Determination of deployment specific chemical uptake rates for SPMD and PDMS using a passive flow monitor

Passive sampling techniques facilitate the time-integrated measurement of pollutant concentrations through the use of a selective receiving phase. Accurate quantification using passive sampling devices rely on the implementation of methods that will negate the effects of environmental factors (flow, temperature, etc.) or that will allow the calculation of the chemical specific rates of uptake (R(s)) into the passive sampler employed. We have applied an in situ calibration technique based on the dissolution of gypsum to measure the average water velocity to which a sampler has been exposed. We demonstrate that the loss of gypsum from the passive flow monitor (PFM) can be applied to predict changes in R(s) dependent on flow when using the absorbent SPMD (semipermeable membrane device) and PDMS (polydimethyl siloxan) passive samplers. The application of the PFM will enhance the accuracy of measurements made when calculating and reporting environmental pollutant concentrations using a passive sampling device.     

A mass mortality of subtropical intertidal populations of the sea urchin Paracentrotus lividus: analysis of potential links with environmental conditions

An outbreak of bald sea urchin disease was detected affecting intertidal populations of the edible temperate species Paracentrotus lividus at its southernmost geographical limit. The mortality event was detected in three sites (Güímar, Palmar and Alcalá) off Tenerife, Canary Islands (Northeastern Atlantic), in October 2003, coinciding with the highest sea surface temperatures (SST) and the lowest wave heights of the year. The prevalence of infection reached 100% but did not affect equally all studied sites or the different size classes. The disease was more prevalent in large sea urchins (>40 mm). The prevalence appeared to be positively correlated with the environmental variable SST and negatively correlated with wave height. In October 2004, only two infected urchins were found (prevalence 1%) at one of the studied sites. However, during 2004 no such extreme values of temperature and wave height were observed. We conclude that high SSTs and low wave heights such as those observed during 2003 are conditions that may trigger outbreaks of urchin disease.     

Toward a unified model of Altaids geodynamics: Insight from the Palaeozoic polycyclic evolution of West Junggar (NW China)

The Altaid tectonic collage extends over Central Asia, exposing numerous accretionary orogens that can account for the Palaeozoic continental crust growth. A pluridisciplinary approach, using geochronological, geochemical, structural and palaeomagnetic tools was carried out to unravel the architecture and the evolution of West Junggar(Northwestern China), a segment of the Altaid Collage. A polycyclic geodynamic evolution is inferred and includes:(1) an Early Palaeozoic cycle, characterized by the closure of two oceanic basins bounded by island-arc systems;(2) an Early Devonian subduction jamming resulting in a minor-scale collision documented by thrusting, syntectonic sedimentation and subsequent crutal thinning associated with alkaline magmatism;(3) a Late Palaeozoic cycle, driven by the evolution of two opposite subduction zones developed upon the Early Palaeozoic basement. Detailed structural analysis and paleomagnetic data provide constraints for the late evolution of Junggar in the frame of the development of the Late Palaeozoic Kazakh orocline, which led to oblique subduction and transpression in the West Junggar accretionary complex. Progressive buckling of the Kazakh orocline further resulted in Late Carboniferous to Permian wrench tectonics, and lateral displacement of lithotectonic units. Block rotations that continued after the Late Triassic are due to diachronous intraplate reactivation. This scenario mirrors the Palaeozoic geodynamics of the Altaid Collage. Multiple Early Palaeozoic collisions of intra-oceanic arcs and micro continents have contributed to the formation of the Kazakhstan Microcontinent. Since the Late Palaeozoic, subductions formed around this microcontinent and the final oblique closure of oceanic domains resulted in the transcurrent collage of Tarim and Siberia cratons. Palaeozoic strike-slip faults were later reactivated during Mesozoic intracontinental tectonics.     

Contribution of a Dense Population of the Brittle Star <Emphasis Type="Italic">Acrocnida brachiata</Emphasis> (Montagu) to the Biogeochemical Fluxes of CO<Subscript>2</Subscript> in a Temperate Coastal Ecosystem

The production of organic matter and calcium carbonate by a dense population of the brittle star Acrocnida brachiata (Echinodermata) was calculated using demographic structure, population density, and relations between the size (disk diameter) and the ash-free dry weight (AFDW) or the calcimass. During a 2-year survey in the Bay of Seine (Eastern English Channel, France), organic production varied from 29 to 50 g_AFDW m⁻² year⁻¹ and CaCO₃ production from 69 to 104 g_CaCO3 m⁻² year⁻¹. Respiration was estimated between 1.7 and 2.0 mol_CO2 m⁻² year⁻¹. Using the molar ratio (ψ) of CO₂ released: CaCO₃ precipitated, this biogenic precipitation of calcium carbonate would result in an additional release between 0.5 and 0.7 mol_CO2 m⁻² year⁻¹ that represented 23% and 26% of total CO₂ fluxes (sum of calcification and respiration). The results of the present study suggest that calcification in temperate shallow environments should be considered as a significant source of CO₂ to seawater and thus a potential source of CO₂ to the atmosphere, emphasizing the important role of the biomineralization (estimated here) and dissolution (endoskeletons of dead individuals) in the carbon budget of temperate coastal ecosystems.     

