Low-degree partial melting trends recorded in upper mantle minerals

The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO₂ and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO₂ and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO₂ for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr₂O₃ and poorer in SiO₂, K₂O, Na₂O, Al₂O₃ and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO₂ >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO₂ and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO₂ and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.     

Accumulation,solid partitioning and remobilisation of 99Tc in subtidal and intertidal sediments in the Irish Sea

Recent studies have shown that accumulation of ⁹⁹Tc in seabed sediments labelled by authorised radioactive liquid discharges into the NE Irish Sea from the Sellafield reprocessing complex is greater than previously thought. In this paper, new data on ⁹⁹Tc concentration profiles in subtidal and intertidal sediments from the eastern and western Irish Sea are provided with a view to elucidating the processes responsible for the incorporation and retention of ⁹⁹Tc in the seabed. The data show that substantial amounts of ⁹⁹Tc have accumulated in the fine-grained subtidal sediments off the Cumbrian coast, particularly after increased releases from Sellafield following the commissioning of the Enhanced Actinide Removal Plant (EARP) in 1994. In all the cores taken in this area, ⁹⁹Tc has been found to be present to depths in excess of 30 cm. Analysis of ¹³⁷Cs and ²⁴¹Am profiles, together with other supporting geochemical data, show a high degree of homogenisation of the sediments down to these depths as a result of physical and biological processes, and confirm that incorporation of ⁹⁹Tc into the sediment compartment is actually the result of mixing and reworking, rather than active sediment accumulation. In contrast, active deposition of material transported from this mixed pool of sediment appears to be the dominant mechanism controlling ⁹⁹Tc profiles in intertidal areas close to the Sellafield discharge outfall.Data obtained from the analysis of subtidal sediment cores from the western Irish Sea mud basin suggest that similar mixing processes to those occurring in the subtidal sediments of the eastern Irish Sea are also active in this area. Time-series data on ⁹⁹Tc concentrations in surficial sediments from this basin, gathered in the period 1988–2004, inclusive, show a clear increase in concentrations, by a factor of ～2, between samples collected pre-EARP and post-EARP. The constancy of ⁹⁹Tc concentrations in surface sediments throughout the 1980s and the early-1990s suggests that little redissolution and export of ⁹⁹Tc occurred over this extended period. A similar observation applies to the post-EARP period, when concentrations remained relatively constant despite the reported steady decrease in ⁹⁹Tc concentrations in the overlying waters.This apparent lack of remobilisation is consistent with data from sequential extraction analyses, which indicate that the bulk of the ⁹⁹Tc is strongly bound to non-labile geochemical phases, with only a small proportion associated with exchangeable and acido-soluble phases. Further, these analyses show that ⁹⁹Tc is not associated with oxygen-sensitive and highly-reactive acid-volatile sulphides (AVS) to any significant extent.     

Eclipses Observed by Large Yield RAdiometer (LYRA) – A Sensitive Tool to Test Models for the Solar Irradiance

We analyze the light curves of the recent solar eclipses measured by the Herzberg channel (200?–?220 nm) of the Large Yield RAdiometer (LYRA) onboard Project for OnBoard Autonomy (PROBA2). The measurements allow us to accurately retrieve the center-to-limb variations (CLV) of the solar brightness. The formation height of the radiation depends on the observing angle, so the examination of the CLV provide information about a broad range of heights in the solar atmosphere. We employ the 1D NLTE radiative transfer COde for Solar Irradiance (COSI) to model the measured light curves and corresponding CLV dependencies. The modeling is used to test and constrain the existing 1D models of the solar atmosphere, e.g. the temperature structure of the photosphere and the treatment of the pseudo-continuum opacities in the Herzberg continuum range. We show that COSI can accurately reproduce not only the irradiance from the entire solar disk, but also the measured CLV. Hence it can be used as a reliable tool for modeling the variability of the spectral solar irradiance.     

