variable density, a color scale permits to see clustered instantaneous phases.In order to determine precisely and simultaneously the three signal parameters (arrival time, frequency, and amplitude) in the depth-propagation time domain, a 3-D visualization software has been developed. The “view” parameters, which give a nice display of the 3-D→2-D projection of the signals in a parallel perspectives relative to depth, are estimated on the monitor screen in an interactive way. A larger size version of the software is available for displaying in detail the acoustic signals for the whole borehole. However, this program needs a large computer, and the maximum size of the drawing depends on the computer memory available for use.The comparison between traditional and 3-D displays shows that without previous preprocessing, the 3-D visualization (1) shows the very small and continuous variations of amplitude (and, therefore, of attenuation) with depth better; and (2) can bring out interferences and “energetic peaks” by simply changing the “view” parameters. As the attenuation of the different waves is directly determined, fresh zones can be distinguished immediately from fracture zones and hard ground from soft ground. The geometry of major fracturing can be deduced directly from graphical representation; i.e. open or closed, and horizontal or oblique fractures. The calculation of their “vertical thickness” is straightfoward. Microfractures, induced by drilling or otherwise, are not detected, but microfractured rocks are detectable.