Chemical equilibrium and mass balance relationships associated with the Long Valley hydrothermal system, California, U.S.A.

Recent drilling and sampling of hydrothermal fluids from Long Valley permit an accurate characterization of chemical concentrations and equilibrium conditions in the hydrothermal reservoir. Hydrothermal fluids are thermodynamically saturated with secondary quartz, calcite, and pyrite but are in disequilibrium with respect to aqueous sulfide-sulfate speciation. Hydrothermal fluids are enriched in ¹⁸O by approximately 1‰ relative to recharge waters. ¹⁸O and Cl concentrations in well cuttings and core from high-temperature zones of the reservoir are extensively depleted relative to fresh rhyolitic tuff compositions. Approximately 80% of the Li and 50% of the B are retained in the altered reservoir rock. Cl mass balance and open-system ¹⁸O fractionation models produce similar water-rock ratios of between 1.0 and 2.5 kg kg⁻¹. These water-rock ratios coupled with estimates of reservoir porosity and density produce a minimum fluid residence time of 1.3 ka. The low fluid Cl concentrations in Long Valley correlate with corresponding low rock concentrations. Mass balance calculations indicate that leaching of these reservoir rocks accounts for Cl losses during hydrothermal activity over the last 40 ka.     

A dispersion scale effect in model calibrations and field tracer experiments

Field tracer experiments and model calibrations indicate that the magnitude of dispersivity increases as a function of the scale at which observations are made. Calculations presented in this study suggest that some part of this scaling may be explained as an artifact of the models used. Specifically, a scaling-up of dispersivity will occur whenever an (n − 1)-dimensional model is calibrated or otherwise employed to describe an n-dimensional system. The calibrated coefficients for such models will depend not only on size of the contaminant plume or tracer experiment at the time of calibration, but will exhibit a size dependency beyond the calibration period. The magnitude of scaling appears to be sufficient to encompass the range of differences between laboratory measurements of dispersivity and model calibrations.     

Rate of soil erosion processes on vineyards in central Piedmont (NW Italy)

The ‘Tertiary Basin of Piedmont’ is a hilly region, mainly composed of marine sediments, such as marls, silts and sands. The slopes, largely devoted to grape production, are usually kept bare of vegetation and are thus prone to soil erosion processes. For two years we have measured soil loss in relation to rainfall on experimental plots located in vineyards. In all the plots considered erosion started with low rainfall intensities (0·07 mm/min), and above 0·4 mm/min the amount of soil loss dramatically increased (to over 1800 g/m in one event). Most of the erosion occurs during summer rainstorms, but the behaviour of the soil under erosive rainfalls is very different from one site to another, depending only in part upon the various rainfall rates, soil and geometrical characteristics of the plots. It can be seen that soil loss varies from nearly negligible values (20 g/m/yr) to unacceptably high levels (to over 4·7 kg/m/yr), according to the different types of land cultivation. Deep ploughing and heavy herbicide treatment give rise to accelerated erosion processes leading to soil losses much higher than in other vineyard plots in Europe.     

Mode of occurrence of Cu and Zn in till over three mineralized areas in Finland

The variation of Cu and Zn contents with grain size was studied in the size fractions: 2000-500 μm, 500-64 μm, 64-2 μm and minus 2 μm. The fixation to different minerals was investigated in the 500-64 μm and minus 64 μm fractions with microscope, microprobe, electron microscope and X-ray diffraction after heavy-liquid separation.The distribution of Cu and Zn between the four size fractions is very similar in all target areas. The contents tend to be highest in the minus 2 μm fraction, and to decrease with increasing grain size except for an increase in the coarsest material. This feature is typical in mineralized areas with till having anomalously high Cu and Zn contents.The anomalous Cu and Zn in the till of Talvivaara are mainly fixed to chalcopyrite and sphalerite, respectively, which indicates that the main part of the material originates from fresh bedrock and that postglacial alterations are slight. In the till of Outokumpu and Maaselkä sulphides are rare. We assume that in Outokumpu the reason for this is the postglacial weathering of sulphides and that in Maaselkä a great deal of till derives from highly weathered, sulphide-poor, preglacial regolith. In both target areas Cu in till seems to fix to limonite and also to clay minerals, particularly in Maaselkä. Zinc seems mainly to be hosted by limonite in Outokumpu.     

Application of integrated methods in mapping waste disposal areas

An integrated suite of environmental methods was used to characterize the hydrogeological, geological and tectonic regime of the largest waste disposal landfill of Crete Island, the Fodele municipal solid waste site (MSW), to determine the geometry of the landfill (depth and spatial extent of electrically conductive anomalies), to define the anisotropy caused by bedrock fabric fractures and to locate potential zones of electrically conductive contamination. A combination of geophysical methods and chemical analysis was implemented for the characterization and management of the landfill. Five different types of geophysical surveys were performed: (1) 2D electrical resistance tomography (ERT), (2) electromagnetic measurements using very low frequencies (VLF), (3) electromagnetic conductivity (EM31), (4) seismic refraction measurements (SR), and (5) ambient noise measurements (HVSR). The above geophysical methods were used with the aim of studying the subsurface properties of the landfill and to define the exact geometrical characteristics of the site under investigation.     

