Low-degree partial melting trends recorded in upper mantle minerals

The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO₂ and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO₂ and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO₂ for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr₂O₃ and poorer in SiO₂, K₂O, Na₂O, Al₂O₃ and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO₂ >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO₂ and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO₂ and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

Spatio-temporal variability of currents over a mobile dune field in the Dover Strait

A one month field campaign featuring two spring–neap tide cycles and three strong storms has been performed in a mobile dune area located in the central part of the Dover Strait. These dunes are known to move in a complex manner as their migration direction varies in space and time (Le Bot et al., 2000, Le Bot, 2001, Le Bot and Trentesaux, 2004). In order to gain some insights into the dune motion processes we present an analysis of the spatio-temporal variability of currents in the area emphasizing the relative influence of tides and storms. A total of eight different hydro-meteorological regimes have been distinguished during the experiment duration. The analysis of the currents measurements at five locations in the area shows that the eight hydro-meteorological regimes induce very different current responses at the bottom. The residual tidal currents exhibit a significant spatial variability both in direction and in intensity. A numerical model of tidal currents over the Dover Strait confirms the strong spatio-temporal variability of the residual tidal currents featuring three singular points. Amongst them, a saddle point is located just south of the I-dune at the convergence of opposite direction residual tidal currents. The wind-induced currents are almost uniform in space, their intensity and direction however strongly depends on the wind regime and thus on time. The mean total current feature a spatial pattern which can be tidal of wind-induced currents dominated, or either in balance, depending on the regime considered. At the PERMOD campaign time scale, the total current is dominated by the residual tidal current. These results proved to give valuable insights to explain the complex dynamics of dune motion observed in this area by Le Bot et al., 2000, Le Bot, 2001, Le Bot and Trentesaux, 2004 at short and long time scales.     

Glacial-interglacial mean sea level pressure change due to sea level, ice sheet and atmospheric mass changes

The change in the global mean atmospheric pressure between glacial and interglacial periods is evaluated at sea level. This change originates in a modification of topography and in a possible variation in the atmospheric mass. In this calculation the atmosphere is at hydrostatic equilibrium, and the parameters describing the glacial period are varied in a plausible range. The result, with constant atmospheric mass, is a mean sea level pressure decrease of 9–15 hPa linked with the deglaciation. The corresponding pressure change at the reference level corresponding to the present day sea level does not exceed one hPa. When considering only the change in the atmospheric mass, an increase which does not exceed 2 hPa is found, linked with the deglaciation.     

Evolution and Morphodynamics of a Prograded Beach‐Ridge Foreland,Northern Baffin Island,Canadian Arctic Archipelago

Landward retreat (marine transgression) is a common response of coastal systems to rising relative sea level. However, given sufficient sediment supply, the coast may advance seaward. The latter response of gravel barriers has been recorded in parts of southeastern and northwestern Canada, where seaward‐rising sets of beach ridges are observed in areas of Holocene RSL rise. Cape Charles Yorke, northern Baffin Island, is a 5 km long gravel foreland characterized by seaward‐rising beach‐ridge crest elevations. The prograded morphology of the Cape Charles Yorke foreland is a prime example of coastal response to a combination of rising RSL and abundant sediment supply, an unusual and little‐documented pattern in the Canadian Arctic. The main gravel supply to Cape Charles Yorke is likely from eroding bedrock and raised marine deposits southwest of the foreland. Although not the dominant sediment source, the Cape Charles Yorke delta contributed to the formation of the foreland by sheltering it from easterly storm waves and providing an anchor point for the prograding ridges. The truncation of relict ridges by the modern shoreline suggests a recent regime shift from continuous deposition to predominant erosion. The cause and timing of this shift are unknown but could result from a recent dwindling in sediment supply, increased accommodation space, increased wave energy, and/or an accelerated rise of relative sea level.     

Urban Morphology Influence on Urban Albedo: A Revisit with the Solene Model

This heuristic study of the urban morphology influence on urban albedo is based on some 3,500 simulations with the Solene model. The studied configurations include square blocks in regular and staggered rows, rectangular blocks with different street widths, cross-shaped blocks, infinite street canyons and several actual districts in Marseilles, Toulouse and Nantes, France. The scanned variables are plan density, facade density, building height, layout orientation, latitude, date and time of the day. The sky-view factors of the ground and canopy surfaces are also considered. This study demonstrates the significance of the facade density, in addition to the built plan density, as the explanatory geometrical factor to characterize the urban morphology, rather than building height. On the basis of these albedo calculations the puzzling results of Kondo et al. (Boundary-Layer Meteorol 100:225–242, 2001) for the influence of building height are explained, and the plan density influence is quantitatively assessed. It is shown that the albedo relationship with plan and facade densities obtained with the regular square plot configuration may be considered as a reference for all other configurations, with the exception of the infinite street canyon that shows systematic differences for the lower plan densities. The curves representing this empirical relationship may be used as a sort of abacus for all other geometries while an approximate simple mathematical model is proposed, as well as relationships between the albedo and sky-view factors.     

Impact of climate change on the hydrogeology of two basins in northern France

This study presents an analysis of climate-change impacts on the water resources of two basins located in northern France, by integrating four sources of uncertainty: climate modelling, hydrological modelling, downscaling methods, and emission scenarios. The analysis focused on the evolution of the water budget, the river discharges and piezometric heads. Seven hydrological models were used, from lumped rainfall-discharge to distributed hydrogeological models, and led to quite different estimates of the water-balance components. One of the hydrological models, CLSM, was found to be unable to simulate the increased water stress and was, thus, considered as an outlier even though it gave fair results for the present day compared to observations. Although there were large differences in the results between the models, there was a marked tendency towards a decrease of the water resource in the rivers and aquifers (on average in 2050 about ?14 % and ?2.5 m, respectively), associated with global warming and a reduction in annual precipitation (on average in 2050 +2.1 K and ?3 %, respectively). The uncertainty associated to climate models was shown to clearly dominate, while the three others were about the same order of magnitude and 3–4 times lower. In terms of impact, the results found in this work are rather different from those obtained in a previous study, even though two of the hydrological models and one of the climate models were used in both studies. This emphasizes the need for a survey of the climatic-change impact on the water resource.