Export and degassing of terrestrial carbon through watercourses draining a temperate podzolized catchment

We measured spatial and temporal variations in carbon concentrations, isotopic compositions and exports during a complete hydrological cycle in nine watercourses draining a lowland forested podzolized catchment, flowing into the Arcachon lagoon (France). In addition, integrated fluxes of CO₂ across the water-atmosphere interface were estimated to assess the relative importance of CO₂ evasion versus lateral carbon transport at the catchment scale. Watercourse similarities and specificities linked to the local catchment characteristics are discussed and compared with other riverine systems. Low concentrations of suspended particulate matter and particulate organic carbon (POC) were generally measured in all the watercourses (8.4 ± 3.4 and 1.6 ± 0.6 mg L^?1, respectively), reflecting limited mechanical soil erosion. The generally high POC content in the suspended matter (20 %), low Chl a concentrations (1.3 ± 1.4 μg L^?1) and the relatively constant δ¹³C-POC value (near ?28 ‰) throughout the year reveal this POC originates from terrestrial C₃ plant and soil detritus. The presence of podzols leads to high levels of dissolved organic carbon (DOC; 6.6 ± 2.2 mg L^?1). Similarly, high dissolved inorganic carbon (DIC) concentrations were measured in the Arcachon lagoon catchment (5.9 ± 2.2 mg L^?1). The δ¹³C-DIC value around ?20 ‰ throughout the year in many small watercourses reveals the predominance of terrestrial carbon mineralisation and silicate rock weathering in soils as the major DIC source. With pCO₂ between 1,000 and 10,000 ppmv, all watercourses were a source of CO₂ to the atmosphere, particularly during the low river stage. Organic carbon parameters remained relatively stable throughout the year, whereas DIC parameters showed strong seasonal contrasts closely linked to the hydrological regime and hyporheic flows. In total, the carbon export from the Arcachon watershed was estimated at 15,870 t C year^?1 or 6 t C km^?2 year^?1, mostly exported to the lagoon as DOC (35 %), DIC (24 %) and lost as CO₂ degassing to the atmosphere (34 %).     

Processes of India’s offshore summer intraseasonal sea surface temperature variability

Active and break phases of the Indian summer monsoon are associated with sea surface temperature (SST) fluctuations at 30–90 days timescale in the Arabian Sea and Bay of Bengal. Mechanisms responsible for basin-scale intraseasonal SST variations have previously been discussed, but the maxima of SST variability are actually located in three specific offshore regions: the South-Eastern Arabian Sea (SEAS), the Southern Tip of India (STI) and the North-Western Bay of Bengal (NWBoB). In the present study, we use an eddy-permitting 0.25° regional ocean model to investigate mechanisms of this offshore intraseasonal SST variability. Modelled climatological mixed layer and upper thermocline depth are in very good agreement with estimates from three repeated expendable bathythermograph transects perpendicular to the Indian Coast. The model intraseasonal forcing and SST variability agree well with observed estimates, although modelled intraseasonal offshore SST amplitude is undere-stimated by 20–30 %. Our analysis reveals that surface heat flux variations drive a large part of the intraseasonal SST variations along the Indian coastline while oceanic processes have contrasted contributions depending of the region considered. In the SEAS, this contribution is very small because intraseasonal wind variations are essentially cross-shore, and thus not associated with significant upwelling intraseasonal fluctuations. In the STI, vertical advection associated with Ekman pumping contributes to ～30 % of the SST fluctuations. In the NWBoB, vertical mixing diminishes the SST variations driven by the atmospheric heat flux perturbations by 40 %. Simple slab ocean model integrations show that the amplitude of these intraseasonal SST signals is not very sensitive to the heat flux dataset used, but more sensitive to mixed layer depth.     

SMOS reveals the signature of Indian Ocean Dipole events

The tropical Indian Ocean experiences an interannual mode of climatic variability, known as the Indian Ocean Dipole (IOD). The signature of this variability in ocean salinity is hypothesized based on modeling and assimilation studies, on account of scanty observations. Soil Moisture and Ocean Salinity (SMOS) satellite has been designed to take up the challenge of sea surface salinity remote sensing. We show that SMOS data can be used to infer the pattern of salinity variability linked with the IOD events. The core of maximum variability is located in the central tropical basin, south of the equator. This region is anomalously salty during the 2010 negative IOD event, and anomalously fresh during the 2011 positive IOD event. The peak-to-peak anomaly exceeds one salinity unit, between late 2010 and late 2011. In conjunction with other observational datasets, SMOS data allow us to draw the salt budget of the area. It turns out that the horizontal advection is the main driver of salinity anomalies. This finding is confirmed by the analysis of the outputs of a numerical model. This study shows that the advent of SMOS makes it feasible the quantitative assessment of the mechanisms of ocean surface salinity variability in the tropical basins, at interannual timescales.

     

Morphological similarities between DBM and a microeconomic model of sprawl

We present a model that simulates the growth of a metropolitan area on a 2D lattice. The model is dynamic and based on microeconomics. Households show preferences for nearby open spaces and neighbourhood density. They compete on the land market. They travel along a road network to access the CBD. A planner ensures the connectedness and maintenance of the road network. The spatial pattern of houses, green spaces and road network self-organises, emerging from agents individualistic decisions. We perform several simulations and vary residential preferences. Our results show morphologies and transition phases that are similar to Dieletric Breakdown Models (DBM). Such similarities were observed earlier by other authors, but we show here that it can be deducted from the functioning of the land market and thus explicitly connected to urban economic theory.