Earthquakes in Switzerland and surrounding regions during 2006

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2006. During this period, 572 earthquakes and 91 quarry blasts were detected and located in the region under consideration. Of these earthquakes, two occurred in conjunction with the construction of the new Gotthard railway tunnel and 165 were induced artificially by the stimulation of a proposed geothermal reservoir beneath the city of Basel. With 20 events with M _L ≥ 2.5, five of which were artificially induced, the seismic activity in the year 2006 was far below the average over the previous 31 years. Nevertheless, six events were felt by the public, most prominently the strongest of the induced Basel events (M _L 3.4), which caused some non-structural building damage. Noteworthy are also the two earthquakes near Cortaillod (M _L 3.2), on the shore of Lake Neuchatel, and in Val Mora (M _L 3.5), between the Engadin and Val Müstair, as well as the 42 aftershocks of the M _L 4.9 Vallorcine earthquake, between Martigny and Chamonix, of September 2005. Editorial handling: Stefan Bucher     

Aquifer development planning to supply a seaside resort: a case study in Goa,India

Using the hydrogeological and socio-economic data derived from a European Commission research project on the measurement, monitoring and sustainability of the coastal environment, two optimization models have been applied to satisfy the future water resources needs of the coastal zone of Bardez in Goa, India. The number of tourists visiting Goa since the 1970s has risen considerably, and roughly a third of them go to Bardez taluka, prompting growth in the tourist-related infrastructure in the region. The optimization models are non-linear mixed integer models that have been solved using GAMS/DICOPT++ commercial software. Optimization models were used, firstly, to indicate the most suitable zones for building seaside resorts and wells to supply the tourist industry with an adequate amount of water, and secondly, to indicate the best location for wells to adequately supply pre-existing hotels. The models presented will help to define the optimal locations for the wells and the hydraulic infrastructures needed to satisfy demand at minimum cost, taking into account environmental constraints such as the risk of saline intrusion.

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Résumé A l’aide de données hydrogéologiques et socio-économiques, dérivées d’un projet de recherche de la Commission Européenne sur l’étude, la surveillance et la durabilité de l’environnement c?tier, deux modèles d’optimisation ont été appliqués en vue de satisfaire les besoins futurs en ressources en eau de la zone c?tière de Bardez au Goa en Inde. Le nombre de touristes qui visitent le Goa depuis les années 70 a considérablement augmenté et environ un tiers d’entre eux se rend à Bardez taluka, ce qui encourage la croissance des infrastructures liées au tourisme dans la région. Les modèles d’optimisation sont des modèles non linéaires mixtes en nombres entiers qui ont été résolus en utilisant le logiciel commercial GAMS/DICOPT++. Les modèles d’optimisation ont été utilisés pour indiquer premièrement les zones les plus appropriées pour construire des stations balnéaires et des puits pour approvisionner en quantité d’eau suffisante l’industrie touristique, et deuxièmement pour indiquer la meilleure localisation de puits pour l’alimentation des h?tels préexistants. Les modèles présentés aideront à définir les localisations optimales des puits et des infrastructures hydrauliques nécessaires à la satisfaction de la demande à un co?t minimum, tout en prenant en compte les contraintes environnementales, tel que le risque d’intrusion saline.

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Resumen Se han aplicado dos modelos de optimización en base a datos socio-económicos e hidrogeológicos derivados de un proyecto de investigación de la Comisión Europea sobre medición, monitoreo y sostenibilidad del ambiente costero para satisfacer las necesidades futuras de recursos hídricos de la zona costera de Bardez en Goa, India. El número de turistas que visita Goa desde la década de 1970′s ha subido considerablemente y cerca de un tercio de ellos van a Bardez taluka impulsando el crecimiento en la infraestructura turística de la región. Los modelos de optimización son modelos de números enteros mixtos no-lineales que se han resuelto usando el programa comercial GAMS/DICOPT++. Los modelos de optimización se usaron, primero para indicar las zonas más adecuadas para la construcción de centros de diversión en las márgenes del océano y pozos para abastecer la industria turística con una adecuada cantidad de agua, y segundo, para indicar la mejor localización de pozos para el abastecimiento de hoteles pre-existentes. Los modelos que se presentan ayudarán a definir las localizaciones óptimas para los pozos y las infraestructuras hidráulicas necesarias para satisfacer la demanda al mínimo costo, tomando en consideración restricciones ambientales tal como el riesgo de intrusión salina.