Contribution of a Dense Population of the Brittle Star <Emphasis Type="Italic">Acrocnida brachiata</Emphasis> (Montagu) to the Biogeochemical Fluxes of CO<Subscript>2</Subscript> in a Temperate Coastal Ecosystem

The production of organic matter and calcium carbonate by a dense population of the brittle star Acrocnida brachiata (Echinodermata) was calculated using demographic structure, population density, and relations between the size (disk diameter) and the ash-free dry weight (AFDW) or the calcimass. During a 2-year survey in the Bay of Seine (Eastern English Channel, France), organic production varied from 29 to 50 g_AFDW m⁻² year⁻¹ and CaCO₃ production from 69 to 104 g_CaCO3 m⁻² year⁻¹. Respiration was estimated between 1.7 and 2.0 mol_CO2 m⁻² year⁻¹. Using the molar ratio (ψ) of CO₂ released: CaCO₃ precipitated, this biogenic precipitation of calcium carbonate would result in an additional release between 0.5 and 0.7 mol_CO2 m⁻² year⁻¹ that represented 23% and 26% of total CO₂ fluxes (sum of calcification and respiration). The results of the present study suggest that calcification in temperate shallow environments should be considered as a significant source of CO₂ to seawater and thus a potential source of CO₂ to the atmosphere, emphasizing the important role of the biomineralization (estimated here) and dissolution (endoskeletons of dead individuals) in the carbon budget of temperate coastal ecosystems.     

The Loyalty—New Hebrides Arc collision: Effects on the Loyalty Ridge and basin system,Southwest Pacific (first results of the ZoNéCo programme)

The ZoNéCo 1 and 2 cruises of Ifremer's Research Vessel L'Atalante, collected new swath bathymetry and geophysical data over the southern and northern segments of the basins and ridges forming the Loyalty system. Between the two surveyed areas, previous studies found evidence for the resistance of the Loyalty Ridge to subduction beneath the New Hebrides trench near 22°S–169°E. On the subducted plate, except for seismicity related to the downbending of the Australian plate, recorded shallow seismicity is sparse within the Loyalty system (Ridge and Basin) where reliable focal mechanism solutions are almost absent.Swath bathymetry, seismic reflection and magnetic data acquired during the ZoNéCo 1 and 2 cruises revealed a transverse asymmetric morphology in the Loyalty system, and an along-strike horst and graben structure on the discontinuous Loyalty Ridge. South of 23°50S and at 20°S, the two WSW-ENE-trending fault systems, respectively, sinistral and dextral, that crosscut the southern and northern segments of the Loyalty system, are interpreted as due to the early effects of collision with the New Hebrides Arc. A NNW-SSE trend, evident along the whole Loyalty system and on the island of New Caledonia, is interpreted as an inherited structural trend that may have been reactivated through flexure of the Australian lithospheric plate at the subduction zone.Overall then, the morphology, structure and evolution of the southern and northern segments of the Loyalty system probably result from the combined effects of the Australian plate lithospheric bulge, the active Loyalty-New Hebrides collision and the overthrust of the New Caledonian ophiolite.     

Evaluation of snow water equivalent datasets over the Saint‐Maurice river basin region of southern Québec

A 10‐km gridded snow water equivalent (SWE) dataset is developed over the Saint‐Maurice River basin region in southern Québec from kriging of observed snow survey data for evaluation of SWE products. The gridded SWE dataset covers 1980–2014 and is based on manual gravimetric snow surveys carried out on February 1, March 1, March 15, April 1, and April 15 of each snow season, which captures the annual maximum SWE (SWEM) with a mean interpolation error of ±19%. The dataset is used to evaluate SWEM from a range of sources including satellite retrievals, reanalyses, Canadian regional climate models, and the Canadian Meteorological Centre operational snow depth analysis. We also evaluate a number of solid precipitation datasets to determine their contribution to systematic errors in estimated SWEM. None of the evaluated datasets is able to provide estimates of SWEM that are within operational requirements of ±15% error, and insufficient solid precipitation is determined to be one of the main reasons. The Climate System Forecast Reanalysis is the only dataset where snowfall is sufficiently large to generate SWEM values comparable to observations. Inconsistencies in precipitation are also found to have a strong impact on year‐to‐year variability in SWEM dataset performance and spread. Version 3.6.1 of the Canadian Land Surface Scheme land surface scheme driven with ERA‐Interim output downscaled by Version 5.0.1 of the Canadian Regional Climate Model was the best physically based model at explaining the observed spatial and temporal variability in SWEM (root‐mean‐square error [RMSE] = 33%) and has potential for lower error with adjusted precipitation. Operational snow products relying on the real‐time snow depth observing network performed poorly due to a lack of real‐time data and the strong local scale variability of point snow depth observations. The results underscore the need for more effort to be invested in improving solid precipitation estimates for use in snow hydrology applications.     

