Comparison of P- and S-waves velocities estimated from Biot-Gassmann and Kuster-Toksöz models with results obtained from acoustic wavetrains interpretation

Kuster-Toksöz and Biot-Gassmann models for estimating velocities of longitudinal and shear waves on the basis of well-logging data were analysed. P-wave and S-wave velocity models are crucial for interpretation of seismic data. Discussed models enable determination with quite good accuracy, in some cases higher than the acoustic full wavetrains interpretation. Because velocity strongly depends on lithology and saturation of pore space, the selection of parameters of rock matrix, hydrocarbons and formation waters has a strong effect on the quality of velocities estimation.     

Traces of structural H2O molecules in baryte

The infrared (IR) spectra of gem-quality baryte crystals from different occurrences are characterized by relatively weak but strongly pleochroic absorption bands at 3,280, 3,220, 3,155, and 3,115 cm⁻¹. These bands are assigned to anti-symmetric and symmetric OH stretching vibrations of two types of H₂O molecules localized on vacant Ba sites. The H–H axis of the H₂O I molecule is slightly tilted from the a-axis direction, its twofold axis being nearly parallel to the b-axis, thus defining the plane of the H₂O molecule practically parallel to (001). The H₂O II molecule has its H–H axis parallel to the b-axis direction, with its plane lying approximately parallel to (101). The values of the total water contents of the baryte crystals, calculated on the basis of IR spectroscopic data, are ranging from about 1.7–3.8 wt.ppm. The possible presence of H₃O⁺ ions is also discussed.     

Types of sedimentary environment in alluvial sediments distinguished on the basis of its chemical constitution: the example of the lower course of the Obra river (Western Poland)

Research concerning chemical constitution of alluvial sediments was done in the lower course of the Obra river (Western Poland). The fragment of vertical profile, which consisted of various alluvial sediments (fine sands, peats, and sandy silts) was chosen for detailed analysis. The main research problem was to determine if lithology and chemical constitution of alluvial deposits are interconnected in a distinct way within studied section of the Obra river valley, and, if changes of chemical elements’ concentration could be used to illustrate depositional processes, which take place in riverbed and floodplain. Concentrations of Fe, Mn, Cu, Zn, Ca, Mg, and K were determined in collected sediment samples. Next, geochemical groups of alluvial sediments were distinguished using cluster analysis. Investigated changes of chemical elements’ concentration show that there is a distinct border between the environment of organic sediments, which marks the place of former functioning of the Obra riverbed, and sandy silts, which were deposited within floodplain during floods. Besides, floodplain sediments, riverbed sediments, and reductive environment within peat deposits were singled out on the basis of the analysis.     

Simulation of an uncertain emission market for greenhouse gases using agent-based methods

The paper presents the problem of a simulation of the greenhouse gases emission permits market where only low accuracy emission amounts are known. An organization of the market with uncertain emissions is proposed and trading rules for individual market participants are discussed. Simulation of the market is based on a multi-agent system. Negotiation of purchase/sale prices between the parties are introduced, where the trading parties adopt one of two options: (i) bilateral negotiations, and (ii) sealed bid reverse auctions. Results of simulation runs show trajectories of transaction prices, as well as probability distributions of learning agents’ bidding prices.     

From Cadomian arc to Ordovician passive margin: geochemical records preserved in metasedimentary successions of the Orlica-Śnieżnik Dome in SW Poland

The chemical composition of metamorphosed siliciclastic rocks in the Orlica-?nie?nik Dome (Bohemian Massif) identifies the main sources for the Neoproterozoic [the M?ynowiec Formation (MF)], Early Cambrian [the Stronie Formation (SF)] and Late Cambrian/Early Ordovician [the Goszów quartzites (GQ)] sediments. The MF developed from erosion of a Cadomian magmatic arc along the northern Gondwana margin. The variegated SF, with supra-subduction affinities, shows chemical characteristics pointing to erosion of the freshly exhumed Cadomian orogen and detritus deposition in the back-arc basin. The very different chemical features of the GQ indicate deposition in a basin sited on a passive continental margin. The explanation proposed for the observed changes in chemical composition involves three main stages: (1) The pre ~540 Ma evolution of an active continental margin and related back-arc basin ceased with the collision and accretion of the magmatic arc to the Gondwana margin; (2) Early Cambrian rift to drift transition (540–500 Ma) and development of a depositional basin filled with detritus derived from remnants of the magmatic arc; (3) Peri-Gondwana break-up leading to the formation of shallow-water passive margin depositional basins filled with quartz-rich detritus resembling Early Ordovician Armorican quartzites known from other parts of the Variscan Belt.     

