Ambient biogenic hydrocarbons and isoprene emissions from a mixed deciduous forest

Experiments were conducted during the growing season of 1993 at a mixed deciduous forest in southern Ontario, Canada to investigate the atmospheric abundance of hydrocarbons from phytogenic origins, and to measure emission rates from foliage of deciduous trees. The most abundant phytogenic chemical species found in the ambient air were isoprene and the monoterpenes -pinene and -pinene. Prior to leaf-bud break during spring, ambient hydrocarbon mixing ratios above the forest remained barely above instrument detection limit (20 parts per trillion), but they became abundant during the latter part of the growing season. Peak isoprene mixing ratios reached nearly 10 parts per billion (ppbv) during mid-growing season while maximum monoterpene mixing ratios were close to 2 ppbv. Both isoprene and monoterpene mixing ratios exhibited marked diurnal variations. Typical isoprene mixing ratios were highest during mid-afternoon and were lowest during nighttime. Peak isoprene mixing ratios coincided with maximum canopy temperature. The diurnal pattern of ambient isoprene mixing ratio was closely linked to the local emissions from foliage. Isoprene emission rates from foliage were measured by enclosing branches of trees inside environment-controlled cuvette systems and measuring the gas mixing ratio difference between cuvette inlet and outlet airstream. Isoprene emissions depended on tree species, foliage ontogeny, and environmental factors such as foliage temperature and intercepted photosynthetically active radiation (PAR). For instance, young (<1 month old) aspen leaves released approximately 80 times less isoprene than mature (>3 months old) leaves. During the latter part of the growing season the amount of carbon released back to the atmosphere as isoprene by big-tooth and trembling aspen leaves accounted for approximately 2% of the photosynthetically fixed carbon. Significant isoprene mixing ratio gradients existed between the forest crown and at twice canopy height above the ground. The gradient diffusion approach coupled with similarity theory was used to estimate canopy isoprene flux densities. These canopy fluxes compared favorably with values obtained from a multilayered canopy model that utilized locally measured plant microclimate, biomass distribution and leaf isoprene emission rate data. Modeled isoprene fluxes were approximately 30% higher compared to measured fluxes. Further comparisons between measured and modeled canopy biogenic hydrocarbon flux densities are required to assess uncertainties in modeling systems that provide inventories of biogenic hydrocarbons.     

Gibt es eine „kritische Windgeschwindigkeit“ für die Grenzfläche Wasser — Luft?

Zusammenfassung Aus Windprofilmessungen in feststehenden H?hen über den Wellenk?mmen lassen sich keine zuverl?ssigen Schlüsse über die effektive Schubkraft des Windes an der Meeresoberfl?che ziehen. Der Grund liegt im wesentlichen in der verschiedenartigen vertikalen Windgeschwindigkeitsverteilung über Wellenbergen und Wellent?lern und in der Tatsache, da? die Windprofilmessungen im wesentlichen nur das Windprofil über den Bergen widerspiegeln. Der Versuch, die Windprofilmessungen zu „reduzieren“, ist mit zu gro?en Fehlern behaftet, zeigt aber qualitativ eine systematische Erh?hung der aus Windmessungen berechneten Reibungsfaktoren an. Damit kann der Anschlu? an die aus Windstaubeobachtungen ermittelten Reibungsfaktoren gewonnen werden, so da? der vermeintliche „Sprung“ von einer „glatten“ zu einer „rauhen“ Grenzfl?che verschwindet, und eine „kritische Windgeschwindigkeit“, die diesen Sprung angeben soll, gar nicht existiert.

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On the problem of the “critical wind velocity” at the air — sea boundary surface

Summary From the measurements of wind profiles at fixed heights above the wave crests no reliable conclusions can be drawn with regard to the wind's effective shearing force at the sea surface. This is essentially due to the diversified vertical distribution of the wind speed above the waves' crests and troughs as well as to the fact that when measuring wind profiles above the waves it is mainly the profiles above the wave crests that are obtained. Attempts to “reduce” wind profiles have proved to be subject to considerable errors; however, they show qualitatively a systematic increase of the frictional factors as computed from wind measurements. This links up with the frictional factors ascertained from observations of the wind effect so that the supposed “leap” from a “smooth” to a “rough” boundary surface and the “critical wind speed” corresponding to this leap do not exist at all.

     

Trophic Status of the South-Eastern Baltic Sea: A Comparison of Coastal and Open Areas

Primary production, nutrient concentrations, phytoplankton biomass (incl. chlorophyll a) and water transparency (Secchi depth), are important indicators of eutrophication. Earlier basin-wide primary production estimates for the Baltic Sea, a shallow shelf sea, were based mainly on open-sea data, neglecting the fundamentally different conditions in the large river plumes, which might have substantially higher production. Mean values of the period 1993–1997 of nutrient concentrations (phosphate, nitrate, ammonium and silicate), phytoplankton biomass, chlorophyll a (chl a) concentration, turbidity and primary production were calculated in the plumes of the rivers Oder, Vistula and Daugava and Klaipeda Strait as well as the open waters of the Arkona Sea, Bornholm Sea, eastern Gotland Sea and the Gulf of Riga. In the plumes, these values, except for primary production, were significantly higher than in the open waters. N:P ratios in the plumes were >16 (with some exceptions in summer and autumn), indicating potential P-limitation of phytoplankton growth, whereas they were <16 in the open Baltic Proper, indicating potential N-limitation. On the basis of in situ phytoplankton primary production, phytoplankton biomass and nutrient concentrations, the large river plumes and the Gulf of Riga could be characterized as eutrophic and the outer parts of the coastal waters and the open sea as mesotrophic. Using salinity to define the border of the plumes, their mean extension was calculated by means of a circulation model. Taking into account the contribution of coastal waters, the primary production in the Baltic Proper and the Gulf of Riga was 42·6 and 4·3×10⁶ t C yr⁻¹, respectively. Hence, an annual phytoplankton primary production in the whole Baltic Sea was estimated at 62×10⁶ t C yr⁻¹. The separate consideration of the plumes had only a minor effect on the estimation of total primary production in comparison with an estimate based on open sea data only. There is evidence for a doubling of primary production in the last two decades. Moreover, a replacement of diatoms by dinoflagellates during the spring bloom was noticed in the open sea but not in the coastal waters. A scheme for trophic classification of the Baltic Sea, based on phytoplankton primary production and biomass, chl a and nutrient concentrations, is proposed.     