Optimisation de la quantification des flux de matière en suspension d'un cours d'eau alpin : l'Isère à Grenoble (France)

This study seeks to determine suspended-matter flux of the Isère at Grenoble, one of the most important rivers of the northern French Alps. Since 1994, and especially 1996, systematic samplings of the left bank make it possible to follow in one point the variations of suspended particles and matter (SPM) of this river. But from a single measurement, sometimes not very representative of the whole observable concentrations within the section, it remains still difficult to estimate precisely the SPM flux. The results of this study show in particular the successive appearance of several turbidity gradients, whose occurrence is explained mainly by the hydrological and hydro-sedimentary dynamics of this river. The estimate of these gradients thus makes it possible to extrapolate specific measurements more easily and consequently to daily define the quantities of suspended matter exported by the Isère. Since 1996, the results show a very high flow, specific of the Isère at Grenoble, variable between 124 and more than 460 t km^?2 yr^?1. To cite this article: D. Dumas, C. R. Geoscience 336 (2004).     

Spatio-temporal variability of currents over a mobile dune field in the Dover Strait

A one month field campaign featuring two spring–neap tide cycles and three strong storms has been performed in a mobile dune area located in the central part of the Dover Strait. These dunes are known to move in a complex manner as their migration direction varies in space and time (Le Bot et al., 2000, Le Bot, 2001, Le Bot and Trentesaux, 2004). In order to gain some insights into the dune motion processes we present an analysis of the spatio-temporal variability of currents in the area emphasizing the relative influence of tides and storms. A total of eight different hydro-meteorological regimes have been distinguished during the experiment duration. The analysis of the currents measurements at five locations in the area shows that the eight hydro-meteorological regimes induce very different current responses at the bottom. The residual tidal currents exhibit a significant spatial variability both in direction and in intensity. A numerical model of tidal currents over the Dover Strait confirms the strong spatio-temporal variability of the residual tidal currents featuring three singular points. Amongst them, a saddle point is located just south of the I-dune at the convergence of opposite direction residual tidal currents. The wind-induced currents are almost uniform in space, their intensity and direction however strongly depends on the wind regime and thus on time. The mean total current feature a spatial pattern which can be tidal of wind-induced currents dominated, or either in balance, depending on the regime considered. At the PERMOD campaign time scale, the total current is dominated by the residual tidal current. These results proved to give valuable insights to explain the complex dynamics of dune motion observed in this area by Le Bot et al., 2000, Le Bot, 2001, Le Bot and Trentesaux, 2004 at short and long time scales.     

Glacial-interglacial mean sea level pressure change due to sea level, ice sheet and atmospheric mass changes

The change in the global mean atmospheric pressure between glacial and interglacial periods is evaluated at sea level. This change originates in a modification of topography and in a possible variation in the atmospheric mass. In this calculation the atmosphere is at hydrostatic equilibrium, and the parameters describing the glacial period are varied in a plausible range. The result, with constant atmospheric mass, is a mean sea level pressure decrease of 9–15 hPa linked with the deglaciation. The corresponding pressure change at the reference level corresponding to the present day sea level does not exceed one hPa. When considering only the change in the atmospheric mass, an increase which does not exceed 2 hPa is found, linked with the deglaciation.