The Glarus Double Fold: a serious scientific advance in mid nineteenth century Alpine Geology

The Glarus overthrust is one of the best known examples of a thrust fault. Prior to its explanation as the base of an overthrust mass, this anomaly of the stratigraphic column had been explained by the Double Fold model, two recumbent folds facing each other. This model, advocated by Arnold Escher and Albert Heim, has been discredited by later geologists as a tectonically unsound concept which retarded the progress of science in this field of research. This article challenges parts of this view and tries instead to demonstrate that the Double Fold concept, though obviously wrong in retrospect, was a considerable scientific advance compared to the situation around 1850 when it was first proposed. To this end, the article summarizes the development of Swiss Alpine geology between 1800 and 1850 and places the Double Fold into its proper historical context. Earlier tectonic models (mostly proposed by Bernhard Studer) viewed crystalline rocks as the main driver of Alpine orogeny: due to somewhat mysterious metamorphic processes these rocks were supposed to have changed their lithology and physical properties and ascended vertically through small fissures. They uplifted, folded and eventually overflowed their sedimentary cover. The Glarus overthrust was also explained in this manner, probably even by Arnold Escher until the late 1840s. He later changed his mind and proposed the Double Fold concept which can be considered as one of the earliest attempts to apply the global contraction theory to the Alps. The global contraction theory later became the base of the geotectonic model of Eduard Suess and contributed to the final acceptance of large-scale horizontal displacements of rock masses around 1900. From this perspective, the Double Fold can be considered as a first step towards the nappe tectonic revolution and we suggest that its proposal was the expression of a fundamentally new way of thinking in Alpine tectonics.     

Analysis of labile form of aluminum and heavy metals in bottom sediments from Kongsfjord, Isfjord, Hornsund fjords

The paper presents study results obtained for the bottom sediment samples of fjords Kongsfjord, Isfjord, Hornsund in the form of surface samples and their core profiles. The concentrations of labile form of aluminum and heavy metals were determined using the single-stage extraction with 3 mol L^?1 HCl. The obtained results allowed defining the occurrence of variability of labile aluminum form in the samples of bottom sediments of the studied fjords depending on the point and depth of sample collection. The conducted chemometric analysis allowed for the study of spatial variability of aluminum occurrence in the area of the investigated fjords. Based on the analysis, the correlations between aluminum and heavy metals were determined.     

Luminescence and other spectroscopic properties of purple and green Cr-clinochlore

For the first time ever, the luminescence spectra of Cr³⁺ centers in two chlorite crystals are presented. Chromium ions occupy the strong crystal-field site M4 in the brucite sheet and the intermediate crystal-field site in the inner octahedral sheet for purple and green chlorite, respectively. We discuss the influence of an effective positive charge on the Cr³⁺ ion and an effective negative charge of ligands on the differences in the values of the Dq and B parameters. It is concluded that the presence of Fe²⁺ ions and other point defects, as well as concentration quenching, causes the very short luminescence lifetimes of chromium ions.     

Low‐cost monitoring of snow height and thermal properties with inexpensive temperature sensors

Small, self‐recording temperature sensors were installed at several heights along a metal rod at five locations in a case study catchment. For each sensor, the presence or absence of snow cover was determined on the basis of its insulating effect and the resulting reduction of the diurnal temperature oscillations. Sensor coverage was then converted into a time series of snow height for each location. Additionally, cold content was calculated. Snow height and cold content provide valuable information for spring flood prediction. Good agreement of estimated snow heights with reference measurements was achieved and increased discharge in the study catchment coincided with low cold content of the snow cover. The results of the proposed distributed assessment of snow cover and snow state show great potential for (i) flood warning, (ii) assimilation of snow state data and (iii) modelling snowmelt process. Copyright © 2010 John Wiley & Sons, Ltd.