Using measured variances to compute surface fluxes and dry deposition velocities: A comparison with measurements from three surface types

Abstract

Fluxes of temperature, water vapour, O₃, SO₂ and CO₂ were estimated from the measurement of their variances, taken over a wetland region in northern Ontario (Canada) during the summer of 1990 and over a deciduous forest when it was fully leafed during the summer of 1988 and when it was leafless during the winter of 1990. A set of flux‐variance relations was employed, including empirical forms of universal functions that could be adjusted with some constants. Results from the present study show that these constants needed to be adjusted with site‐specific data in order to achieve a closer agreement between estimated and observed fluxes. Best estimates were obtained for the fluxes of temperature and water vapour and it was found that the flux estimates of O₃, SO₂ and CO₂ correlated better with water vapour than with temperature. For these trace gases the flux‐variance method yielded estimates of dry deposition velocities that were either comparable with or larger than those obtained from a resistance analogue model. Both methods yielded values that overestimated the observed dry deposition velocities. The employment of the flux‐variance method in an operational network would require the use of fast‐response sensors and a practical method for reducing the noise level of the measured variances.     

Paired bedrock and boulder 10Be concentrations resulting from early Holocene ice retreat near Jakobshavn Isfjord,western Greenland

We measured in situ cosmogenic ¹⁰Be in 16 bedrock and 14 boulder samples collected along a 40-km transect outside of and normal to the modern ice margin near Sikuijuitsoq Fjord in central-west Greenland (69°N). We use these data to understand better the efficiency of glacial erosion and to infer the timing, pattern, and rate of ice loss after the last glaciation. In general, the ages of paired bedrock and boulder samples are in close agreement (r² = 0.72). Eleven of the fourteen paired bedrock and boulder samples are indistinguishable at 1σ; this concordance indicates that subglacial erosion rates are sufficient to remove most or all ¹⁰Be accumulated during previous periods of exposure, and that few, if any, nuclides are inherited from pre-Holocene interglaciations. The new data agree well with previously-published landscape chronologies from this area, and suggest that two chronologically-distinct land surfaces exist: one outside the Fjord Stade moraine complex (～10.3 ± 0.4 ka; n = 7) and another inside (～8.0 ± 0.7 ka; n = 21). Six ¹⁰Be ages from directly outside the historic (Little Ice Age) moraine show that the ice margin first reached its present-day position ～7.6 ± 0.4 ka. Early Holocene ice margin retreat rates after the deposition of the Fjord Stade moraine complex were ～100–110 m yr^?1. Sikuijuitsoq Fjord is a tributary to the much larger Jakobshavn Isfjord and the deglaciation chronologies of these two fjords are similar. This synchronicity suggests that the ice stream in Jakobshavn Isfjord set the timing and pace of early Holocene deglaciation of the surrounding ice margin.     

Orbit determination of the Lunar Reconnaissance Orbiter

We present the results on precision orbit determination from the radio science investigation of the Lunar Reconnaissance Orbiter (LRO) spacecraft. We describe the data, modeling and methods used to achieve position knowledge several times better than the required 50–100 m (in total position), over the period from 13 July 2009 to 31 January 2011. In addition to the near-continuous radiometric tracking data, we include altimetric data from the Lunar Orbiter Laser Altimeter (LOLA) in the form of crossover measurements, and show that they strongly improve the accuracy of the orbit reconstruction (total position overlap differences decrease from ~70 m to ~23 m). To refine the spacecraft trajectory further, we develop a lunar gravity field by combining the newly acquired LRO data with the historical data. The reprocessing of the spacecraft trajectory with that model shows significantly increased accuracy (~20 m with only the radiometric data, and ~14 m with the addition of the altimetric crossovers). LOLA topographic maps and calibration data from the Lunar Reconnaissance Orbiter Camera were used to supplement the results of the overlap analysis and demonstrate the trajectory accuracy.     

No large-angle correlations on the non-Galactic microwave sky

We investigate the angular two-point correlation function of temperature in the Wilkinson Microwave Anisotropy Probe ( WMAP) maps. Updating and extending earlier results, we confirm the lack of correlations outside the Galaxy on angular scales greater than about 60° at a level that would occur in 0.025 per cent of realizations of the concordance model. This represents a dramatic increase in significance from the original observations by the Cosmic Background Explorer Differential Microwave Radiometer ( COBE-DMR) and a marked increase in significance from the first-year WMAP maps. Given the rest of the reported angular power spectrum   C _ℓ  , the lack of large-angle correlations that one infers outside the plane of the Galaxy requires covariance among the   C _ℓ  up to  ℓ= 5  . Alternately, it requires both the unusually small (5 per cent of realizations) full-sky large-angle correlations and an unusual coincidence of alignment of the Galaxy with the pattern of cosmological fluctuations (less than 2 per cent of those 5 per cent). We argue that unless there is some undiscovered systematic error in their collection or reduction, the data point towards a violation of statistical isotropy. The near-vanishing of the large-angle correlations in the cut-sky maps, together with their disagreement with results inferred from full-sky maps, remains open problems, and are very difficult to understand within the concordance model.